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191.
Toshiyuki Abe Hidenobu Shiroishi Kosato Kinoshita Masao Kaneko 《Macromolecular Symposia》1998,131(1):81-86
It was found that photoelectrochemical water oxidation takes place at a polynuclear iron-cyanide complex-coated electrode called Berlin Brown (BB; Fe4III[FeIII(CN)6]33 3X). The electrode-coated BB showed electrocatalytic activity for water oxidation to produce O2 not only in the dark but also under illumination to result in photoinduced water oxidation. The amount of the photoelectrochemically produced O2 increased with the thickness of the BB film, indicating that the BB works as a bulk catalyst. 相似文献
192.
193.
Masao Doi 《Macromolecular Symposia》2003,195(1):101-108
OCTA (Open Computational Tool for Advanced material technology) is an integrated simulation system for polymeric materials developed by a joint project of industry and academia supported by Japanese government. It aims at exploring the utility of mesoscale modelings developed in polymer science. OCTA consists of four simulation engines (molecular dynamics engine, rheology engine, interface engine, multi-phase engine) and a simulation platform. The system is designed to be open and extendable: all programs and source codes can be downloaded at http://octa.jp. 相似文献
194.
Masao Takahashi Takeru Shishido Hitoo Iwasa Hikaru Kobayashi 《Central European Journal of Physics》2009,7(2):227-231
The local photovoltage of the pn-junction single-crystalline silicon solar cells observed by spot light scanning gradually
decreases in the vicinity of edges. The energy conversion efficiency is increased by shadowing the edge regions where the
local photovoltage is lower, showing that the defect density is high in the edge regions. From the analysis of the local photovoltage,
the spacial distribution of defect states is obtained. The cyanide method, i. e., immersion of solar cells in HCN solutions at room temperature, increases the local photovoltage and increases the energy
conversion efficiency.
相似文献
195.
Peter Bury Hikaru Kobayashi Masao Takahashi Kentaro Imamura Peter Sidor Franti??ek ??ernobila 《Central European Journal of Physics》2009,7(2):237-241
Ultrathin silicon dioxide (SiO2) layers formed on Si substrate with nitric acid have been investigated using both acoustic deep-level transient spectroscopy
(A-DLTS) and electrical methods to characterize the interface states. The set of SiO2/Si structures formed in different conditions (reaction time, concentrations of nitric acid (HNO3), and SiO2 thickness [3–9 nm]) was prepared. The leakage current density was decreased by post-oxidation annealing (POA) treatment at
250°C in pure nitrogen for 1 h and/or post-metallization annealing (PMA) treatment at 250°C in a hydrogen atmosphere for 1
h. All structures of the set, except electrical investigation, current-voltage (I - V), and capacitance — voltage (C - V) measurements, were investigated using A-DLTS to find both the interface states distribution and the role of POA and/or PMA
treatment on the interface-state occurrence and distribution. The evident decreases of interface states and shift of their
activation energies in the structures with PMA treatment in comparison with POA treatment were observed in most of the investigated
structures. The results are analyzed and discussed.
相似文献
196.
Miho Tanaka Kazuya Takahashi Tatsuya Urabe Tomohiro Oikawa Masao Nemoto Hideki Nagashima 《Rapid communications in mass spectrometry : RCM》2009,23(5):698-704
Silica, represented by SiO2, is the general name for the compounds composed of Si, O and H with their derivative complexes. Silica forms various chemical species in aquatic solutions, such as a monomer (Si(OH)3O−), dimer (Si2(OH)5O), and others. These species are known to vary in their relative abundances in solution depending on the chemical and physical conditions. Silica species dissolved in seawater have been examined by fast-atom bombardment mass spectrometry (FAB-MS) to elucidate the behavior of silica and its circulation as a novel tracer reflecting the chemical and physical conditions of seawater and the bioactivity of diatoms, which take up silica. In the seawater of Tokyo Bay, silica species such as [Si(OH)2O2Na]− ([monomer–Na]−), [Si2(OH)5O2]− ([dimer]−), [Si2(OH)4O3Na]− ([dimer–Na]−), [Si4(OH)7O5]− ([cyclic tetramer]−), [Si4(OH)6O6Na]− ([cyclic tetramer–Na]−), [Si4(OH)9O4]− ([linear tetramer]−) and [Si4(OH)8O5Na]− ([linear tetramer–Na]−) were observed and assigned by FAB-MS. To investigate the suitability of silica species as a tracer, the relative peak intensity ratios of silica species observed in the mass spectra, i.e. the profiles of the ratio of the linear tetramer to the cyclic tetramer (m/z 329/311) and the ratio of the dimer to the cyclic tetramer (m/z 173/311) against depth, were examined to determine the annual changes and reproducibility of the depth profiles. In particular, the depth profile of the relative ratio of the linear tetramer to the cyclic tetramer, 329/311, exhibits critical changes depending on the seawater budget. These changes in the relative ratios were identified by an experiment involving a simple sodium chloride solution system. Our measurement is expected to elucidate the dynamics of silica and its role as ‘food’ for diatoms, and we showed that speciation using mass spectrometry is a powerful tool for examining elemental behavior in nature and environmental changes. Our results suggest that a silica tracer is useful for investigating the behavior of seawater in small coastal regions and the uptake of silica by diatoms. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
197.
Three new monoterpene glucosides, lamiuamplexosides A–C ( 1 – 3 ), along with thirteen known glucosides, were isolated from the whole plant of Lamium amplexicaule L. The structures of 1 – 3 were elucidated on the basis of spectroscopic, chemical, and physicochemical evidence. 相似文献
198.
Shiho Hirohara Makoto Obata Hiroki Alitomo Kohei Sharyo Tsuyoshi Ando Masao Tanihara Shigenobu Yano 《Journal of photochemistry and photobiology. B, Biology》2009,97(1):22-33
Eight S-glycosylated 5,10,15,20-tetrakis(tetrafluorophenyl)porphyrins (1a′, 1b′, 1a and 1b (a: S-glucosylated, b: S-galactosylated)) and their 1,3-dipolar cycloadducts, i.e. chlorins 2a′, 2b′, 2a and 2b were prepared by nucleophilic substitution of the pentafluorophenyl groups with S-glycoside. These photosensitizers were characterized by 1H, 13C and 19F NMR spectroscopies and elemental analysis. The photocytotoxicity of the S-glycosylated photosensitizers and the parent porphyrin (1) and chlorin (2) was examined in HeLa cells. Photosensitizers 1, 2, 1a′, 1b′, 2a′ and 2b′ showed no significant photocytotoxicity at the concentration of 0.5 μM, while the deprotected photosensitizers 1a, 1b, 2a and 2b were photocytotoxic. The strong inhibition by sodium azide of the photocytotoxicity of these photosensitizers suggested that 1O2 is the main mediator. The S-glucosylated photosensitizers 1a and 2a showed higher photocytotoxicity than S-galactosylated 1b and 2b, respectively. The cellular uptake of 1a and 2a increased up to 24 h, while that of 1b and 2b was saturated by 12 h. 相似文献
199.
Masao Tsugaki 《Combinatorica》2009,29(1):127-129
A tree T is called a k-tree, if the maximum degree of T is at most k. In this paper, we prove that if G is an n-connected graph with independence number at most n + m + 1 (n≥1,n≥m≥0), then G has a spanning 3-tree T with at most m vertices of degree 3. 相似文献
200.
We consider the stochastic linear complementarity problem (SLCP) involving a random matrix whose expectation matrix is positive semi-definite. We show that the expected residual minimization (ERM) formulation of this problem has a nonempty and bounded solution set if the expected value (EV) formulation, which reduces to the LCP with the positive semi-definite expectation matrix, has a nonempty and bounded solution set. We give a new error bound for the monotone LCP and use it to show that solutions of the ERM formulation are robust in the sense that they may have a minimum sensitivity with respect to random parameter variations in SLCP. Numerical examples including a stochastic traffic equilibrium problem are given to illustrate the characteristics of the solutions. 相似文献