Self assembly,structure and properties of the decanuclear lanthanide ring complex,Dy10(OC2H4OCH3)30

Self assembly produced high yields of the lanthanide ring complex Dy10(OC2H4OCH3)30, the largest lanthanide ring known, characterized by X-ray diffraction methods and by magnetic susceptibility as a function of temperature.     

First synthesis of etidronate partial amides starting from PCl3

Methods for the preparation of mixed tetra-amide esters 1 and 2, the partial amide ester 3, and tri- and P,P-diamides 4 and 5 from monophosphorus spieces 12, 8 and 9, respectively, were developed. Compounds 8 and 9 were obtained from phosphorus trichloride via MeOPCl2, which was treated with 2 eq. and 4 eq. of piperidine, followed by water or acetyl chloride, respectively. Tetrasubstituted amide bisphosphonates 1 and 2 were selectively dealkylated with lithium or silyl halide to achieve target compounds 3-5. Piperidine was found to be a good desilylation reagent. Quantum mechanical calculations illustrate why derivative 2 was produced in low yield. The usefulness of compounds 1, 3 and 4 as prodrugs of etidronate was determined in aqueous buffer and human serum.     

Nonadiabatic alignment of asymmetric top molecules: field-free alignment of iodobenzene

Nonadiabatic laser alignment of an asymmetric top molecule is studied using the combination of a quantum dynamical theory and time-resolved photofragment imaging experiments. In particular, the degree of alignment of iodobenzene, induced by an intense, linearly polarized picosecond laser pulse, is calculated and measured. Pronounced alignment is obtained under field-free conditions.     

Robustness of Objective and Subjective Speckle Patterns in the Speckle Strain Gauge

The robustness to rigid body object motions of three optical systems used in the speckle strain gauge were experimentally investigated and compared with analytical results of the correlation. It was found that an out-of-plane motion of the object damaged the reliability of the strain measure when recording the objective speckle patterns while subjective speckle patterns were more robust. Besides out-of-plane object motions, the robustness of a free-space geometry and an afocal imaging configuration are approximately the same, while a telecentric imaging system is more robust to rigid body motions but more sensitive to deformation gradients (basically in-plane rotation and tilt). Results from a measurement of the relaxation in a lead-tin alloy used in organ pipes is also presented.Presented at 1996 International Workshop on Interferometry (IWI ‘96), August 27-29, Wako, Saitama, Japan.     

Internal conversion coefficients of the transitions in Tm169

The conversion electron spectrum of Tm¹⁶⁹ has been measured by an iron-yoke double focusing spectrometer. Gamma-ray energies and gamma-ray intensities were measured by a bent crystal spectrometer. Conversion coefficients and conversion ratios were determined from the electron and gamma intensities. The conversion process of the retardedM 1 transitions of 177 keV and 198 keV was found to be normal, in agreement with our earlier directional correlation results. No penetration effects were found in the conversion process of the retarded 63 keVE1 transition.     

Weakly Compact Homomorphisms Between Small Algebras of Analytic Functions

The weak compactness of the composition operator C(f) = f acting on the uniform algebra of analytic uniformly continuousfunctions on the unit ball of a Banach space with the approximationproperty is characterized in terms of . The relationship betweenweak compactness and compactness of these composition operatorsand general homomorphisms is also discussed. 2000 MathematicsSubject Classification 46J15 (primary), 46E15, 46G20 (secondary).