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71.
Gardolinski JE Ramos LP de Souza GP Wypych F 《Journal of colloid and interface science》2000,221(2):284-290
Well-crystallized kaolinite (K) was initially reacted at 60 degrees C with a water/dimethylsulfoxide (DMSO) mixture and the resulting intercalation derivative (K-DMSO) was characterized by powder X-ray diffractometry (PXRD), thermal analysis (simultaneous TG and DSC), and Fourier-transformed infrared spectroscopy (FTIR). Benzamide crystals were then melted with the K-DMSO derivative at 140 degrees C for 4 days, when a gradual displacement of DMSO by benzamide was observed within the interlayer spacing of the modified kaolinite. The resulting material, after extensive washing with acetone, was characterized and compared to the results obtained previously for the K-DMSO composite. Benzamide intercalation proceeded by gradual displacement of DMSO molecules until completion. The structural stabilization of the K-BZ derivative was explained through the establishment of hydrogen bonds between the carbonyl oxygen atoms of the intercalated benzamide and aluminol groups present at the surface of the kaolinite layer. The interlamellar spacing of K-BZ was shown to be possibly occupied by benzamide molecules that were located at a 68 degrees orientation in relation to the layer surface. Unlike most intercalation molecules such as DMSO, variations in the interplanar spacing of kaolinite were consistent with the nonkeying of any other part of the molecule between the aluminosilicate interlayers. Copyright 2000 Academic Press. 相似文献
72.
Armentano D De Munno G Mastropietro TF Julve M Lloret F 《Journal of the American Chemical Society》2005,127(31):10778-10779
Intermolecular proton transfer in solid phase from the hydroxo bridge to a water molecule occurs in a new mu-hydroxo iron(III) compound of formula {EtNH3[Fe2(ox)2Cl2(mu-OH)].2H2O}n leading to a still crystalline compound in which the mu-oxo bridge replaces the mu-hydroxo one. Both three-dimensional compounds exhibit magnetic ordering at Tc ca. 70 K due to a spin canting. 相似文献
73.
F. Briones D. Golmayo L. González J. L. de Miguel 《Applied Physics A: Materials Science & Processing》1985,36(3):147-151
H2S gas has been used during molecular beam epitaxy (MBE) growth of GaAs and Al
x
Ga1–x
As as sulphur vector forn-type doping. Doping efficiencies are less than 10–3 at usual growth temperatures, and are limited by an incorporation competitive surface process, probably 2Ga+H2SGa2S+H2. In AlxGa1–x
As forx0.2 the doping efficiency is further reduced by carrier freeze-out at deep levels. Measured thermal activation energies depend on growth conditions and remain relatively low even up to the direct-indirect bandgap crossover for substrate temperatures in the 585–645 C range. 相似文献
74.
75.
Wege HA Aguilar JA Rodríguez-Valverde MA Toledano M Osorio R Cabrerizo-Vílchez MA 《Journal of colloid and interface science》2003,263(1):162-169
A new methodology capable of providing reliable and reproducible contact angle (theta) data has been employed to study the effect of clinical treatments grinding, acid etching, and deproteinization on medial dentin tissue. It is based on the application of the ADSA-CD algorithm to the determination of low-rate dynamic contact angles, obtained from slowly growing drops, and on contact angle measurement, as well as spreading behavior analysis, during the relaxation of the system (water on treated dentin) after initial drop growth. The theta data obtained were substantially more reproducible than those obtained with classical methods. A net effect of the treatment on theta was found, increasing dentin wettability: theta (polished) >theta (etched) >theta (deproteinized). The spreading rates correlate with the angles and are adequate for the dentin surface characterization. ANOVA and SNK tests show that for advancing contact angles the means corresponding to all treatments are significantly different. In the relaxing phase, mean angle and spreading rates on polished dentin differ significantly from those on etched and deproteinized dentin, but the latter do not differ significantly from each other. 相似文献
76.
Self-assembly of nonionic surfactants into lyotropic liquid crystals in ethylammonium nitrate, a room-temperature ionic liquid 总被引:2,自引:0,他引:2
The stability of a variety of lyotropic liquid crystals formed by a number of polyoxyethylene nonionic surfactants in the room-temperature ionic liquid ethylammonium nitrate (EAN) is surveyed and reported. The pattern of self-assembly behaviour and mesophase formation is strikingly similar to that observed in water, even including the existence of a lower consolute boundary or cloud point. The only quantitative difference from water is that longer alkyl chains are necessary to drive the formation of liquid crystalline mesophases in EAN, suggesting that a rich pattern of "solvophobic" self-assembly should exist in this solvent. 相似文献
77.
S. R. de Miguel G. Torres A. A. Castro O. A. Scelza 《Reaction Kinetics and Catalysis Letters》1993,51(2):443-447
The hydrogenation activity of Pt supported on activated carbon would depend on both the Pt dispersity (which can be modified by a partial carbon burn-off in air) and the impurities concentration. 相似文献
78.
Cycloreversion of 2-(p-cyanophenyl)-4-methyl-3-phenyloxetane (1) is achieved using 1-methoxynaphthalene (2) as electron-transfer photosensitizer. The experimental results are consistent with the reaction taking place from the singlet excited state of the sensitizer. Ring splitting of the radical anion 1*- occurs with cleavage of O-C2 and C3-C4 bonds, leading to products (acetaldehyde and p-cyanostilbene) different from the reagents used in the Paterno-Büchi synthesis of 1. The olefin radical anion involved in the electron-transfer process has been detected by means of laser flash photolysis. 相似文献
79.
Hong SB Lee SH Shin CH Woo AJ Alvarez LJ Zicovich-Wilson CM Camblor MA 《Journal of the American Chemical Society》2004,126(42):13742-13751
Here, we report that synthetic gallosilicate molecular sieves with the NAT topology and Si/Ga ratios close to but slightly higher than 1.50 undergo an in situ transformation under their crystallization conditions. The materials have been studied ex situ by using powder X-ray diffraction, elemental and thermal analyses, and multinuclear MAS NMR. The transformation is characterized by a change in the distribution of Si and Ga of the NAT framework, from a quite (but not completely) disordered phase to a very highly (but not completely) ordered one, accompanied by a change from tetragonal to orthorhombic symmetry. During most of the solution-mediated transformation, no noticeable signs of fresh precipitation, phase segregation, or changes in the chemical composition are detected. Intermediate materials show variations in the degree of Si-Ga ordering and orthorhombic distortion and are not physical mixtures of the disordered and ordered phases. Ab initio calculations strongly suggest a preferential siting of Si in the tetrahedral sites involved in a smaller number of 4-rings in the NAT topology (i.e., the low multiplicity site). The cost of violations of Loewenstein's rule has also been calculated. For this topology and chemical composition the preferential siting and Loewenstein's rule drive together the system to the ordered configuration. A Monte Carlo sampling procedure affords a reasonable model for the initial, mainly disordered state, which fits well within the experimental disorder-order series. 相似文献
80.
Pilar De Miguel Nazario Martín Miguel F. Braa 《Journal of heterocyclic chemistry》1994,31(5):1235-1239
Novel tetrahydroimidazo[1,5-b]-β-carbolines derivatives 6 bearing complex basic chains as substituents on the imidic nitrogen have been prepared in a one-pot reaction. This simple experimental procedure overcomes the direct handle of isocyanates which can be favorably generated “in situ” from carbonyldiimidazole (CDI) and different amines. The stereochemistry of the novel compounds was determined by nmr experiments. 相似文献