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Stefan Warsink Peter Hauwert Maxime A. Siegler Anthony L. Spek Cornelis J. Elsevier 《应用有机金属化学》2009,23(6):225-228
The synthesis of an air‐stable series of Pd0 complexes with dissymmetric bidentate N‐heterocyclic carbene–amine ligands has been performed. The key step is an unprecedented carbene transfer from AgI to obtain electron‐rich zero‐valent palladium precatalysts. The coordination behavior of the ligands was determined with X‐ray crystallography. Surprising results were obtained in the catalysis of transfer semi‐hydrogenation, where the addition of base appeared not to be necessary to obtain the desired product stereoselectively. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
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Alina Wildenberg Yann Fenard Maxime Carbonnier Alan Kéromnès Benoîte Lefort Zeynep Serinyel Guillaume Dayma Luis Le Moyne Philippe Dagaut Karl Alexander Heufer 《Proceedings of the Combustion Institute》2021,38(1):543-553
The modern catalytic or enzymatic advances allow the production of novel biofuel. Among them, 1,3-dioxolane can be produced from formaldehyde and ethylene glycol, both can be obtained from biomass. In this study, the oxidation of 1,3-dioxolane is studied at stoichiometric conditions. The ignition delay times of 1,3-dioxolane/O2/inert mixtures were measured in a shock tube and in a rapid compression machine at pressures of 20 to 40 bar and temperatures ranging from 630 to 1300 K. The pressure profiles recorded in the rapid compression machine show a first stage of ignition enlightening the influence of the low temperature chemistry of combustion. Furthermore, mole fraction profiles of the stable intermediates produced during the oxidation of 1,3-dioxolane were measured in a jet-stirred reactor at 10 bar. Following these observations, a detailed kinetic model was developed with reaction rate coefficients and thermochemical data calculated by theoretical calculations or estimated by analogies to suitable molecules. In order to get an insight into the most important reaction pathways brute force sensitivity analysis and reaction pathway analysis were performed with the proposed model and discussed. It became clear that in the fuel-in-air case for the alkylhydroperoxide of 1,3-dioxolane the ring opening beta-scission pathway is favored against the further alkane-like second addition to molecular oxygen, which leads to a limited negative temperature coefficient. 相似文献
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Dr. Nguyet Trang Thanh Chau Maxime Meyer Dr. Shinsuke Komagawa Dr. Floris Chevallier Prof. Yves Fort Prof. Masanobu Uchiyama Prof. Florence Mongin Dr. Philippe C. Gros 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(41):12425-12433
Homoleptic lithium tri‐ and tetraalkyl zincates were reacted with a set of bromopyridines. Efficient and chemoselective bromine–metal exchanges were realized at room temperature with a substoichiometric amount of nBu4ZnLi2?TMEDA reagent (1/3 equiv; TMEDA=N,N,N′,N′‐tetramethylethylenediamine). This reactivity contrasted with that of tBu4ZnLi2?TMEDA, which was inefficient below one equivalent. DFT calculations allowed us to rationalize the formation of N???Li stabilized polypyridyl zincates in the reaction. The one‐pot difunctionalization of dibromopyridines was also realized using the reagent stoichiometrically. The direct creation of C? Zn bonds in bromopyridines enabled us to perform efficient Negishi‐type cross‐couplings. 相似文献
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A stiff-stilbene strapped calix[4]pyrrole receptor can be reversibly switched by light between a strong chloride-binding Z-isomer and a very weakly binding E-isomer. The light-induced switching process is monitored by UV-Vis and 1H NMR spectroscopy and chloride binding is studied in detail using both 1H NMR and ITC titrations in DMSO and MeCN. In DMSO, at millimolar concentrations, switching from a fully bound to an almost fully unbound state can be triggered. Quantification of the binding constants in MeCN reveals an extraordinary 8000-fold affinity difference between the Z- and E-isomer. Single crystal X-ray crystallographic analysis gives insight into the structure of the photogenerated E-isomer and the geometry of the chloride-bound receptors is optimized by DFT calculations. The highly effective control of binding affinity demonstrated in this work opens up new prospects for on demand binding and release in extractions and photocontrol of membrane transport processes, among other applications.A reconfigurable calix[4]pyrrole receptor containing a stiff-stilbene strap can be switched by light between a strong and weak binding form, showing an 8000-fold affinity difference for chloride. 相似文献
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L. Semichon M. Flanzy A. Boidin E. Martin A. Wanscheidt O. Ieremejewa Al. Ionescu-Matiu Const Popesco H. S. King A. C. Bell C. Kollo N. Crisan G. Klein H. Linser O. Noetzel F. M. Archibald C. M. Beamer I. M. Korenman L. Palfray S. Sabetay Denise Sontag M. C. Brockmann C. H. Werkman C. Neuberg F. F. Nord C. R. Breden E. I. Fulmer L. Malaprade J. H. Birkinshaw J. H. V. Charles P. W. Clutterbuck C. B. van Niel und K. Száhlender 《Fresenius' Journal of Analytical Chemistry》1934,98(5-6):210-220
Ohne Zusammenfassung 相似文献
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Maxime Cari-Mantrand 《Fresenius' Journal of Analytical Chemistry》1896,35(1):219-220
Ohne Zusammenfassung 相似文献
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Targeting the Two Oncogenic Functional Sites of the HPV E6 Oncoprotein with a High‐Affinity Bivalent Ligand 下载免费PDF全文