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91.
M. Sahedur Rahman 《Mikrochimica acta》2001,137(3-4):203-207
A sensitive and fairly selective quenchofluorimetric method for the determination of mercury ultra-trace with murexide (ammonium
purpurate) has been developed. The method is based on the instantaneous quenching action of the metal-ion upon the native
fluorescence of murexide [λex(max) = 360 nm; λem(max) = 445 nm] in the optimum pH range of 5.8 to 6.6 at room temperature (25±0.5) °C. The fluorescence quenching is collinear
in the range of 5 μg/L to 100 μg/L mercury. The developed method is very precise and accurate (RSD = 2.2% for 11 determination
of 50 μg/L Hg(II). Large excesses of more than 50 cations, anions and complexing agents were found to have no interference.
The developed method was successfully tested over synthetic mixtures of various compositions, certified reference materials
and factory effluents.
Received November 16, 1999. Revision March 30, 2001. 相似文献
92.
文中我们在非对易量子力学(NCQM)的框架下讨论了克莱恩-高登朗道问题.分别在非对易空间(NCS)和非对易相空间(NCPS)中给出了海森伯代数和克莱恩-高登朗道能级. 相似文献
93.
Kazuo Takeuchi Junsuke Yabumoto Yoshiki Okada Terunao Kawai Rahman M. Montajir Yuichi Goto 《Journal of nanoparticle research》2005,7(2):287-293
A new dual-type differential mobility analyzer (dual-type DMA) was developed in order to detect transient number concentrations of airborne nanoparticles with diameters centralized at around 10 nm (for nuclei mode particles) and 100 nm (for accumulation mode particles) in automobile exhaust gas. The apparatus divides the gas sample into two parts, and each part is sent through one of two coaxially nested sections for analysis. For the scanning mode measurement, the nanoparticles are charged by 241Am and their size distributions are determined by varying the applied voltage over 2 min. The transient mode measurement, on the other hand, fixes the voltages for the two sections at peaks near 10 and 100 nm in order to monitor the transient behavior of the exhaust nanoparticles. The measurement principles and design of the dual-type DMA are detailed and the results for time response experiments are presented using model nanoparticles charged by a corona charger. The transient concentrations of the nuclei mode and the accumulation mode particles from a diesel engine were shown to be detected by this method, when 241Am was used for charging the particles. 相似文献
94.
In this paper, we report an efficient coupling scheme with relaxed misalignment tolerances. The proposed coupling scheme consists of two ball lenses of same diameter (1 mm) and different refractive indices. The second ball lens which is facing the fiber tip has a higher refractive index (1.833), whereas the first one which faces the laser diode has a refractive index of 1.5. Employing Gaussian and ABCD ray tracing optics, the theoretically obtained coupling efficiency can reach a unity with relaxed working distance (separation of the coupling system from the fiber tip) in the range between 1 and 4 mm at some optimum positions of the coupling lenses with regard to each other and to the facet of the laser diode. It has been found that if the distance between the first ball lens and the laser diode (d1) is fixed at 1.1 mm, which is twice its focal length, the coupling efficiency and the working distance as well as the misalignment tolerances are greatly affected by variation of the separation between the two ball lenses (s), and for this proposed coupling scheme the highest coupling efficiency and largest working distance are obtained when s is in the range of 0.3-0.35 mm. Above and below this range there is a significant reduction in the values of the above-mentioned parameters. Experimentally, the Nd:YAG laser welding system has been used for the alignment and welding of the coupling components in a butterfly configuration; the experimentally obtained coupling efficiency of the proposed coupling system was around 75% with relaxed working distance. From the effect of lateral and angular offsets on coupling efficiency, it is clearly noticed that the mode field of laser diode is transformed from elliptical into circular and hence effectively matched with that of the single-mode fiber. 相似文献
95.
Following the works of Nikiforov and Uvarov a review of the hypergeometric-type difference equation for a functiony(x(s)) on a nonuniform latticex(s) is given. It is shown that the difference-derivatives ofy(x(s)) also satisfy similar equations, if and only ifx(s) is a linear,q-linear, quadratic, or aq-quadratic lattice. This characterization is then used to give a definition of classical orthogonal polynomials, in the broad sense of Hahn, and consistent with the latest definition proposed by Andrews and Askey. The rest of the paper is concerned with the details of the solutions: orthogonality, boundary conditions, moments, integral representations, etc. A classification of classical orthogonal polynomials, discrete as well as continuous, on the basis of lattice type, is also presented. 相似文献
96.
Wei-Ming Yeoh Kim-Yang Lee Siang-Piao Chai Keat-Teong Lee Abdul Rahman Mohamed 《Journal of Physics and Chemistry of Solids》2013
The present work investigated the influence of calcination temperature for bimetallic Co–Mo/MgO catalyst on the synthesis of carbon nanotubes (CNTs) via catalytic chemical vapor deposition (CCVD) of methane. The experimental results showed that variation in the catalyst calcination temperature affected carbon yield, diameter distribution and quality of the CNTs. Increasing the catalyst calcination temperature enabled Co–Mo/MgO catalysts in growing CNTs at higher yield, narrower diameter distribution and better degree of graphitization, credited to the strong metal–support interaction (MSI) formed between CoO species and MgO support. We also discovered that the catalysts of weak MSI were beneficial to the nucleation and growth of CNTs, meanwhile the catalysts with strong MSI provoked the growth of CNTs with narrow diameter distribution. The catalyst calcined at 700 °C, possessing moderate MSI, was found to be the most suitable catalyst for the growth of high quality CNTs with the diameter of 7.70±0.77 nm and the carbon yield of as high as 647.4%. 相似文献
97.
We investigate transverse electromagnetic waves propagating in a plasma influenced by the gravitational field of the Schwarzschild-de
Sitter black hole. Applying 3+1 spacetime split we derive the relativistic two-fluid equations to take account of gravitational
effects due to the event horizon and describe the set of simultaneous linear equations for the perturbations. We use a local
approximation to investigate the one-dimensional radial propagation of Alfvén and high frequency electromagnetic waves. We
derive the dispersion relation for these waves and solve it for the wave number k numerically. 相似文献
98.
We present a summary of results of systematic first principles calculations of the electronic and geometric structures of the Cu2O(1 0 0) surface and the process of CO oxidation on this surface (energetics and pathways of adsorption, diffusion and reactions of CO and O2 on the surface). The (p, T) phase diagram of the Cu2O(1 0 0) in equilibrium of with gas phase O2 built using the ab initio thermodynamics approach suggests that the O-terminated surface is preferred over the Cu-terminated one within the entire ranges of pressures and temperatures in which the compound exists. Metastable Cu-terminated Cu2O(1 0 0) is found to undergo a surface reconstruction in agreement with experiment. We find CO to oxidize spontaneously on the O-terminated Cu2O(1 0 0) surface by consuming surface O atoms. Our calculations also show that the surface O-vacancies left in the course of the CO oxidation can be easily filled with dissociative adsorption of the gas phase O2 molecules, which are usually present in reaction environment. 相似文献
99.
Parametric Study of Nonplanar Dust Acoustic Solitons in Two‐Dimensional Superthermal Dusty Plasmas 下载免费PDF全文
The nonlinear properties of two dimensional low‐frequency electrostatic excitations of charged dust particles (or defects) are studied in a collisionless, unmagnetized dusty plasma. A fully ionized three‐component model plasma consisting of kappa distributed electrons, Maxwellian ions, and negatively charged massive dust grains is considered. In this regard, the well known reductive perturbation technique is used to the hydrodynamical equations and the Poisson equation, obtaining the cylindrical Kadomtsev–Petviashvili (CKP) equation. A parametric investigation indicates that the structural characteristics of these nonlinear excitations (width, amplitude) are significantly affected by the plasma nonthermality as well as by the relevant plasma parameters, such as dust concentration and dust temperature. (© 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
100.
M.S. Alam M.M. Rahman M.A. Sattar 《Communications in Nonlinear Science & Numerical Simulation》2009,14(5):2132-2143
The combined effect of viscous dissipation and joule heating on steady Magnetohydrodynamic heat and mass transfer flow of viscous incompressible fluid over an inclined radiate isothermal permeable surface in the presence of thermophoresis is studied. Numerical results for the dimensionless velocity, temperature and concentration profiles as well as the local skin-friction coefficient, the local Nusselt number and the local Stanton number are displayed graphically for various physical parameters. Comparisons with previously published work are performed and the results are found to be in very good agreement. Results show that rate of heat transfer is sensitive for increasing angle of inclination parameter for the case of fluid injection and it decreases with the increase of magnetic field parameter and Eckert number. 相似文献