Highly polarized dithiafulvenes: synthesis and nonlinear optical properties

Push-pull dithiafulvenes with reduced bond length alternation (BLA) and high optical nonlinearities have been prepared. The interplay between the proaromaticity of the donor and the structural and optical properties of these merocyanines is discussed. The donor ability of dithiafulvenes can reach that of ferrocene or dialkylaminophenyl groups.     

Order Embeddings with Irrational Codomain: Debreu Properties of Real Subsets

The objective of this paper is to investigate the role of the set of irrational numbers as the codomain of order-preserving functions defined on topological totally preordered sets. We will show that although the set of irrational numbers does not satisfy the Debreu property it is still nonetheless true that any lower (respectively, upper) semicontinuous total preorder representable by a real-valued strictly isotone function (semicontinuous or not) also admits a representation by means of a lower (respectively, upper) semicontinuous strictly isotone function that takes values in the set of irrational numbers. These results are obtained by means of a direct construction. Moreover, they can be related to Cantor’s characterization of the real line to obtain much more general results on the semicontinuous Debreu properties of a wide family of subsets of the real line.      

The Polyakov path integral over bordered surfaces

Following the general scheme of the convariant path integral quantization of gauge systems, two alternative formulations of the first quantized closed bosonic string in a position representation are presented. In both approaches the covariant path integral representations of the propagator and of the higher order off-shell amplitudes are constructed. For a wide class of gauges the explicit formulae for off-shell amplitudes are obtained. This paper is the continuation of our previous work where the corresponding problems in the open string case were considered [20].     

On bulk-service MAP/PH L,N /1/N G-Queues with repeated attempts

We consider a retrial queue with a finite buffer of size N, with arrivals of ordinary units and of negative units (which cancel one ordinary unit), both assumed to be Markovian arrival processes. The service requirements are of phase type. In addition, a PH^L,N bulk service discipline is assumed. This means that the units are served in groups of size at least L, where 1≤ L≤ N. If at the completion of a service fewer than L units are present at the buffer, the server switches off and waits until the buffer length reaches the threshold L. Then it switches on and initiates service for such a group of units. On the contrary, if at the completion of a service L or more units are present at the buffer, all units enter service as a group. Units arriving when the buffer is full are not lost, but they join a group of unsatisfied units called “orbit”. Our interest is in the continuous-time Markov chain describing the state of the queue at arbitrary times, which constitutes a level dependent quasi-birth-and-death process. We start by analyzing a simplified version of our queueing model, which is amenable to numerical calculation and is based on spatially homogeneous quasi-birth-and-death processes. This leads to modified matrix-geometric formulas that reveal the basic qualitative properties of our algorithmic approach for computing performance measures. AMS Subject Classification: Primary 60K25 Secondary 68M20 90B22.     

Velocity Quantization Approach of the One-Dimensional Dissipative Harmonic Oscillator

Given a constant of motion for the one-dimensional harmonic oscillator with linear dissipation in the velocity, the problem to get the Hamiltonian for this system is pointed out, and the quantization up to second order in the perturbation approach is used to determine the modification on the eigenvalues when dissipation is taken into consideration. This quantization is realized using the constant of motion instead of the Hamiltonian. PACS: 03.20.+i, 03.30.+p, 03.65.−w,03.65.Ca     

More compact invariant manifolds appearing in the non-linear coupling of oscillators

Near partially elliptic rest points of generic families of vector fields or transformations, many types of normally hyperbolic invariant compact manifolds can appear, diffeomorphic to intersections of quadrics. To cite this article: M. Chaperon et al., C. R. Acad. Sci. Paris, Ser. I 342 (2006).     

On the polarization of non-paraxial transverse fields

On the basis of a plane-wave spectrum representation, the polarization features of a transverse quasimonochromatic non-paraxial field have been studied. A relationship has been established between the polarization characteristics in the near field and the coherence and symmetry properties of the beam in the far field.     

A high-current electron beam ion trap as an on-line charge breeder for the high precision mass measurement TITAN experiment

The precision of atomic mass measurements in a Penning trap is directly proportional to the charge state q of the ion and, hence, can be increased by using highly charged ions (HCI). For this reason, charge breeding with an electron beam ion trap (EBIT) is employed at TRIUMF’s Ion Trap for Atomic and Nuclear science (TITAN) on-line facility in Vancouver, Canada. By bombarding the injected and trapped singly charged ions with an intense beam of electrons, the charge state of the ions is rapidly increased inside the EBIT. To be compatible with the on-line requirements of short-lived isotopes, very high electron beam current densities are needed. The TITAN EBIT includes a 6 Tesla superconducting magnet and is designed to have electron beam currents and energies of up to 5 A and 60 keV, respectively. Once operational at full capacity, most species can be bred into a He-like configuration within tens of ms. Subsequently, the HCI are extracted, pass a Wien filter to reduce isobaric contamination, are cooled, and injected into a precision Penning trap for mass measurement. We will present the first results and current status of the TITAN EBIT, which has recently been moved to TRIUMF after assembly and commissioning at the Max-Planck-Institute (MPI) for Nuclear Physics in Heidelberg, Germany.     

Pullback attractors for non-autonomous 2D-Navier–Stokes equations in some unbounded domains

In this Note we first introduce the concept of pullback asymptotic compactness. Next, we establish a result ensuring the existence of a pullback attractor for a non-autonomous dynamical system under the general assumptions of pullback asymptotic compactness and the existence of a pullback absorbing family of sets. Finally, we prove the existence of a pullback attractor for a non-autonomous 2D Navier–Stokes model in an unbounded domain, a case in which the theory of uniform attractors does not work since the non-autonomous term is quite general. To cite this article: T. Caraballo et al., C. R. Acad. Sci. Paris, Ser. I 342 (2006).