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941.
Spectroscopic characterization of mineral crystals produced by the bacterium Azospirillum brasilense
Kamnev AA Antonyuk LP Chernyshev AV Ignatov VV De Vargas MC 《Analytical and bioanalytical chemistry》1996,355(5-6):739-741
The results of spectroscopic structural and trace elemental analyses of mineral crystals produced by the soil nitrogen-fixing bacterium Azospirillum brasilense cultivated in a synthetic medium are presented and discussed. The mineral formed is shown to have a structure close to struvite (MgNH(4)PO(4) x 6H(2)O; ASTM file No. 15-762) with some differences which may be attributed to the presence of isomorphic admixtures of other cations (struvite is known to have a variety of forms). AAS/AES and ion chromatography analyses for a number of biologically important microelements and their role in the formation of the crystal structure, as well as some questions related to biomineralization are also discussed. 相似文献
942.
The 4-(trimethyl tin)butyl-2 radical, prepared and excited by the chemical activation reaction of H atoms with 4-(trimethyl tin)butene-1, was found to randomize its excess internal vibrational energy on a subpicosecond time scale. This result differs from an earlier study on the decomposition of 3-(triallyl tin)-2-fluoropropyl radical in which heavy-atom blocking of internal relaxation was reported. 相似文献
943.
The arylation of fluorobenzene with pentafluorophenyl radicals obtained by the reaction of the corresponding aniline with pentyl nitrite is described. The reaction involves attact at the 2t?-,3t?-and 4t?-positions. The composition of the mixture and the nature of its components were determined by 19F NMR spectroscopy and were confirmed by gas-liquid chromatography. 相似文献
944.
The preparation and use of a stainless steel indicator electrode in the accurate potentiometric titration of aqueous hydrogen peroxide are described. The results agree excellently with those obtained by a standard colorimetric weight-titration procedure. The nature of the titration curves, potential changes and the factors affecting them are discussed. Rapid potentiometric titrations directly to the equivalence-point potential are possible, owing to the nature of the titration curve. 相似文献
945.
Simone Gallarati Raimon Fabregat Rubn Laplaza Sinjini Bhattacharjee Matthew D. Wodrich Clemence Corminboeuf 《Chemical science》2021,12(20):6879
Hundreds of catalytic methods are developed each year to meet the demand for high-purity chiral compounds. The computational design of enantioselective organocatalysts remains a significant challenge, as catalysts are typically discovered through experimental screening. Recent advances in combining quantum chemical computations and machine learning (ML) hold great potential to propel the next leap forward in asymmetric catalysis. Within the context of quantum chemical machine learning (QML, or atomistic ML), the ML representations used to encode the three-dimensional structure of molecules and evaluate their similarity cannot easily capture the subtle energy differences that govern enantioselectivity. Here, we present a general strategy for improving molecular representations within an atomistic machine learning model to predict the DFT-computed enantiomeric excess of asymmetric propargylation organocatalysts solely from the structure of catalytic cycle intermediates. Mean absolute errors as low as 0.25 kcal mol−1 were achieved in predictions of the activation energy with respect to DFT computations. By virtue of its design, this strategy is generalisable to other ML models, to experimental data and to any catalytic asymmetric reaction, enabling the rapid screening of structurally diverse organocatalysts from available structural information.A machine learning model for enantioselectivity prediction using reaction-based molecular representations. 相似文献
946.
A.B. Antonova N.E. Kolobova P.V. Petrovsky B.V. Lokshin N.S. Obezyuk 《Journal of organometallic chemistry》1977,137(1):55-67
A rearrangement of transition metal acetylenic π-complexes into compounds with vinylidene n-ligands has been established. Compounds CpMn(CCHPh)-(CO)2 and Cp2Mn2(μ-CCHPh)(CO)4 with terminal and bridging phenylvinylidene (benzylidenecarbene) ligands respectively were obtained from the π-complexes CpMn(CO)2(PhCCR) where R H, Ph3Ge or Ph3Sn. Reactions leading to conversion of the terminal CCHPh group into a bridging ligand and vice versa were studied. Under the action of L Ph3P, (EtO)3P or (PhO)3P, substitution of CO groups in vinylidene complexes takes place and compounds CpMn(CCHPh)-(CO)L are formed. IR, 1H and 13C NMR spectra of the novel complexes are discussed. The data obtained indicate an electron-withdrawing property of the CCHPh ligand and stronger bonding of this ligand to the metal as compared with a CO group. 相似文献
947.
U Aebi R K Bijlenga B ten Heggeler J Kistler A C Steven P R Smith 《Journal of supramolecular structure》1976,5(4):475-495
A study has been made of the structure of the capsids of T4D giant phage produced from mutants in gene 23 and temperature-sensitive mutants in gene 24, and T4D and T2L giant phage formed by the addition of L-canavanine followed by an Larginine chase in the growth medium. All the giant phage capsids have been shown to be built according to the same geometrical architecture. This consists of a near-hexagonal surface net, lattice constant 129.5 A, folded into a left-handed T = 13 prolate icosahedron elongated along one of its fivefold symmetry axes. Their only apparent difference from wild-type T-even phage capsids is their abnormally elongated tubular part. A comparison of the capsomere morphologies and protein compositions of the giant phage capsids showed that all T4D giants are identical but differ from T2L: The T4D capsomere has a complex (6 + 6 + 1)-type morphology, whereas the T2L has a simple 6-type. T2L phage, however, lack two capsid proteins, "soc" and "hoc", present in T4D. The difference in capsomere morphology can therefore be related to the difference in the protein compositions of these two phage. Possible differences between the initiation and means of length regulation of giant phage heads and the aberrant polyheads are discussed. 相似文献
948.
A synthesis of a variety of nine-membered ring intermediates in the cleavaminevelbanamine series is described. The formation of the penultimate intermediate involves a fragmentation reaction in which the cleavamine system is generated from an appropriate rigid pentacyclic Iboga alkaloid derivative. Thus dihydrocatharanthinol tosylate (VIII) on reaction with triethylamine in refluxing benzene undergoes fragmentation to the 5, 18-seco-diene X. This latter substance is then elaborated in various ways to the desired compounds. 相似文献
949.
A systematic study of the adsorption and interfacial behaviour of the adenine mono-nucleotides (5′-AMP, 3′-AMP, cyclic 3′,5′-AMP, 5′-ADP and 5′-ATP) and adenosine for comparison at the HMDE has been carried out at pH 3.4 to 3.5. Thus, the N(1) of the adenine moiety is protonated to a major extent.The adsorption was followed by single sweep voltammetry (measurement of the time integral of the reduction peak of the adsorbed adenine moiety) and by a.c. voltammetry (out-of-phase component of the a.c. response being proportional to the differential double layer capacity). In this paper the situation corresponding to a “dilute” adsorption layer existing at low bulk concentrations is studied for various degrees of coverage. The potential dependence of the coverage is of bell shaped type with an extended maximum region around the potential of electrocapillary maximum (Eecm) of the blank. For the same bulk concentration the coverage decreases in the series AMP, ADP, ATP, i.e. with increasing negative charge of the nucleotide, and at the same time the potential range of adsorption narrows. Among the monophosphates the coverage decreases in the series 3′-AMP, 5′-AMP, cyclic 3′,5′-AMP. The variations are connected with the varying charge of the mononucleotides and with the possibilities for interactions with adjacent molecules in the adsorption layer.At elevated bulk concentrations above a threshold value a substantial increase in coverage occurs around Eecm as due to strong interactions between the adsorbed base moieties a rather compact film is formed. 相似文献
950.
The NaNCS complex of the macrotetrolide antibiotic nonactin, which acts as an ionophore with biological and artificial membranes crystallizes in the space group C2/c, a = 15.55, b = 19.59, c = 15.31 Å, β = 90°. The X-ray crystal structure investigation shows that Na+ is coordinated by four carbonyl oxygen atoms (Na+ … O, 2.42 Å) and four ether oxygen atoms (Na+ … O, 2.77 Å). The cubic coordination by eight equidistant oxygen atoms observed in the K+ complex (K+ … O, 2.81 Å) is thus deformed. This, however, requires only very small changes in the ligand conformation. 相似文献