Surfactant-free hydrothermal synthesis of?submicron?BiFeO3?powders

Submicron BiFeO₃ powders were successfully synthesized via a simple hydrothermal process with the assistance of mineralizer (NaOH) at 150–190°C, using FeCl₃ and Bi(NO₃)₃⋅5H₂O as reactants. The effects of mineralizer concentration, reaction temperature and time on the phase evolution and crystal morphology of the resulting samples were investigated. X-ray diffraction (XRD), transmission electron microscopy (TEM), thermogravimetry and differential scanning calorimetry (TG-DSC), and vibrating sample magnetometry (VSM) were used to characterize the as-synthesized samples. The experimental results revealed that a pure BiFeO₃ phase could be formed at a temperature ranging from 170 to 190°C for 4–20 h in the presence of 0.03–0.12 M NaOH. It was found that the mineralizer concentration, reaction temperature and time played a key role in controlling the growing speed of nuclei and formation of BiFeO₃ crystallites. The possible formation mechanisms of submicron BiFeO₃ powders with different morphologies were presented. The magnetization of BiFeO₃ powders showed a weak ferromagnetic behavior at room temperature.     

基于波数均匀展宽模型的全反射傅里叶变换成像光谱仪高精度光谱定标处理方法

全反射傅里叶变换成像光谱仪ARFTIS(all-reflection Fourier transform imaging spectrometer)是基于FT成像光谱理论的一种新型仪器,它不但具有高光谱分辨率特点,而且还具有宽波段、无色差的特点,特别适合应用在宽波段成像的遥感领域.目前常用的光谱定标方法有单色法、平均法...     

基于小波变换和高斯拟合的在线谱图综合处理方法

微小型移动式现场在线检测技术是分析仪器发展的新领域。针对复杂工作环境中谱图存在强噪声干扰、谱峰重叠、不规则峰形等严重影响仪器的定性和定量准确度的瓶颈技术,提出了一种基于小波变换和高斯拟合相结合的谱图在线综合处理方法,用自研的仪器对甲苯和全氟三丁胺两种典型化合物的谱图进行了处理,并与实验室分析仪器普遍应用的算法进行了对比分析。结果表明,综合方法能够有效解决强噪声干扰、谱峰重叠、不规则峰形问题,提高仪器的定性和定量准确性,同时能够实现数据压缩,满足仪器的在线实时检测要求。综合方法处理甲苯特征峰的平均信噪比(SNR)较移动平滑方法提高了1.3倍,峰位误差ΔM降低了3.6倍,处理全氟三丁胺谱图的数据压缩比为197∶1。     

资料同化中的数字滤波弱约束试验及分析

气象数值预报中,由于分析过程引入初始非平衡,从而引起虚假快波振荡,重力波控制弱约束把资料分析过程和初始化过程结合在一起,通过数字滤波弱约束在极小化过程中实现对分析场的平衡约束,克服非平衡问题. 以2008年初的一次南方雨雪天气为研究个例,进行了数字滤波弱约束的同化试验和预报试验,结果表明,数字滤波弱约束4D-Var能充分控制快波振荡的出现和初始调整现象,使得到的分析场不仅能更好的逼近观测,而且能更好地与模式动力相协调. 预报检验的结果表明,在同化过程中施加数字滤波弱约束,能有效滤除由于地形或观测资料等因素 关键词： 变分同化 初始非平衡 数字滤波 弱约束     

NaLa(MoO4)2∶Eu3+的水热调控合成与发光特性研究

采用水热法合成了不同粒径的NaLa(MoO₄)₂∶Eu³⁺微晶.通过调节乙二醇浓度和反应时间,研究了NaLa(MoO₄)₂∶Eu³⁺微晶的形貌演变过程,在水热条件下180 ℃反应16 h获得了均一梭子形NaLa(MoO₄)₂∶Eu³⁺微晶,其晶粒长度约为2.0 μm.荧光光谱分析表明,Eu³⁺取代了NaLa(MoO₄)₂中La³⁺的格位, Eu³⁺在613 nm处红光发射(⁵D₀–⁷F₂跃迁)的浓度猝灭机理是电偶极-电四极相互作用,并发生了Eu³⁺( ⁵D₁ ) + Eu³⁺(⁷F₀ )→ Eu³⁺( ⁵D₀ ) + Eu³⁺(⁷F₃) 交叉弛豫,由此导致浓度猝灭. 关键词： 钼酸盐 水热法 稀土离子 发光     

散射体排列方式对二维磁振子晶体带隙结构的影响

本文采用平面波展开法数值计算了由铁圆柱分别按正方排列、三角排列以及六角排列在氧化铕基底材料中构成的二维磁振子晶体带结构,讨论了散射体的不同排列方式对磁振子晶体带隙结构的影响.计算结果表明,三角排列散射体的磁振子晶体能够获得最大的自旋波带隙结构. 关键词： 磁振子晶体 带隙 排列方式     

输入方波信号的过阻尼谐振子的随机共振

计算了在输入方波信号情况下过阻尼谐振子的输出功率谱和信噪比,详细讨论了相应的随机共振现象,并与输入余弦信号情况进行对比.研究发现:它们均出现随机共振现象,且均存在共振和抑制并存的现象.但这一并存现象,在两模型中分别出现于不同的共振曲线. 关键词： 过阻尼谐振子 随机共振 方波信号     

具有频率噪声的单模激光线性模型随机共振

将频率有涨落的周期信号输入单模激光增益模型,计算出输出光强的相关函数及功率谱,对信噪比随噪声强度和系统参数的变化进行了研究. 结果表明:信噪比随频率噪声强度的变化、抽运噪声强度的变化、量子噪声强度的变化均出现随机共振;信噪比随增益系数和损失系数的变化也出现随机共振. 关键词： 频率噪声 功率谱 随机共振     

Observable T7 lepton flavor symmetry at the Large Hadron Collider

More often than not, models of flavor symmetry rely on the use of nonrenormalizable operators (in the guise of flavons) to accomplish the phenomenologically successful tribimaximal mixing of neutrinos. We show instead how a simple renormalizable two-parameter neutrino mass model of tribimaximal mixing can be constructed with the non-Abelian discrete symmetry T(7) and the gauging of B-L. This is also achieved without the addition of auxiliary symmetries and particles present in almost all other proposals. Most importantly, it is verifiable at the Large Hadron Collider.     

Graphite nanosheets doped with Fe, Ni, and N, synthesized in one step, and their unique magnetic performance

Graphite nanosheets (GNs) doped with N, Fe, or Ni were synthesized by pyrolysis of metal tetrapyridinoporphyrazine (MPTpz, M=Fe²⁺, and Ni²⁺) and a mixture of MPTpzs in a chemical vapor deposition furnace. The products obtained were characterized by scanning and transmission electron microscopy, and X-ray photoelectron spectroscopy. The magnetic properties of the GNs obtained were investigated at room temperature using a vibrating sample magnetometer with an applied field of −10 000-10 000 Gs. The results show the GNs obtained are terrace-like and ultra-thin, with very high aspect ratio. Fe, Ni and N atoms have been doped to the GNs successfully. There are two types of N atom that are introduced into pure carbon systems: pyrinidic and graphitic N atoms. The GNs obtained exhibit ferromagnetic behavior at room temperature. Sample S1, obtained by pyrolysis of a mixture of MPTpzs (M=Fe²⁺ and Ni²⁺), have the highest coercivity force. The saturation magnetization (M_s), remanent magnetization (M_r), and coercivity (H_c) values of sample S1 are 24.51 emu g⁻¹, 3.95 emu g⁻¹, and 207.34 Gs, respectively.