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81.
Yoshitaka Yoda Yasuhiko Imai Hisao Kobayashi Syunji Goto Kunikazu Takeshita Makoto Seto 《Hyperfine Interactions》2012,206(1-3):83-86
An Upgrade of the nuclear resonant scattering beamline, BL09XU in SPring-8 has been conducted. A liquid nitrogen cooled high-heat load monochromator was installed and a 2nd experimental hutch was constructed. The instruments installed in the hutch allow for a variety of sample conditions. Newly developed high-resolution monochromators with better stability including the back scattering geometry monochromator have opened up the easy access to more isotopes and more precise measurements. 相似文献
82.
83.
Hui Zhao Shinji Mitsuiki Mikako Takasugi Masashi Sakai Masatoshi Goto Hiroaki Kanouchi Tatsuzo Oka 《Applied biochemistry and biotechnology》2012,166(7):1758-1768
Insoluble and hard-to-degrade animal proteins are group of troublesome proteins, such as collagen, elastin, keratin, and prion
proteins that are largely generated by the meat industry and ultimately converted to industrial wastes. We analyzed the ability
of the abnormal prion protein-degrading enzyme E77 to degrade insoluble and hard-to-degrade animal proteins including keratin,
collagen, and elastin. The results indicate that E77 has a much higher keratinolytic activity than proteinase K and subtilisin.
Maximal E77 keratinolytic activity was observed at pH 12.0 and 65 °C. E77 was also adsorbed by keratin in a pH-independent
manner. E77 showed lower collagenolytic and elastinolytic specificities than proteinase K and subtilisin. Moreover, E77 treatment
did not damage collagens in ovine small intestines but did almost completely remove the muscles. We consider that E77 has
the potential ability for application in the processing of animal feedstuffs and sausages. 相似文献
84.
Goto J. Oshima M. Sugawara M. Yamaguchi Y. Bi C. Bamba S. Morimoto T. 《Journal of Radioanalytical and Nuclear Chemistry》2017,314(3):1707-1714
Charged particle activation analysis (CPAA) is a rapid method with high accuracy which can analyze multi-elements simultaneously. Since multiple γ-ray detection method is expected to improve the detection efficiency and the signal-to-noise ratio, we study what design of the γ-ray detector array is the most suitable for CPAA. We take up four design candidates and investigated the responses by the radiation simulation code Geant 4. From the results, we have deduced the best design with 5 germanium detectors in close geometry. By inspecting the sensitivity in CPAA, the method is proved to be useful and applicable to 116 nuclides.
相似文献85.
86.
Koji Hashimoto Keiko Miwa Masanori Goto Yoshio Ishimori 《Supramolecular chemistry》2013,25(4):265-270
Abstract The authors have developed a novel, rapid, convenient, and specific gene detection method, named the ‘DNA sensor,’ using a graphite electrode loaded with DNA probes. Synthesized oligonucleotide (5-TGCAGTTCCGGTGGCTGATC-3′) complementary to oncogene v-myc was employed for a model probe. The oligonucleotide was chemically adsorbed on a basal plane pyrolytic graphite (BPPG) electrode. The sensor was able to be applied to a hybridization reaction (40°C) in a linearized pVM623 solution carrying the Pst I fragment of v-myc (1.5 kbp). After the hybridization reaction, the sensor was immersed into an acridine orange solution (1 μM) and washed with a phosphate buffer (pH 7.0). Acridine orange intercalated between base pairs of the formed double stranded DNAs on the electrode. The anodic peak potential of acridine orange that interacted with the DNAs on the electrode was measured. The positive shift of the peak potential increased in proportional to the pVM623 concentration in the hybridization reaction. 10?1 g/ml of pVM623 was able to be detected in the buffer solution using the sensor. This gene detection was completed within an hour. 相似文献
87.
Ryo Satoh Takaaki Goto Seon Hwa Lee Tomoyuki Oe 《Analytical and bioanalytical chemistry》2013,405(25):8001-8010
88.
Abstract Three types of nematogenic compound, 4-[2-(trans-4-alkylcyclohexyl)ethyl]-4′-alkyltolanes, 2-fluoro-4-[2-(trans-4-alkylcyclohexyl)ethyl]-4′-alkyltolanes and 4-[2-(trans-4-alkylcyclohexyl)ethyl]-4′-halogenotolanes, have been synthesized and their transition temperatures and enthalpies determined. Their bulk viscosity and birefringence have been estimated from those of mixtures with other liquid-crystalline compounds. These compounds have been found to be excellent materials for twisted nematic displays, because of their wide nematic temperature range, high birefringence (Δn = 0·26), and low viscosity (η = 21 cP at 20°C). Several related compounds having other central linkages, namely -CH2O-, a single bond or -COO-, in place of the 1,2-ethylene group, have also been studied. 相似文献
89.
Yuki Goto Masahiro Shiosaki Takeshi Hanamoto Masato Yoshida Hideo Sawada 《Colloid and polymer science》2013,291(5):1211-1217
Fluoro(silyl)acetylenes, which were prepared by reaction of 1,1-difluoroethylene with silyl chlorides, reacted with triethylamine to give dark-brown colored polyfluoro(silyl)acetylene powders in excellent to moderate isolated yields. In contrast, the corresponding nonfluorinated acetylene was unable to react with triethylamine at all to afford poly(silyl)acetylene under similar conditions. Polyfluoro(silyl)acetylenes thus obtained were nanometer size-controlled cubic fine particles with a good dispersibility and stability in a variety of solvents. These polyfluoro(silyl)acetylene nanoparticles exhibited clear absorption and emission spectra related to the conjugated units in polymer main chain. Furthermore, these polyfluoro(silyl)acetylene nanoparticles were applied to the surface modification of poly(methyl methacrylate) [PMMA] film to exhibit a higher oleophobicity imparted by fluorine on their surface, compared to that on the reverse side. Figure
New polyfluoro(silyl)acetylenes were prepared by reaction of the creesponding fluoro(silyl)acetylenes with triethylamine in excellent to moderate isolated yields. In contrast, the corresponding nonfluorinated silylacetylene was unable to give poly(silyl)acetylene under similar conditions. These polyfluoro(silyl)acetylenes thus obtained can form the nanometer size-controlled cubic fine particles (within 100 nm) in a variety of solvents. 相似文献
90.
Mari Iizuka Shoju Fukushima Yuki Goto Masaaki Okazaki Hideo Sawada Masato Yoshida 《Colloid and polymer science》2013,291(3):595-601
Head-to-head-type styrene and substituted styrene dimers bearing two fluoroalkyl end-groups have been efficiently synthesized by a simple reaction of perfluoroalkyl iodide with styrene under radical conditions as a mixture of meso and racemic forms. The meso form obtained from the mixture by recrystallization gave a crystal suitable for X-ray diffraction study and the crystal structure was found to be based on π-stacking of benzene rings and aggregation of fluoroalkyl chains. Dynamic light scattering measurements showed that meso-styrene dimers bearing two fluoroalkyl end-groups can form the nanometer size-controlled self-assemblies through the intermolecular π-stacking of benzene rings and aggregation of end-capped fluoroalkyl groups in methanol. Figure
Self-assembled meso-perfluorohexylated styrene dimer [C6F13–CH2CHPh–CHPh–CH2–C6F13] based on π-stacking of benzene rings and aggregation of fluoroalkyl chains: Fluorous domains are constructed by self-assembly of fluoroalkyl chains. 相似文献