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11.
M. Regiert T. Wimmer J. -P. Moldenhauer 《Journal of inclusion phenomena and macrocyclic chemistry》1996,25(1-3):213-216
To improve the storage stability of instable vegetable oils with a high content of polyunsaturated fatty acid triglycerides, these essential compounds can be complexed with native cyclodextrins. Only with -CD a nearly complete complexation of the oils was achieved as shown by complexation kinetics measurements. Storage trials of the insoluble CD-complexes followed by the determination of the peroxide value of the oils indicated that the best stabilization against autoxidation is obtained with -CD. An additional benefit of the complexation of triglycerides of polyunsaturated fatty acids with -cyclodextrin is the formation of stable dispersions of these oils in aqueous media. 相似文献
12.
Oligonucleotides containing (2′-deoxy-β-D -xylofuranosyl)guanine have been prepared. For this purpose 2-aminoadenosine ( 5 ) was synthesized and converted to 2′-deoxy-β-D -xyloguanosine ( 1 ). The related 2′-deoxy-β-D -xyloisoguanosine ( 3 ) and 2′-deoxy-β-D -xyloxanthosine ( 4 ) were also synthesized. Compound 1 was converted to the phosphonate and phosphoramidite building blocks 10 and 11 , respectively. The oligodeoxynucleotide (5′-3′)d(xG-xT-xA-xG-xA-xA-xT-xT-xC-xT-xA-xC-T) ( 18 ) formed a duplex with the same Tm as the parent (5′-3′)-(G-T-A-G-A-A-T-T-C-T-A-C) ( 19 ), but with an inverted CD spectrum. 相似文献
13.
Prof. Dr. Maximilian Pöhm Harald Kolassa Kurt Jentzsch 《Monatshefte für Chemie / Chemical Monthly》1977,108(2):393-395
It is well known that in the ergot alkaloids of the peptide type the proline appears in thel-configuration. Different methods of acid hydrolysis may lead to various cleavage products; hydrolysis by HCl yieldsd-proline, on the other hand hydrolytic cleavage by means of strongly acid cation exchange resin preserved the orginall-configuration.
Teilveröffentlichung der Dissertation vonH. Kolassa, Univ. Wien, 1973. 相似文献
Teilveröffentlichung der Dissertation vonH. Kolassa, Univ. Wien, 1973. 相似文献
14.
15.
Peter Bellotti Maximilian Koy Christian Gutheil Steffen Heuvel Frank Glorius 《Chemical science》2021,12(5):1810
A highly modular radical cascade strategy based upon radical cyclisation/allylic substitution sequence between alkyl/aryl bromides, 1,3-dienes and nucleophiles ranging from sulfinates to amines, phenols and 1,3-dicarbonyls is described (>80 examples). Palladium phosphine complexes – which merge properties of photo- and cross coupling-catalysts – allow to forge three bonds with complete 1,4-selectivity and stereocontrol, delivering highly value added carbocyclic and heterocyclic motifs that can feature – inter alia – vicinal quaternary centers, free protic groups, gem-difluoro motifs and strained rings. Furthermore, a flow chemistry approach was for the first time applied in palladium–photocatalysed endeavors involving radicals.Highly modular three-bond three-component cascade featuring palladium as dual photoredox/cross coupling catalyst. 相似文献
16.
Goren AC Hrovat DA Seefelder M Quast H Borden WT 《Journal of the American Chemical Society》2002,124(13):3469-3472
Time-dependent B3LYP/6-31G calculations have been performed at the optimized C(2) or C(2v) geometries of several substituted semibullvalenes (1(deloc)) and barbaralanes (2(deloc)), to compare the computed vertical electronic excitation energies with the temperature-dependent, long-wavelength absorptions that have been observed in the UV/vis spectra of some of these compounds by Quast and co-workers. The excellent agreement between the calculated vertical excitation energies and the observed values of lambda(max) provides strong support for the identification of the bishomoaromatic species 1(deloc) and 2(deloc) as the source of these absorptions. Furthermore, the CN stretching frequencies, computed for the C(2) geometry of 1,5-dimethyl-2,6-dicyano-4,8-diphenylsemibullvalene (1f(deloc)), fit the low-frequency absorptions seen in the IR spectrum of 1f, thus furnishing independent evidence that bishomoaromatic geometries of semibullvalenes have, in fact, been observed spectroscopically. B3LYP/6-31G calculations predict that 2,6-dicyano-4,8-diphenylsemibullvalene 1c has a C(2) equilibrium geometry (1c(deloc)) and that the long-wavelength UV/vis absorption (lambda(max) = 585 nm) and CN stretching frequencies (2192 and 2194 cm(-1)) computed for 1c(deloc) should serve to identify this bishomoaromatic semibullvalene when it is synthesized. 相似文献
17.
18.
Michael S. Gruhne Dr. Maximilian H. H. Wurzenberger Marcus Lommel Dr. Jörg Stierstorfer 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(35):9112-9123
Dinitraminic acid (HN(NO2)2, HDN) was prepared by ion exchange chromatography and acid-base reaction with basic copper(II) carbonate allowed the in situ preparation of copper(II) dinitramide, which was reacted with twelve nitrogen-rich ligands, for example, 4-amino-1,2,4-triazole, 1-methyl-5H-tetrazole, di(5H-tetrazolyl)-methane/-ethane/-propane/-butane. Nine of the complexes were investigated by low-temperature X-ray diffraction. In addition, all compounds were investigated by infrared spectroscopy (IR), differential thermal analysis (DTA), elemental analysis (EA) and thermogravimetric analysis (TGA) for selected compounds. Furthermore, investigations of the materials were carried out regarding their sensitivity toward impact (IS), friction (FS), ball drop impact (BDIS) and electrostatic discharge (ESD). In addition, hot plate and hot needle tests were performed. Complex [Cu(AMT)4(H2O)](DN)2, based on 1-amino-5-methyltetrazole (AMT), is most outstanding for its detonative behavior and thus also capable of initiating PETN in classical initiation experiments. Laser ignition experiments at a wavelength of 915 nm were performed for all substances and solid-state UV-Vis spectra were recorded to apprehend the ignition mechanism. 相似文献
19.