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861.
Synthesis, characterization and photophysical properties of benzidine-based compounds 总被引:1,自引:0,他引:1
The N-alkylation of the 3,3′-diaminobenzidine with innocent substituents leads to unusual properties. The emission of the benzidine core can be fine-tuned by subtle modifications, and the N-substitution with benzylic groups results in photoinduced exciplexes with distinct and increased emission. This compound constitutes the first example of intramolecular exciplex containing benzidine unit. We also show that these photoinduced processes could be modulated by proton input, and that the diprotonation of the benzidine core disrupted the intramolecular communication in the excited states with a concomitant inhibition of the ligand-centred fluorescence. Furthermore, upon photo-irradiation at 254 nm, semiquinone imine and quinone diimine systems are produced in CH2Cl2 of which the photolysis generates Cl radicals, which rapidly oxidize the tetraamine compounds. 相似文献
862.
Dr. Haitao Yu Dr. Angelina Angelova Dr. Borislav Angelov Dr. Brendan Dyett Dr. Lauren Matthews Yiran Zhang Mohamad El Mohamad Xudong Cai Dr. Sepideh Valimehr Prof. Calum J. Drummond Dr. Jiali Zhai 《Angewandte Chemie (International ed. in English)》2023,62(35):e202304977
Ionisable amino-lipid is a key component in lipid nanoparticles (LNPs), which plays a crucial role in the encapsulation of RNA molecules, allowing efficient cellular uptake and then releasing RNA from acidic endosomes. Herein, we present direct evidence for the remarkable structural transitions, with decreasing membrane curvature, including from inverse micellar, to inverse hexagonal, to two distinct inverse bicontinuous cubic, and finally to a lamellar phase for the two mainstream COVID-19 vaccine ionisable ALC-0315 and SM-102 lipids, occurring upon gradual acidification as encountered in endosomes. The millisecond kinetic growth of the inverse cubic and hexagonal structures and the evolution of the ordered structural formation upon ionisable lipid-RNA/DNA complexation are quantitatively revealed by in situ synchrotron radiation time-resolved small angle X-ray scattering coupled with rapid flow mixing. We found that the final self-assembled structural identity, and the formation kinetics, were controlled by the ionisable lipid molecular structure, acidic bulk environment, lipid compositions, and nucleic acid molecular structure/size. The implicated link between the inverse membrane curvature of LNP and LNP endosomal escape helps future optimisation of ionisable lipids and LNP engineering for RNA and gene delivery. 相似文献
863.
Back Cover: CuNi binary alloy catalyst for growth of nitrogen‐doped graphene by low pressure chemical vapor deposition (Phys. Status Solidi RRL 10/2016)
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864.
Hamman Tukur Gabdo Ahmad Termizi Ramli Nuraddeen Nasiru Garba Mohamad Sanusi 《Isotopes in environmental and health studies》2016,52(3):298-308
This study was aimed at providing the baseline data of terrestrial gamma dose rates and natural radioactivity to assess the corresponding health risk in the ambient environment of the Pahang State. Terrestrial gamma radiation (TGR) from 640 locations was measured with the mean value found to be 176?±?5 nGy h?1. Ninety-eight soil samples were analysed using a high-purity germanium detector (HPGe), and the mean concentrations of the radionuclides 226Ra, 232Th and 40K are 110?±?3, 151?±?5 and 542?±?51 Bq kg?1, respectively.226Ra and 232Th concentrations were found to be three times the world average, while that of 40K is quite higher than the world average value. The acid-intrusive geological formation has the highest mean concentrations for 226Ra (215?±?6 Bq kg?1), 232Th (384?±?12 Bq kg?1) and 40K (1564?±?153 Bq kg?1). The radium equivalent activities (Req) and the external hazard index (Hex) for the various soil types were also calculated. Some of the soil types were found to have values exceeding the internationally recommended levels of 370 Bq kg?1 and the unity value, respectively. 相似文献
865.
Membranes of chitosan-based proton conductor polymer electrolyte were prepared by dissolving chitosan powder, ammonium nitrate (NH4NO3) salt and ethylene carbonate (EC) plasticizer in acetic acid solution. The temperature dependence of the chitosan-based membrane system was found to obey the Arrhenius relationship. The sample with the highest conductance, 18 wt.% CA + 12 wt.% NH4NO3 + 70 wt.% EC (CA40N70E), also possesses the lowest activation energy. From linear sweep voltammetry (LSV) results, the membrane is electrochemically stable at a potential of 1.6–1.8 V and a temperature of 298–353 K. The cells were fabricated using zinc powder (Zn) + zinc sulfate heptahydrate (ZnSO4·7H2O) + acetylene black (AB) + polytetrafluoroethylene (PTFE)|CA40N70E|manganese (IV) oxide (MnO2) + AB + PTFE. The open circuit voltages of the cells are decreases as temperature increases, the same trend as that obtained by LSV. The cell performance is excellent at 333 K, with discharge capacity of 42.7 mAh, internal resistance of 16.8 Ω, maximum power density of 14.6 mW cm−2 and a short-circuit current density of 31.0 mA cm−2. However, at temperatures above 333 K, decomposition of the membrane degraded the electrochemical properties of the cells. 相似文献
866.
867.
Gas-liquid selective oxidations with oxygen under explosive conditions in a micro-structured reactor
The gas-liquid oxidation of cyclohexane is performed at high temperature (>200 degrees C) and pressure (up to 25 bar) using pure oxygen in a Pyrex capped silicon etched microreactor which allows convenient screen reaction conditions well above the flammability limit. 相似文献
868.
869.
A Mallagaray K Mohammadiannejad-Abbasabadi S Medina G Domínguez J Pérez-Castells 《Organic & biomolecular chemistry》2012,10(33):6665-6672
Cycloisomerization is a totally atom economic procedure which converts dienes and enynes into cyclic molecules. Modification of Grubbs' 2nd generation catalysts by reaction with dimethylformamide provides a new species able to catalyse this transformation. Selection of suitable conditions allowed high yields and selectivity. Studies performed in order to identify the catalytic species point to a non-carbenic ruthenium complex that has lost the phosphine. No hydride signals appeared. In addition, the reaction works with enynes and the new species catalyses efficiently crossed cyclotrimerizations of alkynes with diynes. 相似文献
870.
Y. S. Salim A. Sharon S. Vigneswari M. N. Mohamad Ibrahim A. A. Amirul 《Applied biochemistry and biotechnology》2012,167(2):314-326
This paper investigates the degradation of polyhydroxyalkanoates and its biofiber composites in both soil and lake environment. Time-dependent changes in the weight loss of films were monitored. The rate of degradation of poly(3-hydroxybutyrate) [P(3HB)], poly(3-hydroxybutyrate-co-4-hydroxybutyrate) [P(3HB-co-23?mol% 4HB)] and poly(3-hydroxybutyrate-co-3-hydroxyvalerate-co-4-hydroxybutyrate) [P(3HB-co-9?mol% 3HV-co-19?mol% 4HB)] were investigated. The rate of degradation in the lake is higher compared to that in the soil. The highest rate of degradation in lake environment (15.6?% w/w week?1) was observed with P(3HB-co-3HV-co-4HB) terpolymer. Additionally, the rate of degradation of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) [P(3HB-co-38?mol% 3HV)] was compared to PHBV biofiber composites containing compatibilizers and empty fruit bunch (EFB). Here, composites with 30?% EFB displayed the highest rate of degradation both in the lake (25.6?% w/w week?1) and soil (15.6?% w/w week?1) environment. 相似文献