全文获取类型
收费全文 | 2079篇 |
免费 | 43篇 |
国内免费 | 8篇 |
专业分类
化学 | 1668篇 |
晶体学 | 29篇 |
力学 | 19篇 |
综合类 | 1篇 |
数学 | 108篇 |
物理学 | 305篇 |
出版年
2021年 | 15篇 |
2020年 | 16篇 |
2019年 | 29篇 |
2018年 | 15篇 |
2017年 | 19篇 |
2016年 | 21篇 |
2015年 | 33篇 |
2014年 | 41篇 |
2013年 | 127篇 |
2012年 | 58篇 |
2011年 | 98篇 |
2010年 | 52篇 |
2009年 | 64篇 |
2008年 | 103篇 |
2007年 | 118篇 |
2006年 | 108篇 |
2005年 | 104篇 |
2004年 | 118篇 |
2003年 | 93篇 |
2002年 | 83篇 |
2001年 | 51篇 |
2000年 | 33篇 |
1999年 | 21篇 |
1998年 | 36篇 |
1997年 | 30篇 |
1996年 | 25篇 |
1995年 | 20篇 |
1994年 | 15篇 |
1993年 | 15篇 |
1992年 | 17篇 |
1991年 | 24篇 |
1990年 | 25篇 |
1989年 | 15篇 |
1988年 | 32篇 |
1987年 | 19篇 |
1986年 | 15篇 |
1985年 | 31篇 |
1984年 | 41篇 |
1983年 | 22篇 |
1982年 | 29篇 |
1981年 | 33篇 |
1980年 | 32篇 |
1979年 | 26篇 |
1978年 | 25篇 |
1977年 | 26篇 |
1976年 | 23篇 |
1975年 | 14篇 |
1974年 | 18篇 |
1973年 | 14篇 |
1967年 | 10篇 |
排序方式: 共有2130条查询结果,搜索用时 15 毫秒
1.
Yoshiaki Murata Cheng-Huang Lin Totaro Imasaka 《Fresenius' Journal of Analytical Chemistry》1993,346(6-9):543-544
Summary A supersonic jet spectrum of 9,10-dichloroanthracene is measured by stimulated-emission-pumping fluorescence dip spectrometry and conventional fluorescence spectrometry. The performance obtained is compared for these spectrometric methods, providing same information concerned with the energy level of the ground state. The former is more preferential for measurement of a high-resolution spectrum, since the spectral resolution is determined by the linewidth of the dumping laser. On the other hand, the latter is more preferential for measurement with better sensitivity at the expense of the spectral resolution, since the fluorescence throughput can be improved by increasing the slit width of the monochromator.Dedicated to Professor Dr. Wilhelm Fresenius on the occasion of his 80th birthday 相似文献
2.
Yasushi Seike Ryoko Fukumori Yukiko Senga Hiroki Oka Kaoru Fujinaga Minoru Okumura 《Analytical sciences》2004,20(1):139-142
A new and simple method for the determination of hydroxylamine in environmental water, such as fresh rivers and lakes using hypochlorite, followed by its gas choromatographic detection, has been developed. A glass vial filled with sample water was sealed by a butyl-rubber stopper and aluminum cap without head-space, and then sodium hypochlorite solution was injected into the vial through a syringe to convert hydroxylamine to nitrous oxide. The head-space in the glass vial was prepared with 99.9% grade N2 using a gas-tight syringe. After the glass vial was shaken for a few minutes, nitrous oxide in the gas-phase was measured by a gas chromatograph with an electron-capture detector. The dissolved nitrous oxide in the liquid-phase was calculated according to the solubility formula. The proposed method was applied to the analysis of fresh-water samples taken from Iu river and Hii river, flowing into brackish Lakes Nakaumi and Shinji, respectively. 相似文献
3.
4.
Minoru Murata 《Journal of Functional Analysis》2002,194(1):53-141
We consider positive solutions of elliptic partial differential equations on non-compact domains of Riemannian manifolds. We explicitly determine Martin boundaries and Martin kernels for a class of elliptic equations in skew product form by exploiting and developing perturbation theory for elliptic equations and short/long-time estimates for fundamental solutions of parabolic equations. 相似文献
5.
6.
Minoru Murata 《Journal of Functional Analysis》2007,245(1):177-212
We consider nonnegative solutions of a parabolic equation in a cylinder D×(0,T), where D is a noncompact domain of a Riemannian manifold. Under the assumption [IU] (i.e., the associated heat kernel is intrinsically ultracontractive), we establish an integral representation theorem: any nonnegative solution is represented uniquely by an integral on (D×{0})∪(M∂D×[0,T)), where M∂D is the Martin boundary of D for the associated elliptic operator. We apply it in a unified way to several concrete examples to explicitly represent nonnegative solutions. We also show that [IU] implies the condition [SP] (i.e., the constant function 1 is a small perturbation of the elliptic operator on D). 相似文献
7.
Minoru Wakimoto 《Communications in Mathematical Physics》1986,104(4):605-609
The aim of this note is to show that the affine Lie algebraA
1
(1)
has a natural family , ,v of Fock representations on the spaceC[x
i,y
j;i andj ], parametrized by (,v) C
2. By corresponding the highest weight
, of , to each (,), the parameter spaceC
2 forms a double cover of the weight spaceC0C –1 with singularities at linear forms of level –2; this number is (–1)-times the dual Coxeter number. Our results contain explicit realizations of irreducible non-integrable highest wieghtA
1
(1)
-modules for generic (,v). 相似文献
8.
Summary 3-Hydroxychromone reacts with tin(IV) to produce 11 complex in a weakly acidic-neutral medium. The complex exhibits intense fluorescence. A sensitive method is described for the fluorometric determination of tin(IV) with 3-hydroxychromone. The calibration graph is linear in the range of 0.4–8.0g/25 ml of tin(IV) (pH 4.5–5.0, Excitation wavelength: 365 nm, Measured total fluorescence). Chloride which generally decreases the fluorescence intensity in the fluorometric determination of tin can be tolerated at 300-mg level.
Fluorometrische Bestimmung von Zinn(IV) mit 3-Hydroxychromon
Zusammenfassung 3-Hydroxychromon reagiert mit Zinn(IV) in schwach saurem bis neutralem Medium unter Bildung eines 11-Komplexes. Dieser fluoresziert intensiv. Ein empfindliches Verfahren zur Bestimmung von Sn(IV) auf dieser Grundlage wurde ausgearbeitet. Die Eichkurve verläuft in dem Gebiet zwischen 0,4 und 8,0g Sn/25 ml bei pH 4,5, einer Wellenlänge von 365 nm und bei Messung der Gesamtfluoreszenz geradlinig. Chloride, die die Fluoreszenzintensität bei Zinnbestimmungen im allgemeinen herabsetzen, können bis zu 300 mg toleriert werden.相似文献
9.
Treatment of aliphatic aldehyde with lithium pentamethylcyclopentadienide in the presence of chlorodimethylaluminum provided the corresponding carbinol in excellent yield. The carbinol returns to the parent aldehyde and pentamethylcyclopentadiene by the action of a catalytic amount of 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ). 相似文献
10.
Tsutomu Oishi Kensoh Kagawa Minoru Fujimoto 《Journal of polymer science. Part A, Polymer chemistry》1995,33(8):1341-1352
Two types of optically active N-[N′-(α-methylbenzyl)amino/carbonyl-n-alkyl]maleimides (MBAC) were synthesized from maleic anhydride, 6-amino-n-caproic acid (or 12-amino-n-dodecanoic acid), and (R)-(+)-α-methylbenzylamine. Radical homopolymerizations of MBAC were performed in several solvents at 60 and 110°C for 24 h to give optically active polymers. Radical copolymerizations of MBAC were performed with styrene (ST) and methyl methacrylate (MMA) in dioxane at 60°C. The monomer reactivity ratios and the Alfrey-Price Q-e values were determined. Chiroptical properties of the polymers and copolymers were investigated. © 1995 John Wiley & Sons, Inc. 相似文献