Spin Stiffness of 2D Isotropic Heisenberg Antiferrornagnet

The spin stiffness of spin-1/2 two-dimensional isotropic Heisenberg antiferromagnet is calculated by a perturbation method based on the extended Schwinger-Boson mean-field theory. We arrive at a value of the spin stiffness, p_s = 0.176J, which is in quite well agreement with experiments and the numerical results.     

多光子电离谱的微机控制

本文报道了测量多光子电离谱的一整套硬件和软件系统。自行设计实现了将计算机、激光器及Ｂｏｘｃａｒ连接起来的自动控制系统。这一系统大大改善了实验条件，提高了信噪比及仪器的分辨率。所得的实验结果，未曾见报道。     

Sustained and Controlled Release of Volatile Precursors for Chemical Vapor Deposition of Graphene at Atmospheric Pressure

Precursors and catalysts play vital roles in chemical reactions. Considerable efforts have been devoted to the investigation of catalysts for graphene growth by chemical vapor deposition in recent years. However, there has been little research on precursors because of a lack of innovation in term of creating a controllable feeding method. Herein, we present a novel sustained and controlled release approach, and develop a convenient, safe, and potentially scalable feeding system with the assistance of matrix materials and a simple portable feeder. As a result, a highly volatile liquid precursor can be fed accurately to grow large-area, uniform graphene films with optimal properties. This feeding approach will further benefit the synthesis of other two-dimensional materials from various precursors.     

20Mgβ衰变谱学与15O(α,γ)19Ne反应(英文)

15O（α,γ）19Ne（p,γ）20Na反应链是高温CNO循环向快速质子俘获过程突破的一条关键路径,相关的反应率输入量可通过20Mg的β衰变可布居19Ne共振态并测量其衰变性质来获得。通过高效率高精度地测量20Mg β衰变中产生的质子与γ射线得到了20Mg衰变的详细信息,并构建了完整的衰变纲图,还进行了19Ne 4 033 keV共振态衰变性质的探索,获得了该态在20Mg β衰变中被布居的分支比上限。通过比20Mg和20O镜像能级跃迁的结果确认了同位旋非对称性,为检验相关理论模型提供了精确的实验数据。对于突破路径中有重要影响的19Ne 4 033 keV共振态的性质,有待更高统计的实验进一步研究。The breakout from the hot CNO cycle to the rapid proton capture process can occur via the 15O(α,γ)19Ne(p,γ)20Na reaction sequence, and the β decay of 20Mg can be used as an alternative method to characterize some specific resonances, which will provide detailed nuclear structure input for reaction rate calculations. The reliable information on the decay properties and structure of 20Mg was obtained by measuring the emitted particles and γ-rays in the β decay with high efficiency and high resolution. Attempt was also made to search for the decay channels associated with the 4 033 keV resonance in 19Ne. To test fundamental symmetries, the transitions in the mirror decays of 20Mg and 20O were compared. The precise experimental data presented here would be important to constrain the theoretical calculations. It is desirable to clarify the astrophysically relevant problem by further experiments with improved statistics on the basis of the present work.     

一种红外与可见光融合的“双双目”立体视觉系统的标定方法研究

针对红外相机与可见光相机联合标定的问题,利用不同物体红外辐出度的差异,设计了可同时应用于红外相机与可见光相机标定的平面靶标。利用"最大稳定极值区域"(MSER)算法,检测靶标的镂空深色区域。为克服图像可能存在较大畸变的问题,通过相邻最大稳定极值区域质心的位置关系预估角点所在位置,在预估位置内进行角点检测,提取用于标定的亚像素角点位置。结果表明:新型靶标及相应的角点提取方法能够同时满足于红外相机与可见光相机内外参数标定的需要。通过红外与可见光"双双目"立体视觉系统的融合重构效果可看出,提供的标定数据能够满足系统需求。     

砂土双屈服面的数值建模

通过研究中密砂在等p路径和增p路径下的三轴试验曲线,发现其应力-塑性应变关系曲线在常规应力范围内具有较好的量纲一化特性。选择合适的指标对砂土三轴试验数据进行量纲一化,以量纲一的试验数据为训练样本进行神经网络训练,得到了两种砂土比较理想的双屈服面神经网络模型。研究结果表明两种路径下屈服面是不同的,该方法能反映应力路径的相关性。     

An ab initio study of the ground and valence excited states of GaF

Ab initio calculations on the ground and valence excited states of the GaF molecule have been performed by using the internally contracted multireference electronic correlation methods (MR-CISD, MR-CISD + Q, and MR-AQCC) with entirely uncontracted all-electronic basis sets and Douglas-Kroll scalar relativistic correction. The potential energy curves of all valence states and the spectroscopic constants of bound states are fitted. It is the first time that the 12 valence Lambda-S states of GaF molecule and all of the 23 Omega states generated from the former are studied in a theoretical way. Calculation results well reproduce most of the experimental data. The effects of the size-extensivity correction and the avoided crossing rule between Omega states of the same symmetry are analyzed. The transition properties of the A 3Pi0+, B 3Pi1, C 1Pi1, and 3Sigma1+ states are predicted, including the transition dipole moments, the Franck-Condon factors and the radiative lifetimes. The radiative lifetime of the C 1Pi1 state of GaF molecule is of the order of nanosecond, implying that it is a rather short-live state. The lifetimes of the B 3Pi1 and 3Sigma1+ states are of the order of microsecond, while the lifetime of the A 3Pi0+ state are the order of millisecond.     

一种用于荧光检测痕量Cu2+的锌基金属有机骨架

采用水-溶剂热法制备了一种针对Cu²⁺的新型高效荧光锌基金属有机骨架(Zn-MOF)探针：[Zn₆(L)₃(2,2''-bpy)₄]·2H₂O}_n,其中 H₄L=1,4-双(3,5-二羧基苯氧基)苯,2,2''-bpy=2,2''-联吡啶。本文介绍了它的合成、结构、热稳定性和荧光传感性能。该Zn-MOF表现出良好的稳定性并且可以通过荧光猝灭法高效检测Cu²⁺。在0~1.2 μmol·L^-1的浓度范围内,该Zn-MOF荧光强度与 Cu²⁺浓度呈现出很强的线性相关性,检测限(LOD)低至 67.1 nmol·L^-1。更重要的是,通过系统分析红外光谱、粉末 X 射线衍射、紫外可见吸收光谱、电感耦合等离子体质谱和 X射线光电子能谱,验证了所获得的结果：该 Zn-MOF可通过弱相互作用特异性识别Cu²⁺。此外,该Zn-MOF在连续5个循环中表现出良好的再生性能。     

Electrochemically deposited organic luminescent films: the effects of deposition parameters on morphologies and luminescent efficiency of films

The electropolymerization behaviors of an electroactive and luminescent compound TCPC as precursor are studied. The resultant electrochemical deposition (ED) films are characterized by cyclic voltammetry (CV), UV-vis, fluorescence spectra, scanning electron microscopy (SEM), and atomic force microscopy (AFM). Under the CV mode with potential range of -0.5 to 0.85 V vs Ag/Ag(+), the coupling reactions between the carbazole units of TCPC are very efficient, while the fluorescent trifluorene segment in TCPC is chemically inert in this potential range, which results in a highly fluorescent film formation on indium tin oxide (ITO) electrode. The deposition parameters for preparing the TCPC-based ED films are optimized, and the best ED film gives the fluorescence efficiency of 45.5% with surface roughness of 2.8 nm and morphologic stability as heating to 180 degrees C. The light-emitting devices (LEDs) using this ED film as light emitting layer with structure ITO/ED film (approximately 100 nm)/Ba/Al achieve maximum luminescence and external quantum efficiency of 4224 cd/m(2) at 17 V and 0.72% at 11.5 V, respectively, which are better than the device using TCPC spin-coating films as emitting layer. The technique provides a facile route toward a patternable luminescent film and device because such luminescent ED films can be manipulatively deposited on the electrified electrode.