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101.
Pham Anh Minh 《Proceedings of the American Mathematical Society》2002,130(2):307-310
The purpose of this note is to provide a -group whose mod-3 cohomology ring has a nilpotent element satisfying .
102.
We describe the details of an experiment using an atomic beam of rubidium which allowed us to detect by field ionization techniques the np Rydberg states from n = 28 up to n = 78, to detect also ns and nd states using a Stark mixing, and for all of these detected states to check the classical law Ec = [16n*4]?1 concerning the critical ionizing electric field Ec. It turns out that for n as high as 65 this law is quite well verified. 相似文献
103.
104.
Bendikov M Duong HM Starkey K Houk KN Carter EA Wudl F 《Journal of the American Chemical Society》2004,126(24):7416-7417
A series of oligoacenes from benzene to decacene were studied computationally with DFT and CASSCF methods. In contrast to the common view that acenes are closed-shell systems or may have a triplet ground state, these results offer the first theoretical predictions for the singlet ground state and diradical character for oligoacenes. The nature of the ground states of these molecules arises from the disjoint nature of the NBMOs that are singly occupied in the diradical. 相似文献
105.
The experimental charge density distribution of dimethyl-trans-2-oxohexahydro-pyrimidine-4,6-dicarboxylate 1 has been determined using single-crystal X-ray diffraction data measured at 100 K, in terms of the rigid-pseudoatom formalism. Multipole refinement converged at R(F) = 0.034 for 7283 reflections with I > 3 sigma (I) and sin theta/lambda < or = 1.13 A(-1). Covalent and hydrogen bonding interactions are analyzed using a topological analysis of the Laplacian of the charge density. The experimentally derived electrostatic potential mapped onto the reactive surface of the molecule reveals the potential binding sites of 1. 相似文献
106.
This paper is concerned with the existence, smoothness and attractivity of invariant manifolds for evolutionary processes on general Banach spaces when the nonlinear perturbation has a small global Lipschitz constant and locally Ck-smooth near the trivial solution. Such a nonlinear perturbation arises in many applications through the usual cut-off procedure, but the requirement in the existing literature that the nonlinear perturbation is globally Ck-smooth and has a globally small Lipschitz constant is hardly met in those systems for which the phase space does not allow a smooth cut-off function. Our general results are illustrated by and applied to partial functional differential equations for which the phase space (where r>0 and being a Banach space) has no smooth inner product structure and for which the validity of variation-of-constants formula is still an interesting open problem. 相似文献
107.
Photoexcitation of antiferromagnetic NiO leads to ultrafast reorientation of Ni2+ spins due to change of the magnetic anisotropy. Recovery of the magnetic ground state occurs as coherent oscillation of the antiferromagnetic order parameter between hard- and easy-axis states manifesting itself as quantum beating. The coherence time is approximately 1 ns with the beating frequency being determined by the anisotropy energy. 相似文献
108.
We report the spontaneous emergence of a doubly periodic train of sedimented knolls in a dense suspension. These solidified knolls rise out of, and coexist alongside, a sea of freely flowing liquid in a slowly rotating horizontal bottle. We apply a variable viscosity model that permits simultaneous analysis of fluidlike and solidlike behaviors that are ubiquitous in a variety of sedimenting flows. The model generates qualitative agreement with experiments, and produces new insights into mechanisms by which sedimented structures form. 相似文献
109.
Skidmore MA Patey SJ Thanh NT Fernig DG Turnbull JE Yates EA 《Chemical communications (Cambridge, England)》2004,(23):2700-2701
Glycosaminoglycan oligosaccharides have been attached to thiol-derivatised gold surfaces, via the formation of mercury-sugar adducts at the non-reducing end, representing a new method of generating versatile glycoconjugates incorporating this class of biologically and medically important carbohydrate. 相似文献
110.
N-heterocyclic carbenes as highly efficient catalysts for the cyclotrimerization of isocyanates 总被引:2,自引:0,他引:2
[reaction: see text] A series of N-heterocyclic carbenes (NHCs) were evaluated as potential catalysts for the cyclotrimerization of isocyanates to afford isocyanurates. 1,3-Bis-(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene (SIPr) was found to be a highly efficient catalyst for the cyclotrimerization of a variety of isocyanates. 相似文献