The effect of solvent ratio and water on the growth of C60 nanowhiskers

The growth of C₆₀ nanowhiskers (C₆₀NWs) prepared by a modified liquid–liquid interfacial precipitation method is investigated, focusing on the effect of solvent ratio and water content in the C₆₀–toluene–isopropyl alcohol (IPA) solution system. The precipitation of C₆₀NWs was markedly influenced by the solvent ratio of toluene to IPA, and the C₆₀NWs were found to grow longer above a critical diameter (D_c), which depends on the solvent ratio. The addition of a small amount of H₂O to the C₆₀–toluene–IPA solution promoted the growth of C₆₀NWs. This catalytic effect of water on the growth of C₆₀NWs was confirmed also by the experiment using heavy water (D₂O) and by the decrease of growth activation energy of C₆₀NWs with increase of H₂O content in the C₆₀–toluene–IPA solution.     

Curdlan as a Polymeric Starting Material to Access C6-Modified Glucose Derivatives

We evaluated the potential of a linear β-1,3-glucan (curdlan) as a starting material to access C6-modified glucose derivatives and found that 6-bromo-6-deoxyglucose, 6-azide-6-deoxyglucose, and 6-acetamido-6-deoxyglucose could be readily prepared from curdlan through its C6-selective and quantitative modifications and subsequent acid-catalyzed hydrolysis.     

Application of copper sulfate pentahydrate as an ammonia removal reagent for the determination of trace impurities in ammonia by gas chromatography

Rapid analysis of trace permanent gas impurities in high purity ammonia gas for the microelectronics industry is described, using a gas chromatograph equipped with a phtoionization detector. Our system incorporates a reactive precolumn in combination with the analytical column to remove the ammonia matrix peak that otherwise would complicate the measurements due to baseline fluctuations and loss of analytes. The performance of 21 precolumn candidate materials was evaluated. Copper sulfate pentahydrate (CuSO₄·5H₂O) was shown to selectively react with ammonia at room temperature and atmospheric column pressures, without affecting the hydrogen, oxygen, nitrogen, methane or carbon monoxide peak areas. To prevent loss of trace carbon dioxide, an additional boron trioxide reactant layer was inserted above the copper sulfate pentahydrate bed in the reactive precolumn. Using the combined materials, calibration curves for carbon dioxide proved to be equivalent in both ammonia and helium matrix gases. These curves were equivalent in both matrix gases. The quantitative performance of the system was also evaluated. Peak repeatabilities, based on eight injections, were in the range of 4.1–8.2% relative standard deviation; and detection limits were 6.9 ppb for H₂, 1.8 ppb for O₂, 1.6 ppb for N₂, 6.4 ppb for CH₄, 13 ppb for CO, and 5.4 ppb for CO₂.     

Light tail asymptotics in multidimensional reflecting processes for queueing networks

We are concerned with the stationary distributions of reflecting processes on multidimensional nonnegative orthants and other related processes, provided they exist. Such stationary distributions arise in performance evaluation for various queueing systems and their networks. However, it is very hard to obtain them analytically, so our interest is directed to analytically tractable characteristics. For this, we consider tail asymptotics of the stationary distributions.     

Remarkable Suppression of [2+2] Cycloaddition during Nonresonant Two-photon Photoreaction of trans-Stilbene in the Presence of Tetramethylethylene

Abstract— Nonresonant two-photon excitation of /rans-stilbene in the presence of an excess amount of tetramethylethylene induced predominantly cis-trans isomerization; the [2+2] intermolecular cycloaddition pathway was remarkably suppressed, in contrast to the one-photon excitation under similar conditions, where the cycloaddition is known to be the major pathway.     

Determination of lipid hydroperoxides in low density lipoprotein from human plasma using high performance liquid chromatography with chemiluminescence detection

A high performance liquid chromatographic system with chemiluminescence detection (HPLC-CL) was used for determining phospholipid hydroperoxides in human plasma low density lipoprotein (LDL). This system involved separation of phospholipids from LDL-total lipids with normal phase silica gel HPLC and post-column detection of hydroperoxide-dependent chemiluminescence produced by luminol oxidation during the reaction of hydroperoxide with cytochrome c-haeme. By using HPLC-CL, we could detect phosphatidylcholine hydroperoxide (PCOOH) in human plasma LDL, and the LDL-PCOOH concentration was significantly higher in patients with atherosclerosis and hyperlipidemia than that of healthy volunteers. The LDL-PCOOH level was proportional to the plasma total cholesterol concentration.     

Decomposability in queues with background states

A symmetric queue is known to have a nice property, the so-called insensitivity. In this paper, we generalize this for a single node queue with Poisson arrivals and background state, which changes at completion instants of lifetimes as well as at the arrival and departure instants. We study this problem by using the decomposability property of the joint stationary distribution of the queue length and supplementary variables, which implies the insensitivity. We formulate a Markov process representing the state of the queue as an RGSMP (reallocatable generalized semi-Markov process), and give necessary and sufficient conditions for the decomposability. We then establish general criteria to be sufficient for the queue to possess the property. Various symmetric-like queues with background states, including continuous time versions of moving server queues, are shown to have the decomposability.This author is partially supported by NEC C&C Laboratories.     

Structure-reversibility and departure functions of queueing networks with batch movements and state dependent routing

We consider characterizations of departure functions in Markovian queueing networks with batch movements and state-dependent routing in discrete-time and in continuous-time. For this purpose, the notion of structure-reversibility is introduced, which means that the time-reversed dynamics of a queueing network corresponds with the same type of queueing network. The notion is useful to derive a traffic equation. We also introduce a multi-source model, which means that there are different types of outside sources, to capture a wider range of applications. Characterizations of the departure functions are obtained for any routing mechanism of customers satisfying a recurrent condition. These results give a unified view to queueing network models with linear traffic equations. Furthermore, they enable us to consider new examples as well as show limited usages of this kind of queueing networks. This revised version was published online in June 2006 with corrections to the Cover Date.     

Copper(II) chloride as a new,efficient additive suppressing racemization in peptide synthesis by the carbodiimide method

Copper(II) chloride was found to be an extremely efficient additive suppressing racemization in the carbodiimide mediated couplings.