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971.
972.
Seven differently glycosidated sugar amino acids (SSAs) derived from glucosamine have been prepared. Following standard solution‐phase peptide‐coupling procedures, the glycosidated 2‐amino‐2‐deoxy‐D ‐glucopyranosiduronic acids were condensed with natural amino acids to furnish useful heterodi‐ and ‐trimeric building blocks to be used in peptide synthesis. Combinations of these building blocks yielded hetero‐oligomeric peptides with two sugar amino acid units in different distances to each other. These were prepared to evaluate the influence of glycosidic side chains on the peptide backbone. Conformations of selected examples were examined by means of ROESY spectroscopy in combination with molecular dynamics (MD) simulations and circular‐dichroism (CD) studies. 相似文献
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975.
Petr Munster Tomas Horvath Josef Vojtech Ondrej Havlis Martin Slapak Pavel Skoda 《Fiber and Integrated Optics》2017,36(3):144-156
Currently, individual optical fibers are mostly used for each non-data application, which is very inefficient and uneconomical. Sharing a single fiber for multiple applications is a promising solution. However, in the case of a non-data application, the situation is much more complicated compared to data because of special application´s requirements. In laboratory setup, we performed a measurement with a standard G.652D optical fiber for analyzing possible interaction of stable frequency/accurate time transmission, 1.25/10Gbps data transmission (typical bitrates for access point-to-point networks), and high-power sensor signal for different channel spacing and different pulse duration of sensor signal. 相似文献
976.
Dr. Nina Erini Vera Beermann Martin Gocyla Manuel Gliech Dr. Marc Heggen Dr. Rafal E. Dunin-Borkowski Prof. Peter Strasser 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(23):6633-6638
Direct ethanol fuel cells are attractive power sources based on a biorenewable, high energy-density fuel. Their efficiency is limited by the lack of active anode materials which catalyze the breaking of the C−C bond coupled to the 12-electron oxidation to CO2. We report shape-controlled PtNiRh octahedral ethanol oxidation electrocatalysts with excellent activity and previously unachieved low onset potentials as low as 0.1 V vs. RHE, while being highly selective to complete oxidation to CO2. Our comprehensive characterization and in situ electrochemical ATR studies suggest that the formation of a ternary surface site ensemble around the octahedral Pt3Ni1Rhx nanoparticles plays a crucial mechanistic role for this behavior. 相似文献
977.
Vincent Martin Thibault Le Bourdon Alexander Mattioli Pasqual 《Journal of sound and vibration》2011,330(17):4233-797
Acoustical holography can be used to identify the vibration velocity of an extended vibrating body. Such an inverse problem relies on the radiated acoustic pressure measured by a microphone array and on an a priori knowledge of the way the body radiates sound. Any perturbation on the radiation model leads to a perturbation on the velocity identified by the inversion process. Thus, to obtain the source vibration velocity with a good precision, it is useful to identify also an appropriate propagation model. Here, this identification, or adaptation, procedure rests on a geometrical interpretation of the acoustic holography in the objective space (here the radiated pressure space equipped with the L2-norm) and on a genetic algorithm.The propagator adaptation adds information to the holographic process, so it is not a regularisation method, which approximates the inverse of the model but does not affect the model. Moreover regularisations act in the variables space, here the velocities space. It is shown that an adapted model significantly decreases the quantity of regularisation needed to obtain a good reconstructed velocity, and that model adaptation improves significantly the acoustical holography results.In the presence of perturbations on the radiated pressure, some indications will be given on the interest or not to adapt the model, again thanks to the geometrical interpretation of holography in the objective space.As a numerical example, a disc whose vibration velocity on one of its sides is identified by acoustic holography is presented. On an industrial scale, this problem occurs due to the noise radiated by car wheels. The assessment of the holographic results has not yet been rigorously performed in such situations due to the complexity of the wheel environment made up of the car body, road and rolling conditions. 相似文献
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Desaktivierung von Pd‐Katalysatoren zur Acetoxylierung: direkte Beobachtung durch XPS‐Untersuchungen