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131.
A fundamental study was made on the reduction of calcium phosphate by carbon. The mechanism of reduction was presented on applying different additions. Both silica and alumina increased the extent of reduction but with variable rates. The activation energies were calculated on the basis of first-order reactions. The phases formed during reduction were investigated by X-ray analysis. 相似文献
132.
E. Betranhandy Samir F. Matar Ch. El‐Kfoury R. Weihrich J. Etourneau 《无机化学与普通化学杂志》2004,630(15):2587-2598
The changes in electronic structure and hardness as inferred from the bulk modulus are investigated for model structures of ternary compounds XC3N3 (X = B, Al, P, As, Ga) within the framework of density functional theory (DFT). The optimisations of the proposed two‐ (2D) and three‐dimensional (3D) structures and the calculations of the bulk moduli are performed by a pseudo potential method. The electronic structures are calculated with the augmented sphere wave method (ASW). The obtained hardness for 2D BC3N3 system (B0 ~ 220 GPa) points to a magnitude close to that of graphitic C3N4. For heavier X atoms it decreases rapidly. This is equally observed for the 3D systems examined in the β‐C3N4 structure for which B0(β‐BC3N3) amounts to ~330 GPa. Within the magnitude of the well known hard material cubic BN, the BC3N3 phases can be predicted as candidates for ultra hard materials. The electronic effect induced by the chemical nature of the X substitutional was examined according to its position in the periodic table i.e. XIII or XV. Both, band structures and the electron localisation function (ELF) were used for this analysis. The ELF plots show a decreasing covalency with heavier X‐atoms. Potential applications of the devised systems are proposed such as dopings with atoms (Li, rare gas) and molecules (N2). 相似文献
133.
Abdelfetah Mounir Mohamed El Guendouzi Abderrahim Dinane 《Journal of solution chemistry》2002,31(10):793-799
Ternary aqueous solutions of MgSO4 and K2SO4 have been studied by the hygrometric method at 25°C. The relative humidity of this system is measured at total molalities from 0.35 mol-kg–1 to about saturation for three ionic-strength fractions (y = 0.25, 0.50, and 0.80 of MgSO4. The data allow calculation of water activities and osmotic coefficients. From these measurements, the Pitzer ionic mixing parameters are determined and used to predict the solute activity coefficients in the mixture. The results are used to calculate the excess Gibbs energy at total molalities for ionic-strength fraction y. 相似文献
134.
Houda Marouani Mohamed Rzaigui Muriel Bagieu‐Beucher 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(3):356-357
In hexakis(m‐toluidinium) cyclohexaphosphate, 6C7H10N+·P6O186?, the atomic arrangement is typical of a layer structure. Layers including the centrosymmetric P6O18 ring anions develop around the (100) planes at x = . The hydrogen‐bond distribution is described. 相似文献
135.
Lamia T. Abou El-Kassem Usama W. Hawas Mohamed S. Abdelfattah Ayat A. Mostafa 《Natural product research》2020,34(5):613-620
AbstractA new rotenoid named 12-O-methylrotenolol along with five known rotenoid and isoflavone metabolites were isolated from the seeds of Dalbergia lanceolaria subsp. paniculata, collected from Egypt. The structures of these compounds were identified by physical and spectroscopic data measurements ([α]D, UV, 1D- and 2D-NMR and MS). The methanol extract of the seeds exhibited strong antioxidant activity with IC50 value 0.7?µg/µl against DPPH radical, in respect to quercetin as antioxidant reference (IC50 1.5?μM), while the tested compounds from this extract showed weak activities with IC50 values ranged from 19.6 to 33.0?µM. 相似文献
136.
The syntheses and the X-ray structures of the tetranuclear gold(I) benzamidinate, Au4[PhNC(Ph)NPh]4, and the tetranuclear gold(I) acetamidinate, Au4[PhNC(CH3)NPh]4, clusters are reported. The clusters are produced by the reaction of the sodium salt of an amidine ligand with the gold precursor
Au(THT)Cl in a (1:1) stoichiometry. The average Au...Au distance between adjacent Au(I) atoms is ∼2.9 ?, typical of compounds
having an aurophilic interaction. The four gold atoms are arranged in a square (Au...Au...Au... = 88–91°) in the acetamidinate
and in a distorted square (Au...Au...Au... = 82–97°) in the benzamidinate derivative. Electrochemical oxidation of the tetranuclear
complex Au4[PhNC(Ph)NPh]4 show three reversible waves at 0.87, 1.19, 1.42 V vs. Ag/AgCl at a scan rate of 100 mV/s in CH2Cl2 similar to the three reversible waves seen before from the tetranuclear complexes Au4[ArNC(H)NAr]4, Ar = C6H4-4-OMe, Ar = C6H4-4-Me, and Ar = C6H3-3,5-Cl. A summary of the chemistry of the tetranuclear Au(I) amidinate complexes Au4[ArNC(H)NAr]4, Ar = C6H4-4-OMe, C6H3-3,5-Cl, C6H4-4-Me, C6H4-3-CF3, C6F5, C10H7 also is presented. The tetranuclear clusters Au4[ArNC(H)NAr]4, Ar = C6H4-4-OMe, Ar = C6H4-3-CF3, Ar = C6H4-4-Me and Ar = C6H4-3,5-Cl are the first tetranuclear gold(I) cluster species from group 11 elements to show fluorescence at room temperature.
The lifetimes of the naphthyl and trifluoromethylphenyl complexes are in the millisecond range indicating phosphorescent processes.
Recently it has been shown that Au4[ArNC(H)NAr]4 are very effective catalysts upon calcination for room temperature CO oxidation.
Congratulations to Dieter Fenske, a superb synthetic chemist with exceptional talents in cluster chemistry, on the occasion
of his 65th birthday. 相似文献
137.
The paper presents a new method for the generation of acetaldehyde in the amounts that allow to calibrate the measuring system. The method is based on thermal decomposition of surface compounds at the range 130-190 °C, in which an acetaldehyde as the decomposition product is released. The synthetic pathway leading to the desired surface compounds is described. Investigations demonstrated that the synthesis of the compounds on the surface of the support material (silica gel) was carried out homogeneously. The technique proposed was used for the generation of gaseous standard mixtures containing acetaldehyde for the calibration of a thermal desorber-gas chromatograph-flame ionization detector system. 相似文献
138.
The new unsymmetrical N‐bridgehead, apo (zeromethine), mono‐methine, dimethine, meso substituted tetramethine and styryl cyanine dyes incorporating pyrazolo (4,5‐b) indolizine (benzoindolizine) nuclei were prepared. Structural confirmation was carried out by elemental analyses, IR, H‐NMR, mass spectra and 13C‐NMR with the aid of carbon DEPT spectral data. The visible absorption spectra for the newly synthesized cyanines were examined in 95% ethanol. 相似文献
139.
Mohamed Hilmy Elnagdi Mohamed Riffaat Hamza Elmoghayer Hassan Attia Elfaham Mohamed Mohamed Sallam Hikmat Hussein Alnima 《Journal of heterocyclic chemistry》1980,17(2):209-212
The 4-bromo-3-phenylpyrazol-5-ylhydrazonyl chlorides (Ia,b) and 1,2,4-triazol-5-ylhydrazonyl chlorides (IIa,b) were prepared via coupling of diazotized 4-bromo-3-phenyl-5-aminopyrazole (III) and 5-amino-1,2,4-triazole (IV) with α-chloro derivatives of acetylacetone and of ethyl aceto-acetate. Compounds Ia and IIa,b were utilised for the synthesis of several new heterocyclic derivatives. 相似文献
140.
Mohamed Ariff Md. Jainuddin V. Gopalan K. Venkata Rao 《Journal of polymer science. Part A, Polymer chemistry》1985,23(7):2063-2071
The polymerization of acrylonitrile initiated by an ascorbic acid–peroxodisulfate redox system was studied in an aqueous solution at 35°C in the presence of air. Molecular oxygen was found to have no effect on the polymerization reaction. An increase in ionic strength slightly increased the rate. The overall rate of polymerization, Rp, showed a square dependence on [monomer] and a half-order dependence on [peroxodisulfate]. A first-order dependence on [ascorbic acid] at low concentrations (<3.0 × 10?3 mol L?1) followed by a decrease in Rp at higher concentrations of ascorbic acid (>3.0 × 10?3 mol L?1) was also noted. Rp remained unchanged up to 40°C and showed a decline thereafter. Addition of catalytic amounts of cupric ions decreased the rate whereas ferric ions were found to increase the rate. Added sulfuric acid in the range (6.0?50.0) × 10?5 mol L?1 decreased the Rp. 相似文献