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91.
Freitas LS Von Mühlen C Bortoluzzi JH Zini CA Fortuny M Dariva C Coutinho RC Santos AF Caramão EB 《Journal of chromatography. A》2009,1216(14):2860-2865
In this work the higher peak capacity and resolution of comprehensive two-dimensional gas chromatography (GCxGC) has been successfully applied, for the first time, to tentatively identify several polar organic compounds of organic extracts of aqueous phases resulting from microwave demulsification process of water-in-crude oil emulsions. Results have shown that higher temperatures and longer exposure time to microwave irradiation produced water phases with a wider variety of polar organic compounds. The microwave process showed to be suitable for the extraction of several polar compounds classes of petroleum. The proposed microwave extraction method and GCxGC identification of polar compounds of petroleum samples are of practical interest for the petrochemical industry due to corrosion and related problems associated with these polar compounds in refinery equipments. The GCxGC/time-of-flight MS technique shows to be very important in the total separation of different classes of compounds and allows the identification of many compounds in these classes. 相似文献
92.
Cristiane Costa Verusca H. S. Santos Claudia Sayer Pedro H. H. Araujo Alexandre F. Santos Montserrat Fortuny 《Macromolecular Symposia》2011,302(1):161-168
Summary: Emulsion polymerization reactions were performed under microwave irradiation and conventional heating using anionic or cationic initiators and surfactants. Microwave irradiation promoted higher reaction rates for both initiators and surfactants, in comparison with the conventional heating. The effect of high power microwave irradiation was studied using a method of cycles of heating and cooling, where rapid polymerization reactions were obtained. In the reactions with anionic initiator and surfactant, a decrease in the particle diameters was observed with microwave heating, and even smaller particles were obtained using high power microwave irradiation. Moreover, the decrease in the particle size was acompanied by an increase in the polymer molecular weight. On the other hand, these effects were not observed for reactions with cationic initiator and surfactant. 相似文献
93.
Ramiro Varela Camino R. Vela Jorge Puente María Sierra Inés González-Rodríguez 《Annals of Operations Research》2009,166(1):125-146
We confront a practical cutting stock problem from a production plant of plastic rolls. The problem is a variant of the well-known
one dimensional cutting stock, with particular constraints and optimization criteria defined by the experts of the company.
We start by giving a problem formulation in which optimization criteria have been considered in linear hierarchy according
to expert preferences, and then propose a heuristic solution based on a GRASP algorithm. The generation phase of this algorithm
solves a simplified version which is rather similar to the conventional one dimensional cutting stock. To do that, we propose
a Sequential Heuristic Randomized Procedure (SHRP). Then in the repairing phase, the solution of the simplified problem is
transformed into a solution to the real problem. For experimental study we have chosen a set of problem instances of com-mon
use to compare SHRP with another recent approach. Also, we show by means of examples, how our approach works over instances
taken from the real production process.
All authors are supported by MEC-FEDER Grant TIN2007-67466-C02-01 and by contract CN-05-127 of the University of Oviedo and
the company ERVISA, and by FICYT under grant BP04-021. 相似文献
94.
A series of donor-acceptor heteroleptic open sandwiches with formula CpM-M'Pyl (M = B, Al, Ga; M' = Li, Na; Cp = cyclopentadienyl; Pyl = pentadienyl) has been designed in silico using density functional theory. The most stable complexes are those containing boron as a donor atom. A molecular orbital analysis shows that the s character of the lone pair located at the group 13 element is mainly responsible for the complex stabilization. It is also found that the surrounding medium has a similar effect on these sandwiches such as in the "classical" donor-acceptor complexes, showing a decrement in the group 13 element-alkaline metal bond lengths. 相似文献
95.
Walther C Büchner S Filella M Chanudet V 《Journal of colloid and interface science》2006,301(2):532-537
We present a technique for measuring colloid size distributions between 15 nm and 2 microm at concentrations relevant to natural surface waters. Two particle-measuring methods are combined: laser-induced breakdown detection (LIBD), which allows the quantification of colloid size distributions below 400 nm, and a commercial single-particle counter that extends the accessible size range up to two mum. Centrifugation was used in order to separate micrometer sized particles for the LIBD measurement. The feasibility is demonstrated on water of Lake Brienz (Switzerland) and the River Pfinz (Germany) and the particle size distributions follow Pareto's law even down to 15 nm in both cases. 相似文献
96.
Masllorens E Rodríguez M Romero I Roglans A Parella T Benet-Buchholz J Poyatos M Llobet A 《Journal of the American Chemical Society》2006,128(16):5306-5307
Three new Ru-aqua complexes containing a mixed carbene and pyridylic ligands with general formulas [Ru(CNC)(bpy)(H2O)](PF6)2 (1) (CNC is 2,6-bis(butylimidazol-2-ylidene)pyridine; bpy is 2,2'-bipyridine) and cis-/trans-[Ru(CNC)(nBu-CN)(H2O)](PF6)2 (cis-2 and trans-2) (nBu-CN is 2-(butylimidazol-2-ylidene)pyridine) have been prepared and structurally characterized both in the solid state (monocrystal X-ray diffraction analysis for 1 and for the related complex trans-[Ru(Br)(CNC)(nBu-CN)](PF6)) and in solution (for all of them) through NMR. The electrochemical properties of these three Ru-aqua complexes have been investigated by cyclic voltammetry, differential pulse voltammetry and Coulombimetric techniques. It is found that, for complex 1 at pH 7, the difference between the IV/III and the III/II redox couples (DeltaE1/2) is 50 mV, which is the smallest ever reported for this type of complex. On the other hand, for complexes cis-2 and trans-2, the oxidation state III is unstable with respect to disproportionation to II and IV. The reactivity of their Ru=O species has been tested toward cis-beta-methylstyrene oxidation, and it has been compared to [Ru(O)(trpy)(bpy)]2+. An inverse correlation between the degree of cis/trans-epoxide isomerization and DeltaE1/2 is found. In particular, for complexes cis-2 and trans-2, which have a DeltaE1/2 < 0, the epoxidation is highly stereoselective, yielding only cis-epoxide. 相似文献
97.
J.M. Bluet D. Ziane G. Guillot D. Tournier P. Brosselard J. Montserrat P. Godignon 《Superlattices and Microstructures》2006,40(4-6):399
4.5 kV SiC Schottky diodes have been fabricated using Ni as the Schottky contact. A manufacturing yield of 40% is reached for the bigger area diodes (1.6×1.6 mm2) and of 70% for the smaller ones (0.4×0.4 mm2). The measured variations of barrier height and ideality factor with temperature do not agree with the thermionic model. This has been interpreted in terms of barrier height inhomogeneities using the Werner model. We extracted an average barrier height and its standard deviation . These two parameters are almost independent of the diode size. The variation of the barrier height distribution with field has also been investigated and shows a dependence similar to that of Schottky diodes realized from other semiconductor materials. 相似文献
98.
A furanoside phosphite-phosphoroamidite and diphosphoroamidite ligand library L1-L5a-f was tested in the asymmetric Rh-catalyzed hydrogenation of α,β-unsaturated carboxylic acid derivatives and enamides. Enantioselectivity depended strongly on the ligand parameters. High enantioselectivities were obtained in the reduction of dimethyl itaconate (up to >99% ee), α-dehydroamino acid esters (up to 99% ee) and several enamides (up to 92% ee). Kinetic and NMR studies on the intermediates of the catalytic cycle of the reaction indicate that the [Rh(P(1)-P(2))(substrate)](+) species is the resting state of the reaction and that the rate dependence is first order in rhodium and hydrogen pressure and zeroth order in the substrate. 相似文献
99.
Ramírez EA Cortés E Rubert AA Carro P Benítez G Vela ME Salvarezza RC 《Langmuir : the ACS journal of surfaces and colloids》2012,28(17):6839-6847
The adsorption of 4-mercaptopyridine on Au(111) from aqueous or ethanolic solutions is studied by different surface characterization techniques and density functional theory calculations (DFT) including van der Waals interactions. X-ray photoelectron spectroscopy and electrochemical data indicate that self-assembly from 4-mercaptopyridine-containing aqueous 0.1 M NaOH solutions for short immersion times (few minutes) results in a 4-mercaptopyridine (PyS) self-assembled monolayer (SAM) with surface coverage 0.2. Scanning tunneling microscopy images show an island-covered Au surface. The increase in the immersion time from minutes to hours results in a complete SAM degradation yielding adsorbed sulfur and a heavily pitted Au surface. Adsorbed sulfur is also the main product when the self-assembly process is made in ethanolic solutions irrespective of the immersion time. We demonstrate for the first time that a surface reaction is involved in PyS SAM decomposition in ethanol, a surface process not favored in water. DFT calculations suggest that the surface reaction takes place via disulfide formation driven by the higher stability of the S-Au(111) system. Other reactions that contribute to sulfidization are also detected and discussed. 相似文献
100.
Salinero C Feás X Mansilla JP Seijas JA Vázquez-Tato MP Vela P Sainz MJ 《Molecules (Basel, Switzerland)》2012,17(6):6716-6727
Camellia japonica (CJ) has oil-rich seeds, but the study of these oils has received little attention and has mainly focused only on their health properties. In the present work the relative composition of the fatty acid (FA) components of the triglycerides in cold-pressed oil from CJ is studied by 1H-NMR. The results obtained were: 75.75%, 6.0%, 0.17% and 18.67%, for oleic, linoleic, linolenic and saturated FA respectively. Levels of C?? unsaturated FA found in CJ oil were similar to those reported for olive oils. We also checked the possibility of using 13C-NMR spectroscopy; however, the results confirmed the drawback of 13C over 1H-NMR for the study of FA components of CJ triglycerides due to its low gyromagnetic ratio and its very low natural abundance. 相似文献