Microcavity-controlled single-molecule fluorescence.

We present for the first time cavity-controlled fluorescence spectra and decay curves of single dipole emitters interacting at room temperature with the first longitudinal mode of a Fabry-Perot microcavity offering a lambda/2-spacing between its silver mirrors. The spontaneous emission rate of individual dye molecules was found to be enhanced by the Purcell effect by up to three times compared to the rate in free space, in agreement with theoretical predictions. Moreover, our new microcavity design was found to provide long-term stability and single-molecule sensitivity under ambient conditions for several months without noticeable reduction of the cavity-Q value. We consider this as a significant advance for single-photon sources operating at room temperature.     

Unusual hydrogen bonding behavior in binary complexes of coinage metal anions with water

We have studied the interaction of atomic coinage metal anions with water molecules by infrared photodissociation spectroscopy of M-.H2O.Ar(n) clusters (M=Cu, Ag, Au; n=1, 2). We compare our observations with calculations on density-functional and coupled cluster levels of theory. The gold anion is bound to the water molecule by a single ionic hydrogen bond, similar to the halide-water complexes. In contrast, zero-point motion in the silver and copper complexes leads to a deviation from this motif.     

Comparative thermostability of whey protein and alginate hydrospheres complexed with divalent cations

Journal of Thermal Analysis and Calorimetry - Water retention and thermostability of powders and films of whey protein isolate (WPIp, dWPIf), sodium alginate (NaALGp, NaALGf), and their dry...     

Higher-order ratios of baryon number cumulants

The relevance of higher order cumulants of net baryon number fluctuations for the analysis of freeze-out and critical conditions in heavy-ion collisions at LHC and RHIC is addressed. The sign structure of the higher order cumulants in the vicinity of the chiral crossover temperature might be a sensitive probe and may allow to elucidate their relation to the QCD phase transition. We calculate ratios of generalized quarknumber susceptibilities to high orders in three flavor QCD-like models and investigate their sign structure close to the chiral crossover line.