全文获取类型
收费全文 | 465篇 |
免费 | 8篇 |
国内免费 | 6篇 |
专业分类
化学 | 248篇 |
晶体学 | 3篇 |
力学 | 28篇 |
数学 | 161篇 |
物理学 | 39篇 |
出版年
2023年 | 2篇 |
2022年 | 9篇 |
2021年 | 15篇 |
2020年 | 12篇 |
2019年 | 6篇 |
2018年 | 16篇 |
2017年 | 10篇 |
2016年 | 24篇 |
2015年 | 12篇 |
2014年 | 17篇 |
2013年 | 45篇 |
2012年 | 29篇 |
2011年 | 25篇 |
2010年 | 24篇 |
2009年 | 36篇 |
2008年 | 21篇 |
2007年 | 16篇 |
2006年 | 16篇 |
2005年 | 25篇 |
2004年 | 19篇 |
2003年 | 15篇 |
2002年 | 18篇 |
2001年 | 7篇 |
2000年 | 9篇 |
1999年 | 2篇 |
1998年 | 5篇 |
1997年 | 2篇 |
1995年 | 2篇 |
1993年 | 2篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 7篇 |
1984年 | 6篇 |
1983年 | 3篇 |
1981年 | 1篇 |
1979年 | 2篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1966年 | 1篇 |
1961年 | 1篇 |
1940年 | 1篇 |
排序方式: 共有479条查询结果,搜索用时 31 毫秒
61.
Danting Yang Nicoleta E. Mircescu Haibo Zhou Nicolae Leopold Vasile Chi Mircea Oltean Yibin Ying Christoph Haisch 《Journal of Raman spectroscopy : JRS》2013,44(11):1491-1496
Ethyl carbamate (EC), a potentially toxic compound, is found in alcoholic beverages and fermented foodstuff. A combined experimental and theoretical study of Raman on EC is reported in this work for the first time. The Raman bands observed for EC in solid phase are characteristic for the carbonyl group, C―C, C―H and N―H stretching and deformation vibrations. These spectral features coupled with a pKa study allowed establishing the neutral species of EC present in the aqueous solutions experimentally tested at different concentrations. In addition, by performing a density functional theory study in the gas phase, the calculated geometry, the harmonic vibrational modes, and the Raman scattering activities of EC were found to be in good agreement with our experimental data and helped establish the surface‐enhanced Raman scattering (SERS) behavior and EC adsorption geometry on the silver surfaces. The Raman peak at 1006 cm−1, assigned to the υs(CC) + ω(CH) modes, the strongest and best reproducible peak in the SERS spectra, was used for a quantitative evaluation of EC. The limit of detection, which corresponds to a signal‐to‐noise ratio equal to 3, was found to be 2 × 10−7 M (17.8 µg l−1). SERS spectra obtained by using hydroxylamine hydrochloride‐reduced silver nanoparticles provide a fast and reproducible qualitative and quantitative determination of EC in aqueous solution. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
62.
63.
Two triphenylamine-based polymers were successfully prepared by the interfacial and microemulsion oxidative polymerization of triphenylamine and 4-(diphenylamino)benzyl 2-bromo-2-methylpropanoate. Ammonium peroxodisulfate ((NH4)2S2O8) was used as a chemical oxidant and dichloromethane/water was used as a solvent. Sodium dodecyl benzene sulfonate was employed as a surfactant in the microemulsion system. Polytriphenylamines were characterized via Fourier transform infrared (FTIR) spectra and 1H-NMR and UV–vis absorption spectroscopy. Molecular weights were determined by gel permeation chromatography and redox properties were studied by cyclic voltammetry. The surface morphology of thin polymer films was determined by atomic force microscopy. 相似文献
64.
65.
Mircea Martin 《Integral Equations and Operator Theory》1998,30(1):101-121
In this article, an approach to joint seminormality based on the theory of Dirac and Laplace operators on Dirac vector bundles is presented. To eachn-tuple of bounded linear operators on a complex Hilbert space we first associate a Dirac bundle furnished with a metric-preserving linear connection defined in terms of thatn-tuple. Employing standard spin geometry techniques we next get a Bochner type and two Bochner-Kodaira type identities in multivariable operator theory. Further, four different classes of jointly seminormal tuples are introduced by imposing semidefiniteness conditions on the remainders in the corresponding Bochner-Kodaira identities. Thus we create a setting in which the classical Bochner's method can be put into action. In effect, we derive some vanishing theorems regarding various spectral sets associated with commuting tuples. In the last part of this article we investigate a rather general concept of seminormality for self-adjoint tuples with an even or odd number of entries. 相似文献
66.
Le Dévédec F Bazinet L Furtos A Venne K Brunet S Mateescu MA 《Journal of chromatography. A》2008,1194(2):165-171
A novel approach for chitosan oligosaccharide (COS) separation by immobilized metal affinity chromatography (IMAC) based on the differences in the interactions of chelated copper (II) ions with various COS (dimers, trimers, tetramers) is described. Polyhydroxylic chromatographic supports (agarose CL-6B and silica) were functionalized with various chelating functions such as iminodiacetate (IDA), carboxymethyl-aspartate (CM-Asp) and tris(carboxymethyl)ethylenediamine (TED). The COS retention capacities of the columns were between 2 and 6 mg/cm(3), depending on the chelating group. The COS were separated and/or enriched up to 95% for dimer and trimer and 90% for the tetramer, with yields of 60-95%. 相似文献
67.
Adhikari D Mossin S Basuli F Dible BR Chipara M Fan H Huffman JC Meyer K Mindiola DJ 《Inorganic chemistry》2008,47(22):10479-10490
One-electron reduction of the square-planar nickel precursor (PNP)NiCl ( 1) (PNP (-) = N[2-P(CHMe 2) 2-4-methylphenyl] 2) with KC 8 effects ligand reorganization of the pincer ligand to assemble a Ni(I) dimer, [Ni(mu 2-PNP)] 2 ( 2), containing a Ni 2N 2 core structure, as inferred by its solid-state X-ray structure. Solution magnetization measurements are consistent with a paramagnetic Ni(I) system likely undergoing a monomer <--> dimer equilibrium. The room-temperature and 4 K solid-state X-band electron paramagnetic resonance (EPR) spectra display anisotropic signals. Low-temperature solid-state X-band EPR data at 4 K reveal rhombic values g z = 1.980(4), g x = 2. 380(4), and g y = 2.225(4), as well as a forbidden signal at g = 4.24 for the Delta M S = 2 half field transition, in accord with 2 having two weakly interacting metal centers. Utilizing an S = 1 model, full spin Hamiltonian simulation of the low-temperature EPR spectrum on the solid sample was achieved by applying a nonzero zero-field-splitting parameter ( D = 0.001 cm (-1)), which is consistent with an S = 0 ground state with a very closely lying S = 1 state. Solid-state magnetization data also corroborate well with our solid-state EPR data and reveal weak antiferromagnetic behavior ( J = -1.52(5) cm (-1)) over a 2-300 K temperature range at a field of 1 Tesla. Evidence for 2 being a masked "(PNP)Ni" scaffold originates from its reaction with N 2CPh 2, which traps the Ni(I) monomer in the form of a T-shaped species, Ni(PNPNNCPh 2), a system that has been structurally characterized. The radical nature of complex 2, or its monomer component, is well manifested through the plethora of cooperative H-X-type bond cleavage reactions, providing the nickel(II) hydride (PNP)NiH and the corresponding rare functionalities -OH, -OCH 3, -PHPh, and -B(catechol) integrated into the (PNP)Ni moiety in equal molar amounts. In addition to splitting H 2, compound 2 can also engage in homolytic X-X bond cleavage reactions of PhXXPh to form (PNP)Ni(XPh) (X = S or Se). 相似文献
68.
Aurelia Pascariu Mircea Mracec Stefan Berger 《International journal of quantum chemistry》2008,108(6):1052-1058
Dynamic NMR spectroscopy at very low temperatures (148–182 K) reveal the dynamic behavior of the (2‐tri(3‐furyl)‐3‐methyl‐4‐cyclopropenyl‐oxaphosphetane) generated during a Wittig reaction between tri(3‐furyl)ethylphosphonium iodine and cyclopropylaldehyde. The possibility of formation of different adducts between Li+ ions and oxaphosphetane or betainic intermediates was checked calculating the formation enthalpies using the MNDO, AM1, and PM3 semiempirical MO methods. The observed species are interpreted as oxaphosphetane complexes with lithium ions present in solution. Quantum mechanical calculations confirm the spectroscopic results. © 2008 Wiley Periodicals, Inc. Int J Quantum Chem, 2008 相似文献
69.
Mircea Merca 《Quaestiones Mathematicae》2016,39(4):457-469
In this paper, we prove that the Stirling numbers of both kinds can be written as sums over integer partitions. As corollaries, we rewrite some identities with Stirling numbers of both kinds without Stirling numbers. 相似文献
70.
Ramona F. Curpăn Liliana Halip Ana Borota Maria Mracec Mircea Mracec 《Structural chemistry》2016,27(3):871-881
Dexmedetomidine (4-[(S)-1-(2,3-dimethyl-phenyl)-ethyl]-1H-imidazole), Dex, is potent agonist acting on α2-adrenergic receptors (α2-ARs). It can exist at the physiological pH in both forms: neutral and protonated. The results of receptor-independent and receptor-dependent studies applied to both forms of Dex are reported. A conformational analysis with PM3 semiempirical MO and ab initio HF/6-31G* methods was carried out for both forms of Dex. The calculated geometries of low-energy conformers of Dex were compared with X-ray geometry and those of conformers resulted from molecular docking of Dex in the binding pockets of 3D homology models of the α2A-, α2B-, and α2C-adrenoceptor subtypes. A MM/QM (molecular mechanics/quantum mechanics) docking study was performed to refine and optimize receptor–ligand complex and close contacts between the ligand and amino acids lining the binding cavity. Two-dimensional potential energy surface and docking results suggest that the imidazole ring can easily adopt the best orientation for an efficient interaction with the carboxylate group of Asp3.32 from the binding cavity of alpha2 adrenergic receptor subtypes. 相似文献