Sampled grating distributed feedback (SG DFB) semiconductor laser diode

A laser diode was designed using a method called sampled grating (SG) distributed feedback (DFB), in which the couplings have been distributed in certain regions along the laser cavity (i.e., regions contain grating). These regions play a big role in pushing the main mode to propagate faster than the side mode by increasing the time delay between them. This delay is due to the empty regions (i.e., regions without grating) along the laser cavity. Neither a phase shift nor incomplete grating have been taken into account with the new structure. The theoretical model in the present work is based on the coupled-mode equations which have been solved numerically by the mean of transfer matrix method (TMM).     

The first report on the catalytic oxidation of urazoles to their corresponding triazolinediones via in situ catalytic generation of Br using periodic acid or oxone/KBr system

A combination of periodic acid or oxone^® and a catalytic amount of KBr in the presence of few drops of water, were used for the catalytic oxidation of urazoles and bis-urazoles to their corresponding triazolinediones under mild and heterogeneous conditions with moderate to excellent yields.     

Thermal degradation of iron polymethacrylate

Iron polymethacrylate was synthesized by free radical solution polymerization of methacrylic acid, followed by replacement of the carboxylic proton with iron. Thermal volatilization analysis and thermogravimetry were used to study its thermal stability from ambient temperature up to 500oC. The results reveal that ferric oxide is left as residue at the end of the thermal degradation experiments.The authors dedicate this paper to the memory of the late Dr. Mohammad Zulfiqar of Quaid i Azam University, Islamabad, Pakistan.     

Kinetic study of the oxidation of some catecholamines by digital simulation of cyclic voltammograms

Electrochemical oxidation of some catecholamines such as dopamine ( 1 ), L ‐dopa ( 2 ), and methyldopa ( 3 ) has been studied in various pH values, using cyclic voltammetry. The results indicate participation of catecholamines ( 1–3 ) in intramolecular cyclization reaction to form the corresponding o‐quinone derivatives ( 1d–3d ). In various pHs, based on ECE mechanism, the observed homogeneous rate constants (k_obs) of cyclization reaction were estimated by comparing the experimental cyclic voltammetric responses with the digital‐simulated results. Also, the cyclization rate constants (k_cyc) were calculated using microscopic acidic dissociation constant of ammonium groups. The significant differences in electrochemical behavior, k_obs and k_cyc, of L ‐dopa ( 2 ) and methyldopa ( 3 ) with dopamine ( 1 ) are due to the effects of the side chain carboxyl group. © 2004 Wiley Periodicals, Inc. Int J Chem Kinet 37: 17–24, 2005     

Spectral Analysis of Some Distillates from Asphalt Cracking and Evaluation of UTIMAC as Cracking Catalyst

This paper demonstrates the spectral analysis of some distillates obtained from asphalt cracking in the presence of a conventional expensive catalyst, i.e., HZSM‐5, and local cheap and readily available clay, i.e., UTIMAC. Each distillate was fractionated into pentane soluble (PI) and pentane insoluble (PI) fractions based on solubility in n, pentane. Both PS and PI obtained in the case of HZSM‐5 and UTIMAC were analyzed by ¹H‐NMR spectrophotometry using CDCl₃ as dissolving solvent and tetramethylsilane (TMS) as internal standard. It is evident from the profiles that both catalysts caused the generation of some peaks ascribed to methylene and methene configurations in the aliphatic region. Bands corresponding to aromatic configurations were also generated. The results indicate that the cheap local catalyst used has comparable suitability with the conventional expensive catalyst in terms of asphalt cracking.     

A mild and efficient palladium–triethylsilane system for reduction of olefins and carbon–carbon double bond isomerization

The versatility of palladium(II) acetate and palladium on activated charcoal catalysts with triethylsilane has been investigated in the hydrogenation and the isomerization of carbon–carbon double bond of 1‐alkenes. The reduction of 1‐alkenes was carried out in the presence of triethylsilane, ethanol and a catalytic amount of palladium(II) acetate or palladium on activated charcoal, at room temperature. This facile and efficient method affords high yields for hydrogenation of unsaturated alkenes to the corresponding alkanes. Then the carbon–carbon double bond isomerization of 1‐alkenes was tested using the same catalysts in the absence of solvent. The system palladium(II) acetate‐triethylsilane was found to be more effective compared with palladium on an activated charcoal–triethylsilane system at room temperature, while comparable results were obtained at 50 °C for both catalysts. Copyright © 2006 John Wiley & Sons, Ltd.     

A multistep collocation method for solving advection equations with delay

Advection equations with delay are appeared in the modeling of the dynamics of structured cell populations. In this article, we construct an efficient two-dimensional multistep collocation method for the numerical solution of a class of advection equations with delay. Equations with aftereffect and equations with both aftereffect and retardation of a state variable are considered. Computability of the algorithm and convergence properties of the proposed numerical method are analyzed for solutions in appropriate Sobolev spaces, and it is shown that the proposed scheme enjoys the spectral accuracy. Numerical examples are given and comparison with other existing methods in the literature is made to demonstrate the efficiency, superiority and high accuracy of the presented method.     

Application of an Itô-based approximation method to random vibration of a pinching hysteretic system

In this paper, an extension of the Cumulant-Neglect closure scheme is utilized for the random vibration analysis of a single degree of freedom system with a general pinching hysteresis restoring force. The hysteresis element used in the system model can simulate commonly observed forms of stiffness, strength and pinching degradations. The second order statistics of the system response to a stationary Gaussian white noise input are derived using an Itô-based approximation technique. The validity of these response statistics are then verified by comparing them to Monte Carlo simulation results. The numerical studies performed for different combinations of degradation parameters and excitation levels show that the response estimates obtained by this solution method are in good agreement with Monte Carlo simulation. These studies also indicate the applicability of this technique for response analysis of complicated forms of non-linearities.