全文获取类型
收费全文 | 855篇 |
免费 | 16篇 |
国内免费 | 15篇 |
专业分类
化学 | 383篇 |
晶体学 | 5篇 |
力学 | 19篇 |
数学 | 344篇 |
物理学 | 135篇 |
出版年
2023年 | 7篇 |
2022年 | 10篇 |
2021年 | 25篇 |
2020年 | 12篇 |
2019年 | 15篇 |
2018年 | 17篇 |
2017年 | 19篇 |
2016年 | 21篇 |
2015年 | 24篇 |
2014年 | 26篇 |
2013年 | 64篇 |
2012年 | 47篇 |
2011年 | 45篇 |
2010年 | 42篇 |
2009年 | 49篇 |
2008年 | 48篇 |
2007年 | 61篇 |
2006年 | 47篇 |
2005年 | 44篇 |
2004年 | 27篇 |
2003年 | 33篇 |
2002年 | 27篇 |
2001年 | 8篇 |
2000年 | 10篇 |
1999年 | 13篇 |
1998年 | 6篇 |
1997年 | 11篇 |
1996年 | 11篇 |
1995年 | 5篇 |
1994年 | 4篇 |
1993年 | 8篇 |
1992年 | 6篇 |
1991年 | 3篇 |
1989年 | 4篇 |
1987年 | 8篇 |
1986年 | 4篇 |
1985年 | 6篇 |
1984年 | 8篇 |
1982年 | 5篇 |
1981年 | 9篇 |
1980年 | 3篇 |
1979年 | 3篇 |
1978年 | 4篇 |
1976年 | 5篇 |
1974年 | 3篇 |
1961年 | 3篇 |
1939年 | 2篇 |
1938年 | 2篇 |
1936年 | 4篇 |
1932年 | 2篇 |
排序方式: 共有886条查询结果,搜索用时 281 毫秒
91.
Comorosan S Polosan S Jipa S Popescu I Marton G Ionescu E Cristache L Badila D Mitrica R 《Journal of photochemistry and photobiology. B, Biology》2011,102(1):39-44
Free radicals generation is inhibited through green light (GL) irradiation in cellular systems and in chemical reactions. Standard melanocyte cultures were UV-irradiated and the induced cellular reactive oxygen species (ROS) were quantified by the fluorescence technique. The same cell cultures, previously protected by a 24h GL exposure, displayed a significantly lower ROS production. A simple chemical reaction is subsequently chosen, in which the production of free radicals is well defined. Paraffin wax and mineral oil were GL irradiated during thermal degradation and the oxidation products checked by chemiluminescence [CL] and Fourier transform infrared spectra [FT-IR]. The same clear inhibition of the radical oxidation of alkanes is recorded. A quantum chemistry modeling of these results is performed and a mechanism involving a new type of Rydberg macromolecular systems with implications for biology and medicine is suggested. 相似文献
92.
93.
94.
Mihai Turinici 《Nonlinear Analysis: Theory, Methods & Applications》2011,74(6):2388-2391
Some nonlinear extensions of the vector maximality statement established by Goepfert et al. [A. Goepfert, C. Tammer, C. Z?linescu, On the vectorial Ekeland’s variational principle and minimal points in product spaces, Nonlinear Anal. 39 (2000) 909-922] are given. Basic instruments for these are the Brezis-Browder ordering principle [H. Brezis, F.E. Browder, A general principle on ordered sets in nonlinear functional analysis, Adv. Math. 21 (1976) 355-364] and its logical equivalent in Turinici [M. Turinici, Variational principles on semi-metric structures, Libertas Math. 20 (2000) 161-171]. 相似文献
95.
Sturza M Daviero-Minaud S Huvé M Renaut N Tiercelin N Mentré O 《Inorganic chemistry》2011,50(24):12499-12507
The (Ba,Sr)FeO(3-δ) system is known for its strong tendency for oxygen and vacancies to order into several forms including fully ordered pseudobrownmillerites, hexagonal perovskites with segregation of the vacancies in particular anionic layers and low deficient (pseudo)cubic compounds (generally δ < 0.27, Fe(3/4+)). We show for the first time, using a simple chemical process, the easy access to a large amount of vacancies (δ ≈ 0.5, Fe(3+)) within the room-temperature stable tetragonal (pseudocubic) Sr(0.8)Ba(0.2)FeF(~0.1)(O,F)(~2.5.) The drastic effect of the incorporation of a minor amount of fluoride passes through the repartition of local O/F/□ constraints shifting the tolerance factor into the pseudocubic range for highly deficient compounds. It is stable up to 670 K, where an irreversible reoxidation process occurs, leading to the cubic-form. The comparison with the cubic oxide Sr(0.8)Ba(0.2)FeO(~2.7) shows the increase of the resistivity (3D-VRH model) by two decades due to the almost single valent Fe(3+) of the oxofluoride. In addition, the G-type magnetic ordering shows relatively weak moment for Fe(3+) cations (M(Fe) ≈ 2.64(1) μB at room temperature) attributed to incoherent magnetic components expected from local disorder in such anionic-deficient compounds. 相似文献
96.
In this paper we give a new definition of the softness kernel based on the exchange-correlation density. This new kernel is shown to correspond to the change of electron fluctuation upon external perturbation, thus helping to bridge the gap between conceptual density functional theory and some tools describing electron localization in molecules. With the aid of a few computational calculations on diatomics we illustrate the performance of this new computational tool. 相似文献
97.
Ciobanu M Huang KT Daguer JP Barluenga S Chaloin O Schaeffer E Mueller CG Mitchell DA Winssinger N 《Chemical communications (Cambridge, England)》2011,47(33):9321-9323
We report the synthesis of a nucleic acid-encoded carbohydrate library, its combinatorial self-assembly into 37,485 pairs and a screen against DC-SIGN leading to the identification of consensus ligand motifs. A prototypical example from the selected pairs was shown to have enhanced binding. A dendrimer incorporating the selected motifs inhibited gp120's binding to dendritic cells with higher efficiency than mannan. 相似文献
98.
Raducan M Rodríguez-Escrich C Cambeiro XC Escudero-Adán EC Pericàs MA Echavarren AM 《Chemical communications (Cambridge, England)》2011,47(17):4893-4895
[Au(tmbn)(2)](SbF(6)) is the first gold(I) complex supported by two nitrile ligands that is indefinitely stable at room temperature. This is a highly versatile precatalyst that can be used for the preparation of active and robust solid-supported gold(I) catalysts. 相似文献
99.
Mihaela Badea Rodica Olar Valentina Uivarosi Dana Marinescu Victoria Aldea Stefania Felicia Barbuceanu George Mihai Nitulescu 《Journal of Thermal Analysis and Calorimetry》2011,105(2):559-564
Two new complexes having general formula VOL2·nH2O [(1) L: 5-hydroxyflavone, n = 1; (2) L: chrysin, n = 4] were synthesized and characterized. Based on IR and electronic data we concluded that studied flavones act as bidentate
ligands in complexes with metallic ion coordinated in a square-pyramidal stereochemistry. The thermal analysis (TG, DTA) elucidated
the composition and also the number and nature of the water molecules. The thermal behavior also indicated strong interactions
between oxovanadium (IV) and these oxygen donor ligands. 相似文献
100.
Putz MV 《Molecules (Basel, Switzerland)》2011,16(4):3128-3145
The conceptual and practical issues regarding the reduction of the Haldane-Radi? enzymic mechanism, specific for cholinesterase kinetics, to the consecrated or logistically modified Michaelis-Menten kinetics, specific for some mutant enzymes, are here clarified as due to the limited initial substrate concentration, through detailed initial rate and progress curve analysis, even when other classical conditions for such equivalence are not entirely fulfilled. 相似文献