全文获取类型
收费全文 | 83123篇 |
免费 | 1495篇 |
国内免费 | 617篇 |
专业分类
化学 | 44901篇 |
晶体学 | 956篇 |
力学 | 2630篇 |
综合类 | 20篇 |
数学 | 16459篇 |
物理学 | 20269篇 |
出版年
2021年 | 528篇 |
2020年 | 740篇 |
2019年 | 734篇 |
2018年 | 1730篇 |
2017年 | 1960篇 |
2016年 | 1866篇 |
2015年 | 1518篇 |
2014年 | 1716篇 |
2013年 | 3163篇 |
2012年 | 5755篇 |
2011年 | 5315篇 |
2010年 | 3506篇 |
2009年 | 3109篇 |
2008年 | 3414篇 |
2007年 | 3345篇 |
2006年 | 3319篇 |
2005年 | 6851篇 |
2004年 | 5979篇 |
2003年 | 4079篇 |
2002年 | 2254篇 |
2001年 | 1449篇 |
2000年 | 1071篇 |
1999年 | 1001篇 |
1998年 | 849篇 |
1997年 | 818篇 |
1996年 | 795篇 |
1995年 | 735篇 |
1994年 | 762篇 |
1993年 | 685篇 |
1992年 | 817篇 |
1991年 | 824篇 |
1990年 | 733篇 |
1989年 | 675篇 |
1988年 | 637篇 |
1987年 | 620篇 |
1986年 | 548篇 |
1985年 | 817篇 |
1984年 | 789篇 |
1983年 | 628篇 |
1982年 | 689篇 |
1981年 | 654篇 |
1980年 | 630篇 |
1979年 | 609篇 |
1978年 | 594篇 |
1977年 | 551篇 |
1976年 | 627篇 |
1975年 | 519篇 |
1974年 | 484篇 |
1973年 | 470篇 |
1967年 | 376篇 |
排序方式: 共有10000条查询结果,搜索用时 203 毫秒
91.
Michael A. Brook Yang Chen Kui Guo Zheng Zhang Wen Jin Anil Deisingh Jorge Cruz-Aguado John D. Brennan 《Journal of Sol-Gel Science and Technology》2004,31(1-3):343-348
The preparation of discrete polyol based silane precursors derived from glycerol by a simple one-pot process is described. These polyol-based silanes could be hydrolyzed under mild pH conditions and upon gelation resulted in the formation of optically clear, monolithic, mesoporous silica. The hydrolysis and condensation reactions lead to cure rates that are very sensitive to ionic strength, but are almost unaffected by pH in contrast to those of alkoxysilanes derived from primary alcohols such as Si(OEt)4. Residual glycerol in the silica monolith could be removed by washing, or could be left in the silica to reduce the magnitude of shrinkage during long term storage. The biocompatible glyceroxysilane precursors lead to materials that were able to retain the activity of entrapped enzymes over repeated cycles of use for periods of up to several months. 相似文献
92.
93.
Hiroaki Miyagawa Michael J. Rich Lawrence T. Drzal 《Journal of Polymer Science.Polymer Physics》2004,42(23):4391-4400
The thermophysical and mechanical properties of a nanocomposite material composed of amine‐cured diglycidyl ether of bisphenol A (DGEBA) reinforced with organomontmorillonite clay are reported. The storage modulus at 100 °C, which was above the glass‐transition temperature (Tg), increased approximately 350% with the addition of 10 wt % (6.0 vol %) of clay. Below the Tg, the storage modulus at 30 °C increased 50% relative to the value of unfilled epoxy. It was determined that the Tg linearly increased as a function of clay volume percent. The tensile modulus of epoxy at room temperature increased approximately 50% with the addition of 10 wt % of clay. The reinforcing effect of the organoclay nanoplatelets is discussed with respect to the Tandon–Weng and Halpin–Tsai models. A pseudoinclusion model is proposed to describe the behavior of randomly oriented, uniformly dispersed platelets in nanocomposite materials. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 4391–4400, 2004 相似文献
94.
Sándor G?r?g 《Analytical sciences》2004,20(5):767-782
The development during the last 15 years and the state-of-the-art in the analysis of bulk steroid hormone drugs and hormone-like structures and pharmaceutical formulations made thereof are summarized. Other steroids (sterols, bile acids, cardiac glycosides, vitamins D) as well as biological-clinical aspects and pharmacokinetic and metabolic studies are excluded from this review. The state-of-the-art is summarized based on comparisons of monographs in the latest editions of the European Pharmacopoeia, United States Pharmacopoeia and the Japanese Pharmacopoeia. This is followed by sections dealing with new developments in the methodology for the fields of spectroscopic and spectrophotometric, chromatographic, electrophoretic and hyphenated techniques as well electroanalytical methods. The review is terminated by two problem-oriented sections: examples on impurity and degradation profiling as well as enantiomeric analysis. 相似文献
95.
The electrochemical reduction of 1-([(4-halophenyl)imino]methyl)-2-naphthols on graphite electrodes was studied using cyclic voltammetry, chronoamperometry, constant-potential coulometry and preparative constant-potential electrolysis techniques. The data revealed that the reduction on graphite was irreversible and followed an EC mechanism. The diffusion coefficients and the number of electrons transferred were determined using the chronoamperometric Cottrell slope and the ultramicro disc Pt-electrode steady-state current. The number of electrons was also determined by bulk electrolysis. The compounds were subjected to constant-potential preparative electrolysis and the electrolysis products were purified and identified by spectroscopic methods. Based on these findings, a mechanism for the electro-reduction process is proposed. 相似文献
96.
JingXiaWANG ChengYouKAN DeShanLIU 《中国化学快报》2004,15(10):1161-1163
Two novel polymerizable dyes with anthraquinone residue have been prepared, and their structures were characterized by FTIR, ^1HNMR and EA. 相似文献
97.
98.
99.
The control of piecewise-deterministic processes is studied where only local boundedness of the data is assumed. Moreover the discount rate may be zero. The value function is shown to be solution to the Bellman equation in a weak sense; however the solution concept is strong enough to generate optimal policies. Continuity and compactness conditions are given for the existence of nonrelaxed optimal feedback controls. 相似文献
100.
A model is developed for the flow of a slightly compressible fluid through a saturated inelastic porous medium. The initial‐boundary‐value problem is a system that consists of the diffusion equation for the fluid coupled to the momentum equation for the porous solid together with a constitutive law which includes a possibly hysteretic relation of elasto‐visco‐plastic type. The variational form of this problem in Hilbert space is a non‐linear evolution equation for which the existence and uniqueness of a global strong solution is proved by means of monotonicity methods. Various degenerate situations are permitted, such as incompressible fluid, negligible porosity, or a quasi‐static momentum equation. The essential sufficient conditions for the well‐posedness of the system consist of an ellipticity condition on the term for diffusion of fluid and either a viscous or a hardening assumption in the constitutive relation for the porous solid. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献