On the mechanism of phenol ozonolysis

The mechanisms of liquid-phase phenol ozonation are revised. A new mechanism in which a significant role is played by free-radical reactions is suggested for this process.     

Submillimeter-wave large-orbit gyrotron

We develop a thermionic-emission electron-optical system forming a dense beam of electrons moving along helical trajectories round the axis of a gyrotron cavity. The maximum beam current is 4 A and the pitch-factor of electrons is 1.0 for a particle energy of 250 keV and a pulse duration of 10 µs. Using such a beam in a gyrotron operated at the third cyclotron harmonic, we obtain single-mode oscillation with a power of 10 µs in the TE_3,8 and TE_3,9 modes with frequencies 371 and 414 GHz, respectively.     

Molecular hydrodynamics of degenerate weakly nonideal bose gas. I. Generalized equations of two-fluid hydrodynamics

A degenerate weakly nonideal Bose gas is investigated at temperatures near zero. Relations connecting the irreducible Green's functions are used to obtain exact expressions for the two-time temperature-dependent Green's functions. In the case of weak nonideality an expression possessing interpolation properties with respect to the frequency and momentum is obtained for the density—density Green's function. At low frequencies, the results of two-fluid hydrodynamics are reproduced. At wavelengths less than the mean free path the energy of the elementary excitations and the damping obtained in the paper agree with the results of perturbation theory with respect to the coupling constant. An expression for the operator of the superfluid velocity is obtained.In memory of Nikolai Nikolaevich BogolyubovV. A. Steklov Mathematics Institute, Russian Academy of Sciences. Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 93, No. 3, pp. 412–465, December, 1992.     

原伊鲁烷型倍半萜醇芳香酸酯的碳谱研究

作者自人工发酵得到的蜜环菌Armillaria mellea (Vahl.ex Fr.) Quel.菌丝体中分离出十七个原伊鲁烷型倍半萜醇芳香酸翻,在研究这些化合物的化学结构中,对其全去偶碳谱,偏共振谱或INEPT谱,C-H COSY谱和远程C-H COSY谱进行比较仔细地分析,指定了每个化合物各碳的归属,讨论了其碳谱的特征,并指出¹³C NMR谱是对新的该类型化合物结构测定的有效方法.     

Classes of regular and singular boundary problems

Translated from Matematicheskie Zametki, Vol. 51, No. 2, pp. 149–151, February, 1992.     

一项从CAA到CAD的工作 ～正交优化法与SPICE相结合

电子电路的计算机辅助设计方法是促进电子技术发展的一种有效工具。本文介绍如何将行之有效的正交优化法与国际盛行的模拟电子电路的分析程序ＳＰＩＣＥ相结合，形成了ＡＣＯＤ软件，将ＣＡＡ扩展为ＣＡＤ。     

Elastoplastic state of axisymmetrically loaded laminated bodies of revolution made of isotropic and orthotropic materials

Institute of Mechanics, Ukrainian Academy of Sciences, Kiev. Translated from Prikladnaya Mekhanika, Vol. 28, No. 1, pp. 31–39, January, 1992.     

Charm production in two-photon collisions: Calculation of the leading nonperturbative contribution in QCD

The leading nonperturbative contribution to the cross section of charm production in two-photon collisions is calculated in QCD. Operator expansion is used and the c-quark interaction with vacuum gluon condensate is taken into account. As a result, the moments of the charm contribution to the photon structure function are obtained. The moments with sufficiently high numbers turn out to be sensitive to the gluon condensate.     

Electrochemical reduction of 1,1-dihalo-2,2-disubstituted cyclopropanes

The electrochemical reduction of 1,1-dihalo-2-R-2-methylcyclopropanes was studied by polarography and preparative electrolysis. A mixture of stereoisomeric monoboro- and monochlorocyclopropanes was obtained with preparative yield of 60–70% in preparative electroreduction in methanol against a background of 0.1 M LiClO₄. In the case of bromine derivatives of cyclopropanes (except when R = CN) an effect was found on the part of the current density on the ratio of cis and trans isomers, which was interpreted as a change, in dependence on current density, of the contributions of the reactions of reduction of the starting compounds (S_N2 mechanism) and ionic pairs (S_N1 mechanism). The effect of the solvent (CHCl₃, DMF, DMSO, MeOH) and background salt (LiClO₄, Et₄NBr) on the ratio of stereoisomers is in agreement with this interpretation.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Science Center, Russian Academy of Sciences, Kazan. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 9, pp. 2023–2032, September, 1992.     

Copper-D-penicillamine complex as potential contrast agent for MRI.

In vitro and in vivo proton T1 data are reported that demonstrate that the paramagnetic copper-D-penicillamine complex can be applied as a potential contrast agent to magnetic resonance imaging.