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91.
Grzegorz M. Salamończyk 《Tetrahedron letters》2003,44(40):7449-7453
An efficient synthesis of antiviral dendritic prodrug candidates, water-soluble, polyanionic conjugates of 1st and 2nd generation thiophosphate dendrimers with acyclovir, is described. 相似文献
92.
Xinhua Liang Zhentao Mi Yaquan Wang Li Wang Xiangwen Zhang 《Reaction Kinetics and Catalysis Letters》2004,82(2):333-337
The ammoximation of acetone to acetone oxime with 30 wt.% hydrogen peroxide over TS-1 has been studied. The conversion of
acetone and the selectivity to acetone oxime can reach 99% and 94%, respectively. The by-products are the corresponding hydrazone,
imine and small amounts of unidentified compounds. The influence of various parameters such as solvent, temperature, amounts
of catalyst and the NH3 to acetone molar ratio were investigated.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
93.
Jarosł Spychała 《Research on Chemical Intermediates》2007,33(6):481-486
Evidence for a stereoinduction profile of the reaction of N-methyl-1,3-diaminopropane with acyl chlorides has been provided. A possibility to engage in intramolecular CH2⋯HN and Cl⋯H-N interactions and the proton migration process to the methylamino group leads to the E secondary amides carrying the N⋯H+⋯N or N-H⋯N bridges, that show unusual spectroscopic images. Empirical relations between the Δδ
C chemical shift differences, the polarizability of the CO(S) groups and hydrogen bonding strength have been found. Both 1H-15N-GHSQC and GHMBC experiments provide insight into the nature of hydrogen bonding and confirm the cyclic array of atoms. 相似文献
94.
Hubert Grudzński 《Reports on Mathematical Physics》2004,53(3):331-338
New elements of the dual cone of the set of fermion N-representable 2-density operators are proposed. So far, the explicit form of the corresponding necessary conditions for N-representability is obtained for N = 3. In this case the new condition is stronger than the known B- and C-conditions for 3-representability. The results provide evidence that in the spectral decomposition of the N-representable 2-density operator there exists an intrinsic relation between the eigenvalue and the corresponding eigenfunction. 相似文献
95.
Orewczyk J. Jasieńska S. Iwanczenko S. 《Journal of Thermal Analysis and Calorimetry》1998,54(1):79-84
This paper presents applications of thermal analysis to observe the course of reduction of acidic pellets, metallurgical substances
whose reducibility and strength are basic parameters of use in blast furnace processes. Both parameters depend on the mineral
composition of the samples. The investigations included determination of the chemical and phase compositions of the initial
samples and reduction products.
Research was conducted on acidic pellets from Połtawa (Poland), applied in the T. Sendzimir Steelworks (Poland), in comparison
with pellets from Brazil, Canada and Lebedyn (Russia).
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
96.
Marek Pękała Jan Mucha Benedicte Vertruyen Rudi Cloots Marcel Ausloos 《Journal of magnetism and magnetic materials》2006
Samples of La0.7Ca0.3Mn1−xGaxO3 with x=0, 0.025, 0.05 and 0.10 were prepared by standard solid-state reaction. They were first characterized chemically, including the microstructure. The magnetic properties and various transport properties, i.e. the electrical resistivity, magnetoresistivity (for a field below 8 T), thermoelectric power and thermal conductivity measured each time on the same sample, are reported. The markedly different behaviour of the x=0.1 sample from those with a smaller Ga content, is discussed. The dilution of the Mn3+/Mn4+ interactions with Ga doping considerably reduces the ferromagnetic double exchange interaction within the manganese lattice leading to a decrease of the Curie temperature. The polaron binding energy varies from 224 to 243 meV with increased Ga doping. 相似文献
97.
98.
Zbigniew Peradzyński Bogdan Kazmierczak 《Archive of Applied Mechanics (Ingenieur Archiv)》2005,74(11-12):827-833
The influence of mechano-chemical coupling on calcium concentration waves is considered. The propagation of calcium waves is described by a reaction–diffusion equation with the reaction term dependent on the mechanical stress responsible for the release of calcium. Similarly the balance of mechanical forces is influenced by the calcium concentration through the so-called traction force. 相似文献
99.
Dealing with infinite iterated function systems we introduce and develop the ergodic theory of Hölder systems of functions similarly as in [HU] and [HMU]. In the context of conformal infinite iterated function systems we prove the volume lemma for the Hausdorff dimension of the projection onto the limit set of a shift invariant measure. This can be considered as a Billingsley type result. Our cenral goal is to demonstrate the appearance of the "singularity-absolute continuity" dichotomy for equilibrium states of Hölder systems of functions which has been observed in [PUZ,I] and [PUZ,II] (see also [DU1] and [DU2]) in the setting of rational functions of the Riemann sphere. 相似文献
100.
Wojciech Bocian Jarosław Jaźwínski Lech Stefaniak Graham A. Webb 《Chemistry of Heterocyclic Compounds》1995,31(9):1103-1107
1H,13C,14N and15N NMR measurements are reported for four mesoionic 1-oxa-2, 3, 4-triazoles containing exocyclic nitrogenous groups. The NMR signal assignments are discussed and compared with those previously published for some corresponding oxatriazoles. The results obtained support the proposed cyclic mesoionic structures for the compounds studied. The questions of possible charge delocalization and valence tautomerism are addressed. Compound with N– H as a exocyclic group (Fig. 1) is found to be relatively unstable, this is attributed to proton migration in the corresponding non-cyclic form of this molecule.Published in Khimiya Geterotsikiicheskikh Soedinenii, No. 9, pp. 1260–1263, September, 1995. 相似文献