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53.
Joan Adler Yigal Meir Amnon Aharony A. B. Harris Lior Klein 《Journal of statistical physics》1990,58(3-4):511-538
We discuss recent work on the development and analysis of low-concentration series. For many models, the recent breakthrough in the extremely efficient no- free-end method of series generation facilitates the derivation of 15th-order series for multiple moments in general dimension. The 15th-order series have been obtained for lattice animals, percolation, and the Edwards-Anderson Ising spin glass. In the latter cases multiple moments have been found. From complete graph tables through to 13th order, general dimension 13th-order series have been derived for the resistive susceptibility, the moments of the logarithms of the distribution of currents in resistor networks, and the average transmission coefficient in the quantum percolation problem, 11th-order series have been found for several other systems, including the crossover from animals to percolation, the full resistance distribution, nonlinear resistive susceptibility and current distribution in dilute resistor networks, diffusion on percolation clusters, the dilute Ising model, dilute antiferromagnet in a field, and random field Ising model and self-avoiding walks on percolation clusters. Series for the dilute spin-1/2 quantum Heisenberg ferromagnet are in the process of development. Analysis of these series gives estimates for critical thresholds, amplitude ratios, and critical exponents for all dimensions. Where comparisons are possible, our series results are in good agreement with both-expansion results near the upper critical dimension and with exact results (when available) in low dimensions, and are competitive with other numerical approaches in intermediate realistic dimensions. 相似文献
54.
A method is described for the activation of Sepharose withN,N′-disuccimidyl carbonate. The activated carbonate reacts smoothly with amine-containing ligands yielding stable carbamate derivatives. 相似文献
55.
Nery JG Bolbach G Weissbuch I Lahav M 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(10):3039-3048
The formation of diastereoisomeric libraries of oligopeptides through the heterogeneous polymerization of racemic crystals of phenylalanine N-carboxyanhydride (PheNCA) is reported. The diastereoisomeric compositions of the oligopeptides formed on polymerization of (R,S) crystals incorporating the deuterium-tagged S enantiomer were determined by MALDI-TOF mass spectrometry. The racemic mixtures of the oligopeptides longer than pentamers are represented primarily by diastereoisomers of homochiral sequence and with peptides containing only one heterochiral repeating unit. A mechanism comprising the following three sequential steps to account for this unusual observation is proposed: 1) formation of dimers and trimers at a partially damaged liquid/solid interface, 2) chain propagation that takes place within the bulk of the crystal through a lattice-controlled "zipper-like" mechanism between homochiral molecules arranged in a head-to-tail motif to yield crystalline antiparallel beta-sheets of alternating oligopeptide chains of homochiral sequence of opposite handedness, and 3) enantiomeric cross-inhibition that results in chain termination. Induced desymmetrization of the racemic mixtures of the formed peptides was achieved by the polymerization of the mixed quasi-racemic crystals of (R)-PheNCA, ((S)-PheNCA), and (S)-ThieNCA (3-(2-thienyl)-alanine N-carboxyanhydride) of various compositions. These experiments resulted in the formation of nonracemic libraries of oligopeptides composed of homochiral chains of (R)-Phe and copolymers of randomly distributed (S)-Phe and (S)-Thie sequences. From these findings, we propose a stochastic model for the generation of libraries of nonracemic mixtures of oligopeptides from the polymerization of host (R,S)-PheNCA with racemic mixtures of other guest NCA amino acids dissolved in limited quantities in the crystal. 相似文献
56.
We present the S1 → S0 fluorescence spectrum, between 740 and 940 nm, of azulene solutions (10?3 M in methanol) excited with a Q-switched ruby laser. The nitrogen-laser excited S2 → S1 fluorescence spectrum, between 700 and 930 nm, is also reported. The transient S1 → Sn spectrum between 500 and 650 nm was studied, using synchronous nitrogen laser and dye laser excitation. The S5 (1B1(3)) state of azulene was found to be located at 45500 cm?1 and the cross section σ25 of the transient absorption S2 → S5 is estimated to be 3 × 10?18 cm2/molecule. 相似文献
57.
Mohamed F. Meidine Catherine J. Meir Stephen Morton John F. Nixon 《Journal of organometallic chemistry》1985,297(2):255-263
Syntheses of the complexes trans-[PtCl2(PR3)Mo2(CO)4(η5-C5H5)2(tBuCP)], (PR3=PEt3, PPr3, PBu3, PPh2Me, PPhMe2) trans-[PdCl2(PBu3)Mo2(CO)4(η5-C5H5)2(tBuCP)], and trans[RhCl{(PF2NMe)2CO}Mo2(CO)4(η5-C5H5)2(tBuCP)] are described and their 31P NMR spectra presented and discussed. 相似文献
58.
Klon AE Glick M Davies JW 《Journal of chemical information and computer sciences》2004,44(6):2216-2224
We have previously reported that the application of a Laplacian-modified naive Bayesian (NB) classifier may be used to improve the ranking of known inhibitors from a random database of compounds after High-Throughput Docking (HTD). The method relies upon the frequency of substructural features among the active and inactive compounds from 2D fingerprint information of the compounds. Here we present an investigation of the role of extended connectivity fingerprints in training the NB classifier against HTD studies on the HIV-1 protease using three docking programs: Glide, FlexX, and GOLD. The results show that the performance of the NB classifier is due to the presence of a large number of features common to the set of known active compounds rather than a single structural or substructural scaffold. We demonstrate that the Laplacian-modified naive Bayesian classifier trained with data from high-throughput docking is superior at identifying active compounds from a target database in comparison to conventional two-dimensional substructure search methods alone. 相似文献
59.
Fritz Pittner Talia Miron Gisela Pittner Meir Wilchek 《Applied biochemistry and biotechnology》1980,5(3):167-180
Cyanogen bromide was used to convert pyridine rings in polymers to polyaldehyde. By reaction with NH2-containing substances, the rings are rebuilt, resulting in a pyridinium compound. Thus proteins and other NH2-containing substances can be covalently bound. This method provides a new means for a immobilization technique. Pyridine-gels based on polysaccharide and polyacrylamide matrices, as well as pyridine glass beads, were synthesized and used to study the conditions necessary for coupling. Trypsin and — chymotrypsin were used as test substances for immobilization of proteins. Some properties of the bound protein were studied and compared to native enzyme. Some general results on the applicability of these gels for affinity chromatography are also presented. 相似文献
60.
Inside Back Cover: Solvent‐Induced Crystal Polymorphism as Studied by Pyroelectric Measurements and Impedance Spectroscopy: Alcohols as Tailor‐Made Inhibitors of α‐Glycine (Angew. Chem. Int. Ed. 18/2018) 下载免费PDF全文