Numerical predictions and experiments on the free-plate edge mode

In this paper, te edge mode variation is studied with three different methods: the reciprocal work method, already used by Torvik [J. Acoust. Soc. Am. 41 (1967) 346] to model this phenomenon, the S-parameter method and a finite element model that are applied for the first time to the study of the edge resonance. Moreover, laser probe measurements of the edge mode have also been performed and compared to the numerical predictions. The good agreement between the numerical predictions and the experimental data allows full understanding of the resonant phenomenon. The edge resonance is linked to the strong increase in amplitude of two complex Lamb waves, and the edge mode is proved to radiate into the plate as the first symmetrical Lamb mode S(0). Displacements at the edge and away from the edge have been computed and measured to evaluate the spatial and temporal behaviour of the edge mode. The dependence of the edge resonance frequency and amplitude on the Poisson coefficient has also been studied.     

Optical bistability in axially modulated OmniGuide fibers

We demonstrate the feasibility of optical bistability in an axially modulated nonlinear OmniGuide fiber through analytical theory and detailed numerical experiments. At 1.55-microm carrier wavelength, the in-fiber devices that we propose can operate with only a few tens of milliwatts of power, can have a nearly instantaneous response and recovery time, and can be shorter than 100 microm.     

Delayed crossing in the \pi h_{9/2} 1/2-[541] band of 173 Lu

High-spin states in the odd-proton nucleus ¹⁷³Lu have been populated in a ¹⁷⁰Er(⁷Li,4n) reaction and the emitted -radiation was detected with the GASP array. The favoured and unfavoured sequences of the band have been considerably extended. The favoured sequence does not show any indication of a band crossing up to a rotational frequency of 0.45 MeV. This is the largest crossing frequency ever observed for 1/2^- [541] bands of odd-proton nuclei with and . Previous Cranked Shell Model (CSM) calculations underestimate the crossing frequency by 100 keV.Received: 19 May 2003, Published online: 11 November 2003PACS: 21.10.-k Properties of nuclei; nuclear energy levels - 21.10.Re Collective levels - 23.20.Lv transitions and level energies - 27.70. + q      

Structural and optical characterization of undoped, doped, and clustered ZnO thin films obtained by PLD for gas sensing applications

The synthesis by pulsed laser deposition technique of zinc oxide thin films suitable for gas sensing applications is herein reported. The ZnO targets were irradiated by an UV KrF^* (λ = 248 nm, τ_FWHM ∼7 ns) excimer laser source, operated at 2.8 J/cm² incident fluence value, whilst the substrates consisted of SiO₂(0 0 1) wafers heated at 150 °C during the thin films growth process. The experiments were performed in an oxygen dynamic pressure of 10 Pa. Structural and optical properties of the thin films were investigated. The obtained results have demonstrated that the films are c-axis oriented. Their average transmission in the visible-infrared spectral region was found to be about 85%. The equivalent refractive indexes and extinction coefficients were very close to those of the tabulated reference values. Doping with 0.5% Au and coating with 100 pulses of Au clusters caused but a very slight decrease (with a few percent) of both transmission and refractive index values. The coatings with the most appropriate optical properties as waveguides have been selected and their behavior was tested for butane sensing.     

Polycaprolactone biopolymer thin films obtained by matrix assisted pulsed laser evaporation

We report the successful deposition of polycaprolactone polymer by MAPLE using a KrF* excimer laser (λ = 248 nm, τ = 7 ns). According to FTIR spectra the deposited films have similar chemical structure to the dropcast material. The fluence plays a key role in optimizing the performances of MAPLE-synthesized polycaprolactone structures. We demonstrated that MAPLE allows for controlling the morphology of films to the level required in targeted drug delivery of pharmacologic agents.     

Matrix assisted pulsed laser evaporation of poly(d,l-lactide) thin films for controlled-release drug systems

We report the successful deposition of the porous polymer poly(d,l-lactide) by matrix assisted pulsed laser evaporation (MAPLE) using a KrF* excimer laser (248 nm, τ = 7 ns) operated at 2 Hz repetition rate. The chemical structure of the starting materials was preserved in the resulting thin films. Fluence played a key role in optimizing our depositions of the polymer. We demonstrated MAPLE was able to improve current approaches to grow high quality thin films of poly(d,l-lactide), including a porosity control highly required in targeted drug delivery.     

Temperature field distribution in multi-layered solid media heated with multi-modes laser beam

In the present paper we want to develop an analytical model to study the thermal behavior of multi-layered solid media in interaction with a laser beam. We suppose that each layer has a constant thermal conductivity. We consider that the laser beam is formed by decoupled [Phys Rev A 1996; 53: 4435] multi-modes Hermite–Gauss beams. The model is applied using the classical heat equation which was solved using the integral transform method [Infrared Phys Technol 2002; 42: 31; Optics Laser Technol 2004; 36: 219–22; Optics Laser Technol 2004; 36: 677–9; Proc SPIE 2003; 5227: 323].     

Thermal fields in laser–multi-layer structures interaction

In the present paper, we are dealing with the thermal fields for laser–periodic multilayer structures interaction. Our point of view is originally that we consider any order transverse laser beams, like heating sources. We consider that the laser beam acts in IR (Nd:YAG or CO₂ laser beam) and it is in one transverse mode or in only a few decoupled modes. In order to solve this problem, we will use the Green function method. Specific results are presented for a laser beam (Nd:YAG laser) operating in the mode TEM₀₁ and a two-layer structure.     

Thermal degradation behavior of some ruthenium complexes with fluoroquinolone derivatives as potential antitumor agents

Three new complexes with ligands belong to the fluoroquinolone class having the general formula [RuL₂Cl₂]Cl nH₂O ((1) L: norfloxacin (nf), n = 4; (2) L: ciprofloxacin (cp), n = 3; (3) L: enrofloxacin (enro), n = 5) were synthesized and characterized by chemical analysis UV–Vis and IR spectroscopy. In all complexes fluoroquinolone derivative acts as bidentate chelate ligand. The thermal behavior steps were investigated in synthetic air flow. The thermal transformations are complex processes according to TG and DTG curves including dehydration, quinolone derivative degradation, as well as RuCl₃ conversion in RuO₂.     

Variational principles for symmetric bilinear forms

Every compact symmetric bilinear form B on a complex Hilbert space produces, via an antilinear representing operator, a real spectrum consisting of a sequence decreasing to zero. We show that the most natural analog of Courant's minimax principle for B detects only the evenly indexed eigenvalues in this spectrum. We explain this phenomenon, analyze the extremal objects, and apply this general framework to the Friedrichs operator of a planar domain and to Toeplitz operators and their compressions. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)