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排序方式: 共有542条查询结果,搜索用时 15 毫秒
101.
Maryam Sadat Hosseini-ZareMohammad Mahdavi Mina SaeediMehdi Asadi Shahrzad JavanshirAbbas Shafiee Alireza Foroumadi 《Tetrahedron letters》2012,53(27):3448-3451
We describe a new one-pot synthesis of 2,3-diaryl-5H-imidazo[2,1-a]isoindol-5-ones via the reaction of 1,2-diketones, 2-formylbenzoic acids, and ammonium acetate in acetic acid under reflux conditions and in the absence of a catalyst. 相似文献
102.
Mohammad Ali Rasouli Mohammad Mahdavi Parviz Rashidi Ranjbar Mina Saeedi Abbas Shafiee Alireza Foroumadi 《Tetrahedron letters》2012,53(52):7088-7092
This work describes a green and efficient one-pot synthesis of N-alkyl-2-(2-oxoazepan-1-yl)-2-arylacetamide derivatives via an Ugi four-center, three-component reaction of 6-aminohexanoic acid, aromatic aldehydes, and isocyanide derivatives in water under reflux conditions in the absence of a catalyst. 相似文献
103.
The rational design of small building block molecules and understanding their molecular assemblies are of fundamental importance in creating new stimuli-responsive organic architectures with desired shapes and functions. Based on the experimental results of light-induced conformational changes of four types of triangular azo dyes with different terminal functional groups, as well as absorption and fluorescence characteristics associated with their molecular assemblies, we report that aggregation-active emission enhancement (AIEE)-active compound (1) substituted with sterically crowded tert-butyl (t-Bu) groups showed approximately 35% light-induced molecular switching and had a strong tendency to assemble into highly stable hexagonal structures with AIEE characteristics. Their sizes were regulated from nanometer-scale hexagonal rods to micrometer-scale sticks depending on the concentration. This is in contrast to other triangular compounds with bromo (Br) and triphenylamine (TPA) substituents, which exhibited no photoisomerization and tended to form flexible fibrous structures. Moreover, non-contact exposure of the fluorescent hexagonal nanorods to ultraviolet (UV) light led to a dramatic hexagonal-to-amorphous structure transition. The resulting remarkable variations, such as in the contrast of microscopic images and fluorescence characteristics, were confirmed by various microscopic and spectroscopic measurements. 相似文献
104.
Xiaohui Duan Mina Zhang Huan Du Xiu Gu Caihong Bai Liuqiang Zhang Kaixian Chen Kaifeng Hu Yiming Li 《Molecules (Basel, Switzerland)》2022,27(15)
Scrophulariae Radix (SR) is one of the oldest and most frequently used Chinese herbs for oriental medicine in China. Before clinical use, the SR should be processed using different methods after harvest, such as steaming, “sweating”, and traditional fire-drying. In order to investigate the difference in chemical constituents using different processing methods, the two-dimensional (2D) 1H-13C heteronuclear single quantum correlation (1H-13C HSQC)-based metabolomics approach was applied to extensively characterize the difference in the chemical components in the extracts of SR processed using different processing methods. In total, 20 compounds were identified as potential chemical markers that changed significantly with different steaming durations. Seven compounds can be used as potential chemical markers to differentiate processing by sweating, hot-air drying, and steaming for 4 h. These findings could elucidate the change of chemical constituents of the processed SR and provide a guide for the processing. In addition, our protocol may represent a general approach to characterizing chemical compounds of traditional Chinese medicine (TCM) and therefore might be considered as a promising approach to exploring the scientific basis of traditional processing of TCM. 相似文献
105.
Lab-on-a-chip (LOC) technologies can take advantage of sheath flows for particle/cell focusing before sensing or sorting. The integration of focusing with other microscale manipulation techniques (e.g., sorting) creates a trade-off between the throughput of the device and its performance. Therefore, exploring the effective parameters for cells/particles focusing enables us to improve the desired output of LOC devices. A common configuration for sheath-assisted focusing is Y junctions, which are parametrically studied in this paper. First, a computational model was developed and validated by comparing it with our experimental results. Using COMSOL Multiphysics modeling, the effects of multiple parameters were studied. These parameters include the sheath flow ratio (sheath flow over total flow), width ratio (width of the sheath inlet over the total width), junction angles, and particle size on the focusing width and the distribution of the particles within the focusing region. Then, the numerical data were used to develop two generalized linear models to predict the focusing width of the particles and the standard deviation of the position of the particles. The results showed that the focusing width is greatly impacted by the sheath flow rate ratio. Further, the standard deviation of the position of the particles, which represents the concentration of the particles, is mostly dependent on the flow rate ratio, width ratio, and particle size. Our results provide a better understanding of how the device geometrical and operational factors affect the position of the particles in the development of high-performance on-chip sensing and sorting of both cells and particles. 相似文献
106.
This paper is the first in a series of three papers concerning the surface T×T. Here we study the degeneration of T×T and the regeneration of its degenerated object. We also study the braid monodromy and its regeneration. 相似文献
107.
H. Teicher 《Probability Theory and Related Fields》1988,79(2):303-316
Summary If
where {X
n j
,ℱ
n j
1≦j≦m
n
↑∞, n≧1} is a martingale difference array, conditions are given for the distribution and moment convergence of S
n,k
to the distribution and moments of
where H
k
is the Hermite polynomial of degree k and Z is a standard normal variable. This is intimately related to an identity (*) for multiple Wiener integrals. Under alternative
conditions, similar results hold for S
n, k
/U
n
k
and S
n, k
/V
n
k
where
and V
n
2
V
n
2
is the conditional variance.
Research supported by the National Science Foundation under Grant DMS-8601346 相似文献
108.
Henry Teicher 《Journal of Theoretical Probability》1995,8(4):779-793
Conditions are obtained for (*)E|S
T
|γ<∞, γ>2 whereT is a stopping time and {S
n=∑
1
n
,X
j
ℱ
n
,n⩾1} is a martingale and these ensure when (**)X
n
,n≥1 are independent, mean zero random variables that (*) holds wheneverET
γ/2<∞, sup
n≥1
E|X
n
|γ<∞. This, in turn, is applied to obtain conditions for the validity ofE|S
k,T
|γ<∞ and of the second moment equationES
k,T
2
=σ
2
EΣ
j=k
T
S
k−1,j−1
2
where
and {X
n
, n≥1} satisfies (**) and
,n≥1. The latter is utilized to elicit information about a moment of a stopping rule. It is also shown for i.i.d. {X
n
, n≥1} withEX=0,EX
2=1 that the a.s. limit set of {(n log logn)−k/2
S
k,n
,n≥k} is [0,2
k/2/k!] or [−2
k/2/k!] according ask is even or odd and this can readily be reformulated in terms of the corresponding (degenerate kernel)U-statistic
. 相似文献
109.
Yoshiyuki Oishi Mina Ishida Masa-Aki Kakimoto Yoshio Imai Toshikazu Kurosaki 《Journal of polymer science. Part A, Polymer chemistry》1992,30(6):1027-1035
New aromatic polyimides containing triphenylamine unit were prepared by two different methods, i.e., a conventional two-step method starting from 4,4′-diaminotriphenylamine and aromatic tetracarboxylic dianhydrides and the one-step thioanhydride method starting from the aromatic diamine and aromatic tetracarboxylic dithioanhydrides. Both procedures yielded high-molecular-weight polyimides with inherent viscosities of 0.47–1.17 dL/g. Some of these polymers were soluble in organic solvents such as N,N-dimethylacetamide, N-methyl-2-pyrrolidone, m-cresol, and pyridine. All the polyimides afforded transparent, flexible, and tough films, and the color varied from pale yellow to dark red, depending markedly on the tetracarboxylic acid components. The glass transition temperatures (Tgs) of these polyimides were in the range of 287–331°C and the 10% weight loss temperatures were above 520°C in air. The polyimides prepared by the one-step method exhibited better solubility in organic solvents and had somewhat lower Tgs than the polymers prepared by a conventional two-step method. 相似文献
110.
Guey‐Sheng Liou Sheng‐Huei Hsiao Mina Ishida Masaaki Kakimoto Yoshio Imai 《Journal of polymer science. Part A, Polymer chemistry》2002,40(16):2810-2818
A new triphenylamine‐containing aromatic diamine, N, N′‐bis(4‐aminophenyl)‐N, N′‐diphenyl‐1,4‐phenylenediamine, was prepared by the condensation of N,N′‐diphenyl‐1,4‐phenylenediamine with 4‐fluoronitrobenzene, followed by catalytic reduction. A series of novel aromatic polyamides with triphenylamine units were prepared from the diamine and various aromatic dicarboxylic acids or their diacid chlorides via the direct phosphorylation polycondensation or low‐temperature solution polycondensation. All the polyamides were amorphous and readily soluble in many organic solvents such as N, N‐dimethylacetamide and N‐methyl‐2‐pyrrolidone. These polymers could be solution cast into transparent, tough, and flexible films with good mechanical properties. They had useful levels of thermal stability associated with relatively high glass‐transition temperatures (257–287 °C), 10% weight‐loss temperatures in excess of 550 °C, and char yields at 800 °C in nitrogen higher than 72%. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 2810–2818, 2002 相似文献