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151.
Seiji Yamaguchi Masao Mutoh Masaaki Shimakura Kunihiro Tsuzuki Yoshiyuki Kawase 《Journal of heterocyclic chemistry》1991,28(1):119-123
Some ω-(3-chromonyl)alkanoic acid derivatives, 1a and 2a , n = 4, 5; 3a, 4a and 5a , n = 2-6, were synthesized by cyclization of corresponding methyl ω-(2-hydroxybenzoyl)alkanoates 7b or ethyl ω-(2,4-dihydroxybenzoyl)alkanoates 8b with N,N-dimethylformamide-dimethyl acetal or acetic anhydride-DBU followed by hydrolysis. 相似文献
152.
Optical channel waveguides of meta-nitroaniline (m-NA) crystal, which has potential applications to nonlinear optical devices, have been fabricated on glass substrates having fine grooves. The crystal growth was performed by zone-melting, scanning a CO2 laser beam along the grooves filled with the polycrystal m-NA. Optical and X-ray observations showed that zone-melting changed the polycrystalline state to a single crystalline state with the 〈001〉 direction along the groove. The scattering loss for a 5 mm-long m-NA crystal waveguide (100 μm both in width and in depth) was found to decrease from 50 dB to 2.5 dB with this process. 相似文献
153.
We derive a theorem of exponential decay of correlation functions at high temperature for a general statistical mechanical system following the approach introduced by L. Gross. The theorem is formulated so as to be useful for locality problems in lattice quantum gravity. 相似文献
154.
Masao Kimura Roger S. Porter Gideon Salee 《Journal of Polymer Science.Polymer Physics》1983,21(3):367-378
Blends of poly(butylene terephthalate) (PBT) and a copolyester of bisphenol-A with 50% terephthalate-50% isophthalate (PAr), before and after transesterification, have been studied by thermal and dynamic mechanical tests to determine crystallinity and phase behavior. Blends without transesterification, as prepared by solution precipitation, show a single Tg, indicating amorphous miscibility of PBT and PAr. A melting-point depression for PBT crystals is not observed; this means that PBT crystallizes excluding PAr and the entropy of melting is small. The highest fractional crystallinity for PBT is obtained at 20-35% of PAr. Transesterified blends were obtained by holding the physical blends at 250°C for up to 16 h. The transesterified systems show higher Tg's than the corresponding physical blends and also show a marked melting-point depression and lesser PBT crystallinity at the corresponding increased PAr content. 相似文献
155.
156.
Yoshinori Asakawa Tsunematsu Takemoto Masao Toyota Takaaki Aratani 《Tetrahedron letters》1977,18(16):1407-1410
The stereostructures of the two new exceptional diterpene dialdehydes from the liverwort, Trichocoleopsis sacculata: sacculatal (1), responsible for the characteristic pungent taste, and isosacculatal (2) have been determined by the spectral evidence and by comparison with polygodial (3), isopolygodial (4), and drimanediol (6) of known relative configurations. 相似文献
157.
The heat capacity of 1T-TaS2 has been measured over the temperature range including the successive phase transitions (140 K–370 K) by an adiabatic calorimeter. There are three transitions in the measured temperature range, two first-order transitions (at about 226 K (T1) and about 353.5 K (T3)) and one small anomaly at about 283 K (T2) with a broad peak. The transition enthalpies are as follows; ΔH1=52±5 cal·mol-1, ΔH2=7.5±2 cal· mol-1 and ΔH3=122±8cal·mol-1. 相似文献
158.
A new optogalvanic technique with an rf discharge was applied to a high-resolution study of the Rydberg states of N2. The Ledbetter band, c4(0)1Πu ← a″(0)1Σg+, and a new visible band, c′5(0)1Σu+ ← a″(0)1Σg+, were studied at a Doppler-limited resolution of 0.05 cm?1. A Doppler-free method was also applied to resolve overlapped lines. Precise wavenumbers were determined for the rotational transitions of the two Rydberg bands. The rotational and the centrifugal constants for the lowest Rydberg state, a″(0)1Σg+, were determined to be B0 = 1.913748(42) cm?1 and D0 = 6.088(99) × 10?6 cm?1, where the numbers in parentheses are the standard deviation and apply to the last digits. 相似文献
159.
160.
The electrochemical behavior of ten nitrogen heterocycles was investigated in DMF-water and aqueous buffer solution. On the basis of these data, the effect of proton on the reduction behavior in DMF-water media and the reduction pathway in aqueous buffer solution ware phenomenologically classified. The adsorption phenomena in aqueous buffer solution and the correlation of reduction behavior with structure and reactivity were discussed. The structure of electrolytic products was also estimated and identified by negative electron density distributions of radical anion, GC-MS and spectrophotometry. 相似文献