Soft X-ray emissions by high-current vacuum discharges

Soft X-ray emissions by Z-pinch discharge between vacuum spark electrodes are examined. Mainly aluminum and molybdenum were utilized to generate soft X-rays, and emissions resulted for pulse currents of about 150 kA. These emissions increased as the discharge current increased. A large X-ray intensity was obtained when a spherical anode and a conical cathode were used. A stable spot plasma was produced for an electrode separation distance of 2 mm. For molybdenum, the X-ray emission of the 0.52-nm line and continuous X-rays of 0.65-1.2 nm were observed. The X-ray continuum was assumed to be a recombination continuum. For aluminum alloy containing magnesium, the 0.62-, 0.66-, 0.72-, 0.78-, and 0.92-nm lines were observed. The experimental results indicate that vacuum spark is a potential exposure source for X-ray lithography     

Structural modeling of beams on elastic foundations with elasticity couplings

A new simplified structural model and its governing equations for beams on elastic foundations with elastic coupling are proposed. This modeling system is simple but appropriate for the initial structural design of large-scale submerged floating-beam structures moored by tension legs spaced at uniform interval along the beam. The model is actually for beam on discrete elastic supports rather than on continuous elastic foundations. Therefore, the governing equations are based on finite difference calculus and solutions for beams on discrete elastic supports with elasticity coupling are also proposed. To clarify the applicability limit of the proposed model, the equivalence between a beam on discrete elastic supports and that on continuous elastic foundation is investigated by comparisons of characteristic solutions.     

Simulation of metastable zone width and induction time for a seeded aqueous solution of potassium sulfate

The metastable zone width (MSZW, ΔT_m) and induction time (t_ind) were determined with computer simulation for seeded batch crystallization of potassium sulfate from aqueous solution. The MSZW and induction time determined with simulation showed the same behavior as experimental values reported in the literature; log (ΔT_m) increased linearly with an increase in log R (R: cooling rate) and t_ind decreases in proportion to (ΔT)⁻ⁿ (ΔT: supercooling, n: nucleation order in the secondary rate expression of B=k_n(ΔT)ⁿ). The secondary nucleation parameters (k_n and n) were deduced both from the simulated MSZW and induction times by using the previously proposed model [J. Cryst. Growth, 2010, 312, 548–554]. The secondary nucleation rate calculated with the deduced parameters was in agreement with that calculated with the parameters input for simulation.     

Ligand effect of bulky 2,2-dialkyl-1-phosphaethenes on Au-catalyzed cycloisomerization of 1,6-enynes and lactonization of pent-4-ynoic acids

2,2-Dimethyl- and 2-benzyl-2-methyl-1-(2,4,6-tri-tert-butylphenyl)-1-phosphaethenes were employed as ligand of mononuclear chlorogold(I) complexes, which catalyzed cycloisomerization of 1,6-enyne affording vinylcyclopentene exclusively in the absence of silver co-catalyst. The reaction mechanisms are discussed based on DFT calculations. In addition to the cycloisomerization, the phosphaalkene-chlorogold(I) complexes catalyzed cyclization of pent-4-ynoic acids providing γ-methylene-γ-lactones under basic conditions.     

Indium tribromide-catalyzed deacetoxylation of propargylic acetate with triethylsilane

Indium(III) bromide catalyzed the deacetoxylation of propargylic acetates with Et₃SiH to produce the corresponding internal alkynes containing a variety of functional groups in good yields.     

Solvent-dependent conformational switching of the aromatic N-methyl amides depending upon the acceptor properties of solvents

An aromatic N-methyl amide containing N-(2-pyridyl) and 2,6-pyridinedicarboxamide moieties switches its conformation from cis to trans depending upon the acceptor number of solvents.     

Combination of sp2‐ and sp3‐Type Phosphorus Atoms for Gold Chemistry: Preparation,Structure, and Catalytic Activity of Gold Complexes That Bear Ligated 2‐Silyl‐1,3‐diphosphapropenes

Kinetically protected 2‐silyl‐1,3‐diphosphapropenes that bear both sp²‐ and sp³‐type phosphorus atoms were employed in the preparation of gold complexes. The structural properties of the 1,3‐diphosphapropene digold(I) complexes were characterized by spectroscopic and crystallographic analyses, which revealed unique aurophilic interactions and conformational properties of the ligand. The 2‐silyl‐1,3‐diphosphapropene‐bis(chlorogold) complexes catalyzed cycloisomerization reactions of 1,6‐enyne derivatives even in the absence of silver co‐catalyst, and were able to be recovered after the reaction. The catalytic activity of the digold complexes primarily depended on the sp²‐type phosphorus atom and the silyl group, and could be tuned by the sp³‐phosphino group. Additionally, results on the catalytic activity of the digold complex in the presence and absence of silver salts showed considerable differences.     

Melidianolic acid A and B, new antimalarial acyclic diterpenes from Aphanamixis grandifolia

Two new acyclic diterpenes, melidianolic acids A (1) and B (2), have been isolated from the bark of Aphanamixis grandifolia. Their structures were elucidated on the basis of spectroscopic and chemical methods. Melidianolic acids A (1) and B (2) showed antimalarial activity against Plasmodium falciparum 3D7 with IC50 of 6.1 and 7.3 microg/mL, respectively.