Zwei Vorrichtungen zum sicheren Ablesen des Volumens von Gasen

Ohne Zusammenfassung     

Liquid chromatography–tandem mass spectrometry analysis of neonicotinoid pesticides and 6-chloronicotinic acid in environmental water with direct aqueous injection

An efficient, high throughput and cost-effective direct aqueous injection approach for the analysis of neonicotinoid pesticides and a common metabolite in environmental water has been described here. The method determines eight neonicotinoid pesticides (acetamiprid, clothianidin, dinotefuran, flonicamid, imidacloprid, nitenpyram, thiacloprid, thiamethoxam) and 6-chloronicotinic acid (a common metabolite of the first generation neonicotinoids, acetamiprid, imidacloprid, nitenpyram and thiacloprid) without any sample enrichment/cleanup steps. The method detection limits are 2–8 ng/L for the neonicotinoids and 93 ng/L for 6-chloronicotinic acid. The performance of the QTRAP^®5500 mass spectrometer was compared against a 4000QTRAP^®, and a QTRAP^®6500, to provide insights for future method transfer among different generations of instrumentations. Critical mass spectrometric parameters such as collision energy were quite consistent among the three instruments evaluated. However, increased chemical background levels for some target compounds on the more sensitive instruments were observed. The application of differential ion mobility spectrometry combined with tandem mass spectrometry was demonstrated to have great potential in reducing chemical background and/or isobaric interferences inherited in sample matrices. This ISO 17025 accredited method was employed to quantitate neonicotinoids in Ontario stream water samples. Good correlation for analytical results of this direct aqueous injection approach and a previously published solid phase extraction approach warrant high confidence in data quality.     

Enantioselective counter-anions in photoredox catalysis: The asymmetric cation radical Diels-Alder reaction

Control of absolute stereochemistry in radical and ion radical transformations is a major challenge in synthetic chemistry. Herein, we report the design of a photoredox catalyst system comprised of an oxidizing pyrilium salt bearing a chiral N-triflyl phosphoramide anion. This class of chiral organic photoredox catalysts is able to catalyze the formation of cation radical-mediated Diels-Alder transformations in up to 75:25 e.r. in both intramolecular and intermolecular examples.     

Acoustic quasi-holographic images of scattering by vertical cylinders from one-dimensional bistatic scans

When synthetic aperture sonar (SAS) is used to image elastic targets in water, subtle features can be present in the images associated with the dynamical response of the target being viewed. In an effort to improve the understanding of such responses, as well as to explore alternative image processing methods, a laboratory-based system was developed in which targets were illuminated by a transient acoustic source, and bistatic responses were recorded by scanning a hydrophone along a rail system. Images were constructed using a relatively conventional bistatic SAS algorithm and were compared with images based on supersonic holography. The holographic method is a simplification of one previously used to view the time evolution of a target's response [Hefner and Marston, ARLO 2, 55-60 (2001)]. In the holographic method, the space-time evolution of the scattering was used to construct a two-dimensional image with cross range and time as coordinates. Various features for vertically hung cylindrical targets were interpreted using high frequency ray theory. This includes contributions from guided surface elastic waves, as well as transmitted-wave features and specular reflection.     

Acoustic radiation torque and the conservation of angular momentum (L)

This note concerns the evaluation of the static acoustic radiation torque exerted by an acoustic field on a scatterer immersed in a nonviscous fluid based on far-field scattering. The radiation torque is expressed as the integral of the time-averaged flux of angular momentum over a spherical surface far removed from the scattering object with its center at the centroid of the object. That result was given previously [G. Maidanik, J. Acoust. Soc. Am. 30, 620-623 (1956)]. Another expression given recently [Z. W. Fan et al., J. Acoust. Soc. Am. 124, 2727-2732 (2008)] is simplified to this formula. Comments are made on obtaining it directly from the general theorem of angular momentum conservation in the integral form.     

Precise measurement of the positive muon anomalous magnetic moment

A precise measurement of the anomalous g value, a(mu) = (g-2)/2, for the positive muon has been made at the Brookhaven Alternating Gradient Synchrotron. The result a(mu+) = 11 659 202(14) (6) x 10(-10) (1.3 ppm) is in good agreement with previous measurements and has an error one third that of the combined previous data. The current theoretical value from the standard model is a(mu)(SM) = 11 659 159.6(6.7) x 10(-10) (0.57 ppm) and a(mu)(exp) - a(mu)(SM) = 43(16) x 10(-10) in which a(mu)(exp) is the world average experimental value.     

Backscattering enhancements from Rayleigh waves on the flat face of a tilted solid cylinder in water

When the face of a finite solid elastic cylinder is ensonified by an acoustic wave, a variety of backscattering contributions associated with acoustic wave coupling into elastic waves are observed. A significant backscattering enhancement is observed for tilts such that the acoustic wave is incident on the face of the cylinder in the vicinity of the coupling angle for launching Rayleigh waves across the face. The observed backscattering indicates that the Rayleigh waves are reflected at the edge of the face and subsequently radiate acoustic waves in the backscattering direction. The measured backscattering is compared to an approximate theoretical prediction. Approximating the focusing of the Rayleigh wave after reflection at the (circular) edge by a Gaussian beam pressure distribution on the cylinder's face yields simple expressions for the amplitude which are consistent with the measurements. In the vicinity of end-on incidence, other backscattering contributions due to the reflection of waves traveling down the length of the cylinder are observed. There is also evidence of a face-traversing longitudinal wave for slightly tilted cylinders.