二维多环全苯芳烃的合成、性能及应用

二维多环全苯芳香烃(PBAH)具有类似于石墨的结构形态,拥有良好的稳定性,被视作一种理想的导电材料,自问世以来受到了广泛关注。本文详细总结了由树枝形聚苯前驱体平面化而制得PBAH的合成方法, 指出了PBAH的表征难点,阐述了PBAH的多功能性如热致液晶性、导电性以及光学性能,展示了PBAH在电子传输材料、场效应晶体管、光伏电池、发光二极管、二次电池等方面的应用前景。特别指出了带有柔性侧链的PBAH分子可以形成碟状的液晶态,从而呈现有序的超分子结构,在各种PBAH光电材料的应用中占据领先地位。     

Refractive index changes induced by sheet beams with various intensity distributions in LiNbO<Subscript>3</Subscript>:Fe crystal

1 IntroductionSince the discovery of photorefractive effect by Ashkin et al. at the Bell laboratories in 1966[1], such effects of light-induced refractive index changes in electro-optic oxide crystals have attracted great attention because of their potential use in volume holo- graphic storage[2], optical information processing[3], optical spatial solitons[4], and light-induced optical waveguides[5―9]. The photo-induced index changes are the basis ofthe entire photorefractive phenomena in pho…     

一类min-max-min问题的区间算法

讨论了一类由一阶连续可微函数构成的无约束min-max-min问题．通过构造目标函数的区间扩张、无解区域删除原则，建立了求解min-max-min问题的区间算法，证明了算法的收敛性，给出了数值算例．理论证明和数值结果表明方法是可靠和有效的．     

ON THE APPLICATIONS OF LERAY-SCHAUDER CONTINUATION THEOREM TO BOUNDARY VALUE PROBLEMS OF SEMILINEAR DIFFERENTIAL EQUATIONS

1IntroductionLeray-Schauderdegree,anditsvariantssuchascoinidencedegree113]andtopologicaltransversality[4],isanefficienttooltostudythesolvabilityofboundaryvalueproblemsfornonlineardifferentialequations,especiallyf'Orsemilineardifferentialequations.Bytherec…     

迭代映射的一个整体性质

本文应用微分动力系统理论讨论了一个常用的扰动技术的数学基础，并且得到了关于迭代过程的一些结果。     

InCl分子A3Π0态时间分辨谱研究

采用激光诱导荧光技术对 In Cl分子 A3 Π0 → X1Σ 荧光光谱进行了分析和归属 ,并对A3 Π0 (ν′=1)→ X1Σ (ν"=1,2 ,3,4 ,5)的时间分辨谱进行了观测 ,得到 In Cl分子 A3 Π0 态无碰撞辐射寿命τ0 ≈ 370 ns,无碰撞弛豫速率常数 k Q ≈ 9.87× 10 -11cm3 molec-1s-1。     

结晶诱导的手性分子自发对称性破缺的研究进展

对称性破缺是自然界特别是生命体内常见的一种现象。开展手性分子在结晶过程中自发对称性破缺发生的机理与机制研究,将会为探索生命起源提供更多新的科学依据。本文主要从自发对称性破缺的基本原理、结晶诱导的手性分子对称性破缺的机制方面进行综述,并讨论了影响结晶过程中自发对称性破缺的各种因素。     

Identifying the Zn-Co binary as a robust bifunctional electrocatalyst in oxygen reduction and evolution reactions via shifting the apexes of the volcano plot

The performance of an electrocatalyst is closely correlated with the binding strength of key oxygencontaining intermediates,i.e.,*OOH,*O and*OH,in the oxygen reduction reaction(ORR)and oxygen evolution reaction(OER).Facile strategies to achieve favorable binding strength of these oxygen-containing species are urgently demanded,yet it still remains great challenges.Herein,the Zn-Co bimetallic isolation,which serves as an ideal model,is studied systematically by the density functional theory(DFT).Reaction activity volcano plots are built from 48 models,among them the ZnCoN6-gra(I)configuration is confirmed to be the most stable,featured of the strongest interaction with the oxygen-containing species.Optimal △G*O(free energy change of an atomic oxygen containing intermediate)is facilitated,which effectively drifts the volcano peaks of ORR and OER closer to each other,enabling promising bifunctional catalyst.Moreover,the small overpotential in the simulation of protonation and oxidation by hydroxy groups rationalizes the durability of the catalyst in both acid and alkaline media.