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991.
Andrew Mills Anne Lepre Nicholas Elliott Sharan Bhopal Ivan P. Parkin S. A. ONeill 《Journal of photochemistry and photobiology. A, Chemistry》2003,160(3):213-224
Pilkington Glass Activ™ represents a possible suitable successor to P25 TiO2, especially as a benchmark photocatalyst film for comparing other photocatalyst or PSH self-cleaning films. Activ™ is a glass product with a clear, colourless, effectively invisible, photocatalytic coating of titania that also exhibits PSH. Although not as active as a film of P25 TiO2, Activ™ vastly superior mechanical stability, very reproducible activity and widespread commercial availability makes it highly attractive as a reference photocatalytic film. The photocatalytic and photo-induced superhydrophilitic (PSH) properties of Activ™ are studied in some detail and the results reported. Thus, the kinetics of stearic acid destruction (a 104 electron process) are zero order over the stearic acid range 4–129 monolayers and exhibit formal quantum efficiencies (FQE) of 0.7×10−5 and 10.2×10−5 molecules per photon when irradiated with light of 365±20 and 254 nm, respectively; the latter appears also to be the quantum yield for Activ™ at 254 nm. The kinetics of stearic acid destruction exhibit Langmuir–Hinshelwood-like saturation type kinetics as a function of oxygen partial pressure, with no destruction occurring in the absence of oxygen and the rate of destruction appearing the same in air and oxygen atmospheres. Further kinetic work revealed a Langmuir adsorption type constant for oxygen of 0.45±0.16 kPa−1 and an activation energy of 19±1 kJ mol−1. A study of the PSH properties of Activ™ reveals a high water contact angle (67°) before ultra-bandgap irradiation reduced to 0° after prolonged irradiation. The kinetics of PSH are similar to those reported by others for sol–gel films using a low level of UV light. The kinetics of contact angle recovery in the dark appear monophasic and different to the biphasic kinetics reported recently by others for sol–gel films [J. Phys. Chem. B 107 (2003) 1028]. Overall, Activ™ appears a very suitable reference material for semiconductor film photocatalysis. 相似文献
992.
K. K. Kadyrzhanov S. Khazhekber S. N. Lukashenko V. P. Solodukhin I. V. Kazachevskiy V. L. Poznyak B. B. Knyazev Ch. Rofer 《Czechoslovak Journal of Physics》2003,53(1):A39-A44
Data on the spatial distribution of radionuclides (241Am, 239Pu, 137Cs and 152Eu) formed during nuclear explosions of different types near P2 SNTS test site are presented. Radionuclide contamination induced by the explosions varies in the concentrations of individual radionuclides, their proportions and species. Examination of the variations is a crucial task to plan remediation activities as well as those aimed at decrease of radiation risk for population and prevention of repeated contamination. Concentrations of 241Am and 239+240Pu that are the most toxic radionuclides in the area lie in hundred thousands of Bqkg?1. The most contaminated areas are classified by the radionuclide concentration, ratio and form present in soil. 相似文献
993.
994.
Pyroelectric effect in lead-magnoniobate-based solid solutions 总被引:1,自引:0,他引:1
E. P. Smirnova S. E. Aleksandrov K. A. Sotnikov A. A. Kapralov A. V. Sotnikov 《Physics of the Solid State》2003,45(7):1305-1309
A coordinated study of the dielectric, electrostriction, and pyroelectric properties of the lead-magnoniobate-based ceramic solid solutions 0.9PbMg1/3Nb2/3O3-0.1PbTiO3 and 0.55PbMg1/3Nb2/3O3-0.45PbSc1/2Nb1/2O3 conducted at the relaxor transition temperatures is reported. Electromechanical coupling stimulated by the giant electrostriction effect is shown to play an essential part in the pyroelectric effect. 相似文献
995.
This paper investigates the existence of positive solutions of a singular boundary value problem with negative exponent similar
to standard Emden-Fowler equation. A necessary and sufficient condition for the existence of C[0, 1] positive solutions as
well as C1[0, 1] positive solutions is given by means of the method of lower and upper solutions with the Schauder fixed point theorem. 相似文献
996.
The enthalpies of formation of simple nonmetal or metalloid oxyanions in aqueous solution are discussed. Archival values are cited and estimates are made. Trends prove evasive. 相似文献
997.
A method for suppressing self-modulation in backward-wave tubes is proposed. Additional delay is introduced into the feedback
circuit, owing to which the output signal amplitude affects the electron beam current that enters into the interaction space.
Numerical simulations demonstrate that the operating current in the single-frequency oscillation mode may be increased roughly
twofold. 相似文献
998.
Faitel'son E. A. Korkhov V. P. Aniskevich A. N. Starkova O. A. 《Mechanics of Composite Materials》2004,40(1):57-66
The results of a complex study of structural changes in a cured Norpol 440 polyester resin under the action of damp environment and mechanical loading are presented. A considerable effect of absorbed moisture on the structure and some characteristics of the material is revealed by using thermophysical methods and X-ray diffractometry. The joint effect of moisture and mechanical stress is estimated by investigating the creep in stationary and nonstationary moisture conditions. The anisotropy of the material structure formed during creep is evaluated from the results of dilatometric measurements. It is found that the degree of anisotropy of the material after creep accompanied by moisture sorption is higher than that after creep in the conditions of moisture equilibrium with atmosphere. It is established that the aftercure and relaxation of the residual creep deformation come to an end at heating to 80-85°C. At a further rise in temperature and repeated heating, changes in the material structure are not observed. 相似文献
999.
Cao H. P. Chen G. Grechkoseeva M. A. Mazurov V. D. Shi W. J. Vasil'ev A. V. 《Siberian Mathematical Journal》2004,45(6):1031-1035
The spectrum of a finite group is the set of its element orders. A finite group G is said to be recognizable by spectrum, if every finite group with the same spectrum as G is isomorphic to G. The purpose of the paper is to prove that for every natural m the finite simple Chevalley group F
4(2
m
) is recognizable by spectrum. 相似文献
1000.