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121.
The orientational ordering of several liquid crystals containing a difluorosubstituted phenyl ring has been studied through the use of C-13 NMR. The fluorinated phenyl ring of these liquid crystals have Cs symmetry, so three order parameters are required to completely describe the ordering of this ring. All three of these order parameters have been calculated from carbon-fluorine dipolar coupling constants obtained from the carbon-fluorine splittings in the C-13 NMR spectra. Because of the complexity of the fluorine-coupled spectra, variable angle spinning (VAS) was used to resolve the carbon-fluorine splittings. In order to study the orientational ordering over wide ranges of temperature, we have developed an empirical correlation between the order parameter and the value of a carbon-fluorine dipolar coupling constant. This enabled us to study the change in the order parameter with temperature. The results of applying this method to several structurally similar liquid crystals containing the same type of difluorinated phenyl ring are presented. A comparison is made to a similar mono-fluorinated liquid crystal. 相似文献
122.
A review of otoacoustic emissions 总被引:32,自引:0,他引:32
R Probst B L Lonsbury-Martin G K Martin 《The Journal of the Acoustical Society of America》1991,89(5):2027-2067
Otoacoustic emissions measured in the external ear canal describe responses that the cochlea generates in the form of acoustic energy. For the convenience of discussing their principal features, emitted responses can be classified into several categories according to the type of stimulation used to evoke them. On this basis, four distinct but interrelated classes can be distinguished including spontaneous, transiently evoked, stimulus-frequency, and distortion-product otoacoustic emissions. The present review details the findings that have been described for each emission type according to this classification schema. Additionally, the known features of emitted responses are discussed for both normally hearing and hearing-impaired humans and experimental animals, and with respect to their potential clinical applications. The findings reviewed here clearly indicate that future studies of otoacoustic emissions will significantly increase our understanding of the basic mechanisms of cochlear function while, at the same time, provide a new and important clinical tool. 相似文献
123.
V.A. Khoze A.D. Martin M.G. Ryskin 《The European Physical Journal C - Particles and Fields》2002,24(3):459-468
The rich structure of photon-exchange processes at hadron colliders is studied. We discuss central vector meson production
, W production and production. Each process has distinct, and large, soft pp rescattering effects, which can be directly observed by detecting the outgoing protons. This allows a probe of the optical
density of the proton, which plays a crucial role in the evaluation of the rapidity gap survival probabilities in diffractive-like
processes at hadron colliders. We note that an alternative mechanism for production is odderon, instead of photon, exchange; and that the ratio of odderon to photon contributions is enhanced (suppressed)
for vector meson production.
Received: 1 February 2002 / Revised version: 4 April 2002 / Published online: 22 May 2002 相似文献
124.
Jan Andres Karel Pastor Pavla Šnyrychová 《Journal of Fixed Point Theory and Applications》2007,2(1):153-170
A multivalued version of Sharkovskiĭ’s theorem is formulated for M-maps on linear continua and, more generally, for triangular M-maps on a Cartesian product of linear continua. This improves the main result of [AP1] in the sense that our multivalued
analogue holds with at most two exceptions. A further specification requires some additional restrictions. For instance, 3-
orbits of m-maps imply the existence of k-orbits for all
k ? \mathbbNk \in {\mathbb{N}}
, except possibly for
k ?k \in
{4, 6}. It is also shown that, on every connected linearly ordered topological space, an M-map with orbits of all periods can always be constructed. This demonstrates that Baldwin’s classification of linear continua
in terms of admissible periods [Ba] is useless for multivalued maps. 相似文献
125.
Influence of boric acid on the electrochemical deposition of Ni 总被引:1,自引:0,他引:1
M. Šupicová R. Rozik L. Trnková R. Oriňáková M. Gálová 《Journal of Solid State Electrochemistry》2006,10(2):61-68
The electrolytic deposition of Ni onto a paraffin-impregnated graphite electrode from supporting chloride electrolyte (0.5 mol dm−3 NaCl) adjusted to the required pH using dilute HCl is investigated. The effect of electrolyte composition on the Ni electrodeposition
is studied using linear sweep voltammetry in the cathodic region. An elimination voltammetry procedure was applied to evaluate
the polarization curves. The aim of this work was to deduce the mechanism of Ni reduction in the chloride bath as well as
the influence of boric acid on this. Positively-charged NiCl+ ions were found to be the electroactive particles in the Ni reduction mechanism. The strong competition between the NiCl+, Cl− and H+ ions for active sites at the electrode is discussed. Kinetically-controlled adsorption/desorption processes of various species
were also confirmed using elimination voltammetry with a linear scan. The evolution of gaseous hydrogen, catalyzed by the
freshly-deposited Ni, accompanies the electrodeposition process. The presence of boric acid at a sufficiently high concentration
inhibits the deposition of Ni and, at the same time, improves the morphology and brightness, as well as the adhesion of the
deposited Ni.
Elimination voltammetry with a linear scan is an efficient way to evaluate current–potential curves that reflect the electrodeposition
of one-component Ni coatings. By eliminating selected currents, additional interesting and useful information can be obtained
from voltammetric data. 相似文献
126.
Martin Loeser Lorenzo Occhi Christian Vélez Raffaele Rezzonico Bernd Witzigmann 《Optical and Quantum Electronics》2006,38(12-14):1069-1075
The impact of self-heating and cavity length on the spectral emission properties of SLEDs is investigated using a state-of-the-art simulation tool. Simulated data are compared to measurements for two InP-based benchmark devices operating around 1300 nm, and excellent agreement is achieved in either case. 相似文献
127.
Motivated by Gauss's first proof of the Fundamental Theorem of Algebra, we study the topology of harmonic algebraic curves.
By the maximum principle, a harmonic curve has no bounded components; its topology is determined by the combinatorial data
of a noncrossing matching. Similarly, every complex polynomial gives rise to a related combinatorial object that we call a
basketball, consisting of a pair of noncrossing matchings satisfying one additional constraint. We prove that every noncrossing
matching arises from some harmonic curve, and deduce from this that every basketball arises from some polynomial. 相似文献
128.
Pavol Ševera 《Letters in Mathematical Physics》2006,75(3):273-277
We introduce an affine-invariant version of generating functions of symplectic transformations of affine symplectic spaces,
together with a generalization for other symmetric symplectic spaces. The composition of these functions has a nice connection
with the Moyal product. 相似文献
129.
Andrew S. Zektzer Gary E. Martin Raymond N. Castle 《Journal of heterocyclic chemistry》1987,24(3):879-884
Phenanthro[3,4:3′,4′]phenanthro[2,1-b]thiophene ( 1 ) served as the model system to evaluate two-dimensional proton zero quantum coherence nmr in order to establish the vicinal proton-proton connectivities. The utility of the two-dimensional proton zero quantum nmr experiment has been compared with the utility of the traditional autocorrelated proton-proton (COSY) experiment. In the case of a molecule such as 1 , where the proton chemical shifts are so highly congested, the zero quantum coherence experiment provides data not obtainable from the COSY experiment. 相似文献
130.
We give a self‐contained proof of the preservation theorem for proper countable support iterations known as “tools‐preservation”, “Case A” or “first preservation theorem” in the literature. We do not assume that the forcings add reals. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献