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141.
Ramin Ghahremanzadeh Mojtaba Mirhosseini Moghaddam Ayoob Bazgir Mohammad Mehdic Akhondi 《中国化学》2012,30(2):321-326
A four‐component reaction in the presence of Alum [KAl(SO4)2·12H2O] as an inexpensive and reusable catalyst using the ionic liquid as an effective green reaction media is reported. 相似文献
142.
Abedien Zabardasti Ali Kakanejadifard Motaleb Ghasemian Mohammad Solimannejad 《Structural chemistry》2012,23(4):1155-1161
The molecular interactions between phosphorous ylide (PY) and HX molecules (X?=?F, CN, and N3) were investigated using the MP2 method at 6-311++G(2d,2p) basis set. Three different patterns including non-classical hydrogen bond H···C, X···P interaction and classical hydrogen bond H···X were found for complex formation between PY and HX molecules. From the predicted models, stability of the H···C type complexes are greater than other types. Quantum theories of atoms in molecules and natural bond orbitals methods have been applied to analyze the intermolecular interactions. Good correlations have been found between the interaction energies (SE), the second-order perturbation energy E (2), and the charge transfer qCT in the studied systems. 相似文献
143.
144.
G. D?browska 《Journal of Thermal Analysis and Calorimetry》2012,109(2):745-749
A new compound in the Al?CSb?CV?CO system of the composition AlSbVO6 was successfully synthesized by a solid-state reaction and characterized by powder XRD diffraction. The structural and thermal properties of AlSbVO6 were investigated. The infra-red spectrum of the new phase is presented. 相似文献
145.
Pál Perjési Gábor Maász Renáta Reisch András Benk? 《Monatshefte für Chemie / Chemical Monthly》2012,5(3):1107-1114
Abstract
The non-enzyme-catalyzed reaction of reduced glutathione (GSH) with two tumor cell cytotoxic cyclic chalcone analogues was investigated by reversed-phase high-performance liquid chromatography (RP-HPLC). HPLC analysis of the reaction mixtures indicated the formation of two diastereomeric chalcone–GSH adducts in each case, whose structural assignments were supported by MALDI-TOF-MS and HPLC–MS with electrospray ionization (ESI) measurements. Such reactivity accounts for the previously observed effect of the two cyclic chalcone analogues on the in vivo cellular thiol level of Jurkat T cells. 相似文献146.
Elgiz Bairamov Rukiye ?zturk Mert Zameddin Ismailov 《Journal of mathematical chemistry》2012,50(5):1100-1110
In this work, firstly in the Hilbert space of vector-functions all selfadjoint extensions of the minimal operator generated by linear singular symmetric differential expression with a selfadjoint operator coefficient A in any Hilbert space H, are described in terms of boundary values. Later structure of the spectrum of these extensions is investigated. 相似文献
147.
The reaction of [RuHCl(CO)(PPh3)3] with 4-phenylpyrimidine gave a new ruthenium(II) complex, namely [RuHCl(CO)(PPh3)2(pyrim-4-Ph)]. The complex has been studied by IR and UV?Cvis spectroscopy and by X-ray crystallography. The molecular orbitals of the complex have been calculated by density functional theory. The spin-allowed singlet?Csinglet electronic transitions of the complex have been calculated by time-dependent DFT, and the UV?Cvis spectrum of the compound has been discussed on this basis. The emission properties of the complex were also studied. 相似文献
148.
Mohammad Ali Karimi Zarchi Mojgan Nejabat 《Journal of the Iranian Chemical Society》2012,9(5):767-774
Alkyl halides are efficiently converted to their corresponding S-alkyl thioacetates under mild and nonaqueous conditions, using polymer-supported sodium thioacetate as a new polymeric reagent at room temperature in high yields and purity. The spent polymeric reagent can be removed quantitatively by filtration and pure products can be obtained by evaporation of the solvent. The spent polymeric reagent can be regenerated and reused several times without its activity changing appreciably. 相似文献
149.
Non-uniform distribution of moisture contents inside of the porous materials during drying results in compressional stresses inside of the material and tensional ones close to the surface. The tensional stresses together with brittleness of dry material are the reasons of fracturing of the material. The proposed model consists of two parts. The mass transfer is described by simple diffusion equation. The mechanical behaviour of the material is modelled with the network model in which the material is modelled as the set of small particles interconnected elastically via springs. The spring constants and strengths depend on Young modulus and the material tensional strength. The dependences of these material parameters on the moisture content are determined. Then two 2D initial-boundary problems are solved. The results show possible way of cracks initiation and generation by drying. 相似文献
150.
This paper presents a special use of the linear poroelasticity theory to describe tidally induced groundwater oscillations. Two models of oscillation inducing mechanism make use of this theory to predict groundwater level fluctuations. The numerical solutions of both models are presented and compared with well water level measurement obtained in Police Basin, north-east Bohemia. 相似文献