全文获取类型
收费全文 | 12366篇 |
免费 | 1112篇 |
国内免费 | 786篇 |
专业分类
化学 | 9024篇 |
晶体学 | 150篇 |
力学 | 455篇 |
综合类 | 74篇 |
数学 | 1048篇 |
物理学 | 3513篇 |
出版年
2024年 | 11篇 |
2023年 | 110篇 |
2022年 | 223篇 |
2021年 | 321篇 |
2020年 | 318篇 |
2019年 | 332篇 |
2018年 | 244篇 |
2017年 | 243篇 |
2016年 | 453篇 |
2015年 | 481篇 |
2014年 | 574篇 |
2013年 | 894篇 |
2012年 | 950篇 |
2011年 | 967篇 |
2010年 | 738篇 |
2009年 | 618篇 |
2008年 | 937篇 |
2007年 | 804篇 |
2006年 | 777篇 |
2005年 | 683篇 |
2004年 | 599篇 |
2003年 | 498篇 |
2002年 | 456篇 |
2001年 | 363篇 |
2000年 | 261篇 |
1999年 | 202篇 |
1998年 | 134篇 |
1997年 | 94篇 |
1996年 | 110篇 |
1995年 | 102篇 |
1994年 | 77篇 |
1993年 | 91篇 |
1992年 | 85篇 |
1991年 | 59篇 |
1990年 | 58篇 |
1989年 | 52篇 |
1988年 | 30篇 |
1987年 | 32篇 |
1986年 | 24篇 |
1985年 | 50篇 |
1984年 | 25篇 |
1983年 | 22篇 |
1982年 | 29篇 |
1981年 | 23篇 |
1980年 | 19篇 |
1979年 | 9篇 |
1977年 | 15篇 |
1976年 | 8篇 |
1975年 | 10篇 |
1974年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 920 毫秒
11.
Naoto Takase Junpei Kuwabara Seong Jib Choi Takeshi Yasuda Liyuan Han Takaki Kanbara 《Journal of polymer science. Part A, Polymer chemistry》2015,53(4):536-542
The Pd‐catalyzed polycondensation of 4‐octylaniline with various dibromoarylenes was carried out under microwave heating. Microwave heating led to a decrease in the reaction time and an increase in the molecular weight of the polymers as compared to conventional heating. Microwave heating also allowed the catalyst loading to be reduced to 1 mol %, yielding polymerization results that were comparable to those under conventional heating and 5 mol % catalyst. Investigations regarding field‐effect transistors and organic photovoltaic cells using the obtained poly(arylamine) with azobenzene units revealed that increasing the molecular weight of the polymer led to improved device performance, including hole mobility and power conversion efficiency. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 536–542 相似文献
12.
Sung Hwan Koo Dong Jun Li Taeyeong Yun Dong Sung Choi Kyung Eun Lee Gil Yong Lee Youngtak Oh Joonwon Lim Suchithra Padmajan Sasikala Ho Jin Lee In Ho Kim Hong Ju Jung Rishabh Jain Sang Ouk Kim 《Particle & Particle Systems Characterization》2019,36(7)
Efficient water electrolysis catalyst is highly demanded for the production of hydrogen as a sustainable energy fuel. It is reported that cobalt derived nanoparticle (CoS2, CoP, CoS|P) decorated reduced graphene oxide (rGO) composite aerogel catalysts for highly active and reliable hydrogen evolution reaction electrocatalysts. 7 nm level cobalt derived nanoparticles are synthesized over graphene aerogel surfaces with excellent surface coverage and maximal expose of active sites. CoS|P/rGO hybrid aerogel composites show an excellent catalytic activity with overpotential of ≈169 mV at a current density of ≈10 mA cm?2. Accordingly, efficient charge transfer is attained with Tafel slope of ≈52 mV dec?1 and a charge transfer resistance (Rct) of ≈12 Ω. This work suggests a viable route toward ultrasmall, uniform nanoparticles decorated graphene surfaces with well‐controlled chemical compositions, which can be generally useful for various applications commonly requiring large exposure of active surface area as well as robust interparticle charger transfer. 相似文献
13.
We consider the problem of estimating a large rank-one tensor u ⊗k ∈ (ℝn)⊗k , k ≥ 3 , in Gaussian noise. Earlier work characterized a critical signal-to-noise ratio λ Bayes = O(1) above which an ideal estimator achieves strictly positive correlation with the unknown vector of interest. Remarkably, no polynomial-time algorithm is known that achieved this goal unless λ ≥ Cn(k − 2)/4 , and even powerful semidefinite programming relaxations appear to fail for 1 ≪ λ ≪ n(k − 2)/4 . In order to elucidate this behavior, we consider the maximum likelihood estimator, which requires maximizing a degree-k homogeneous polynomial over the unit sphere in n dimensions. We compute the expected number of critical points and local maxima of this objective function and show that it is exponential in the dimensions n , and give exact formulas for the exponential growth rate. We show that (for λ larger than a constant) critical points are either very close to the unknown vector u or are confined in a band of width Θ(λ−1/(k − 1)) around the maximum circle that is orthogonal to u . For local maxima, this band shrinks to be of size Θ(λ−1/(k − 2)) . These “uninformative” local maxima are likely to cause the failure of optimization algorithms. © 2019 Wiley Periodicals, Inc. 相似文献
14.
Hejia Hu Linlin Wu Mei Li Cun Xue Guangcheng Wang Siying Chen Yong Huang Lin Zheng Aimin Wang Yueting Li Zipeng Gong 《Biomedical chromatography : BMC》2020,34(1):e4714
Eucommia ulmoides Oliv. (E. ulmoides) is a valuable and nourishing medicinal herb in China that has been used in the treatment of hypertension. Given the fact that most traditional Chinese medicine is mainly used to treat disease, investigating the pharmacokinetics of traditional Chinese medicines in the pathological state is more useful than that in the normal state. However, the differences in the absorption kinetics of active ingredients of E. ulmoides extract between pathological and physiological conditions have not been reported. Therefore, in this study, the rat intestinal in situ circulatory perfusion model was used to investigate the differences in absorption kinetics of seven active ingredients of E. ulmoides extract in normal and spontaneously hypertensive rats, namely, genipinic acid, protocatechuic acid, neochlorogenic acid, chlorogenic acid, cryptochlorogenic acid, (+)-pinoresinol di-O-β-D -glucopyranoside and (+)-pinoresinol 4′-O-β-D -glucopyranoside. Our results indicate that the pathological state of spontaneous hypertension may change the absorption of active components of E. ulmoides extracts, and these findings may provide a reference for improving the rational use of E. ulmoides in the clinic. 相似文献
15.
史美华 《纯粹数学与应用数学》2002,18(2):145-150,155
设k,r分别是自然数和非零整数,Jk(n)是Jordan函数。以E(x;k,r)表示和式sum from (n≤x) Jkr(n)的渐近公式中的误差项,本文研究了E(x;k,r)的某种加权平方积分均值。 相似文献
16.
国人大概都知道杞人忧天的故事.相传战国时列御寇所撰《列子》一书中的《天瑞》篇载有“杞国有人,忧天地崩坠,身亡所寄,废寝食者”;唐朝大诗人李白《梁甫吟》一诗中也提到这件事:“白日不照吾精诚,杞国无事忧天倾”;清李汝珍所著《镜花缘》第二十七回也有言:“杞人忧天,伯虑愁眠”.说的都是古时候杞国有个人,老爱瞎操心,明明不用担忧的事情,他也是不放心,特别是害怕天会塌下来,弄得自己无处安身. 相似文献
17.
18.
科学与完美是不是一致的?科学家们是否有权使用完美这个词?至少,对于物理学家和数学家来说答案是肯定的“是”.2002年,温伯格(Steven Weinberg)写道:“近代物理学的一些重要方程式是科学知识的永久部分,甚至比它们较早出现的美丽大教堂还要经久不衰.”1960年代,狄拉克(Paul A.M.Dirac)有句名言:“完整的方程式之完美较之它们适合实验结果更为重要.”1965年诺贝尔物理学奖获得者费因曼(Richard P.Feynman)也坚信他提出的一项理论,即使该理论显得与实验数据有矛盾.1957年,他写道:“理论是优雅和完美的,重大事件是短暂的闪光.” 相似文献
19.
In this paper, we shall find the uniquerational price associated with the exchange option. Also, we find the decomposition of Snell envelope and value function of the American exchange option. 相似文献
20.
Quantization of Underdamped, Critically Damped, and Overdamped Electric Circuits with a Power Source
Jeong-Ryeol Choi 《International Journal of Theoretical Physics》2002,41(10):1931-1939
We have investigated the quantum mechanical effect of the underdamped, critically damped, and overdamped electric circuits with a power source. The charge of the underdamped circuit oscillates while those of the critically damped and overdamped ones don't. The wave function of the system of overdamped circuit represented parabolic cylinder function while underdamped circuit was represented by well-known Hermite polynomial. The eigenvalues of underdamped circuit is discrete while those of the critically damped and overdamped ones are given as continuously. 相似文献