Computational characterization of magneto-electric composites: the role of ferroelectric pre-polarization

The interaction between electric and magnetic fields enables smart devices which can find applications in sensor technology and data storage. Materials showing magneto-electric (ME) coupling combine different ferroic characteristics. In the present contribution we focus on composites, which combine ferroelectric and ferromagnetic phases due to strain couplings, such that they generate a strain-induced ME coupling. We derive a two-scale homogenization approach for the determination of effective properties in consideration of microscopic morphologies. Furthermore, we demonstrate the strong influence of ferroelectric polarization states on the ME-coefficient by modeling the switching of remanent polarizations on the microscale. (© 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Numerical simulation and laser-based imaging of mixture formation, ignition, and soot formation in a diesel spray

Laser-based imaging of fuel vapor distribution, ignition, and soot formation in diesel sprays was carried out in a high-pressure, high-temperature spray chamber under conditions that correspond to temperature and pressure in a diesel engine. Rayleigh scattering and laser-induced incandescence are used to image fuel density and soot volume fraction. The experimental results provide data for comparison with numerical simulations. An interactive cross-sectionally averaged spray model based on Eulerian transport equations was used for the simulation of the spray, and the turbulence-chemistry interaction was modeled with the representative interactive flamelet (RIF) concept. The flamelet calculation is coupled to the Kiva3V computational fluid dynamics (CFD) code using the scalar dissipation rate and pressure as an input to the RIF-code. The flamelet code computes the instationary flamelet profiles for every time step. These profiles were integrated over mixture fraction space using a prescribed β-PDF to obtain mean values, which are passed back to the CFD-code. Thereby, the temperature and the relevant species in each CFD-cell were obtained. The fuel distribution, the average ignition delay as well as the location of ignition are well predicted by the simulation. Furthermore, simulations show that the experimentally observed injection-to-injection variations in ignition delay are due to temperature inhomogeneities. Experimental and simulated spatial soot and fuel vapor density distributions are compared during and after second stage ignition.     

Volume preserving curvature flows in Lorentzian manifolds

Let N be a (n + 1)-dimensional globally hyperbolic Lorentzian manifold with a compact Cauchy hypersurface ${\mathcal{S}_{0}}$ and F a curvature function, either the mean curvature H, the root of the second symmetric polynomial ${{\sigma}_{2}=\sqrt{H_{2}}}$ or a curvature function of class (K*), a class of curvature functions which includes the nth root of the Gaussian curvature ${{\sigma}_{n}= K^{\frac{1}{n}}}$ . We consider curvature flows with curvature function F and a volume preserving term and prove long time existence of the flow and exponential convergence of the corresponding graphs in the C ^∞-topology to a hypersurface of constant F-curvature, provided there are barriers. Furthermore we examine stability properties and foliations of constant F-curvature hypersurfaces.     

Fractionalized fermi liquids

In spatial dimensions d>or=2, Kondo lattice models of conduction and local moment electrons can exhibit a fractionalized, nonmagnetic state (FL(*)) with a Fermi surface of sharp electronlike quasiparticles, enclosing a volume quantized by (rho(a)-1)(mod 2), with rho(a) the mean number of all electrons per unit cell of the ground state. Such states have fractionalized excitations linked to the deconfined phase of a gauge theory. Confinement leads to a conventional Fermi liquid state, with a Fermi volume quantized by rho(a)(mod 2), and an intermediate superconducting state for the Z2 gauge case. The FL(*) state permits a second order metamagnetic transition in an applied magnetic field.     

Optical sectioning in wide-field microscopy obtained by dynamic structured light illumination and detection based on a smart pixel detector array

Optical sectioning in wide-field microscopy is achieved by illumination of the object with a continuously moving single-spatial-frequency pattern and detecting the image with a smart pixel detector array. This detector performs an on-chip electronic signal processing that extracts the optically sectioned image. The optically sectioned image is directly observed in real time without any additional postprocessing.     

Graver basis and proximity techniques for block-structured separable convex integer minimization problems

We consider $N$ -fold $4$ -block decomposable integer programs, which simultaneously generalize $N$ -fold integer programs and two-stage stochastic integer programs with $N$ scenarios. In previous work (Hemmecke et al. in Integer programming and combinatorial optimization. Springer, Berlin, 2010), it was proved that for fixed blocks but variable  $N$ , these integer programs are polynomial-time solvable for any linear objective. We extend this result to the minimization of separable convex objective functions. Our algorithm combines Graver basis techniques with a proximity result (Hochbaum and Shanthikumar in J. ACM 37:843–862,1990), which allows us to use convex continuous optimization as a subroutine.     

The Spin-Coating Process: Analysis of the Free Boundary Value Problem

In this paper, an accurate model of the spin-coating process is presented and investigated from the analytical point of view. More precisely, the spin-coating process is being described as a one-phase free boundary value problem for Newtonian fluids subject to surface tension and rotational effects. It is proved that for T > 0 there exists a unique, strong solution to this problem in (0, T) belonging to a certain regularity class provided the data and the speed of rotation are small enough in suitable norms. The strategy of the proof is based on a transformation of the free boundary value problem to a quasilinear evolution equation on a fixed domain. The keypoint for solving the latter equation is the so-called maximal regularity approach. In order to pursue in this direction one needs to determine the precise regularity classes for the associated inhomogeneous linearized equations. This is being achieved by applying the Newton polygon method to the boundary symbol.     

Nitrous Oxide as a Hydrogen Acceptor for the Dehydrogenative Coupling of Alcohols

The oxidation of alcohols with N₂O as the hydrogen acceptor was achieved with low catalyst loadings of a rhodium complex that features a cooperative bis(olefin)amido ligand under mild conditions. Two different methods enable the formation of either the corresponding carboxylic acid or the ester. N₂ and water are the only by‐products. Mechanistic studies supported by DFT calculations suggest that the oxygen atom of N₂O is transferred to the metal center by insertion into the Rh?H bond of a rhodium amino hydride species, generating a rhodium hydroxy complex as a key intermediate.     

Micellar spheres in a high frequency oscillatory field

The viscoelasticity of aqueous micellar solutions of two oxyethylene/oxybutylene block copolymers (E(92)B(18) and B(20)E(510)) has been investigated using a torsional resonator operated at 26 kHz. For both systems considered, values of the dynamic viscosity (eta'(infinity)) point to partial draining of the micellar corona induced by the high-frequency oscillatory field. At low effective volume fractions, values of the elastic modulus (G'(infinity)) indicate that the repulsive interactions between micelles can be modeled by a power law function u(r) proportional to 1/r(nu) with exponents close to 13 and 6 for copolymers E(92)B(18) and B(20)E(510) respectively. At a critical copolymer concentration (c*) plots of log(G'(infinity)) against log(c) deviate from the straight lines established at low concentrations, implying that the systems undergo ergodic/nonergodic transitions.