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31.
Motivated by the central limit problem for convex bodies, we study normal approximation of linear functionals of high-dimensional
random vectors with various types of symmetries. In particular, we obtain results for distributions which are coordinatewise
symmetric, uniform in a regular simplex, or spherically symmetric. Our proofs are based on Stein’s method of exchangeable
pairs; as far as we know, this approach has not previously been used in convex geometry. The spherically symmetric case is
treated by a variation of Stein’s method which is adapted for continuous symmetries.
This work was done while at Stanford University. 相似文献
32.
Mark Jerrum 《Random Structures and Algorithms》1995,7(2):157-165
A fully polynomial randomized approximation scheme is presented for estimating the number of (vertex) k-colorings of a graph of maximum degree Δ, when k ≥ 2Δ + 1. © 1995 John Wiley & Sons, Inc. 相似文献
33.
Eric Gifford Mark Johnson Chun-che Tsai 《Journal of computer-aided molecular design》1991,5(4):303-322
Summary The metabolic pathways of medazepam, oxazepam, and diazepam were modeled using graph-theoretic transforms which are incorporable into computer-assisted metabolic analysis programs. The information, represented in the form of a graph-theoretic transform kit, which was obtained from these pathways was then used to predict the metabolites of other benzodiazepine compounds. The transform kits gave statistically significant predictions with respect to a statistical method for evaluating the performance of the transform kits. 相似文献
34.
Christopher A. Luckhurst Ian Millichip Beth Parker James Reuberson Mark Furber 《Tetrahedron letters》2007,48(50):8878-8882
A one-pot reaction of carboxylic acids with sulfonamides to afford sulfonylureas is described. 相似文献
35.
Mark Pollicott 《Topology and its Applications》2007,154(12):2365-2375
We study lifts of the stable foliation of a pseudo-Anosov diffeomorphism to abelian covers. Under certain conditions, we show that it is ergodic but not uniquely ergodic and describe the ergodic measures. 相似文献
36.
Mark A. S. Aarons 《Calculus of Variations and Partial Differential Equations》2006,25(2):205-246
We study the forced mean curvature flow of graphs in Minkowski space and prove longtime existence of solutions. When the forcing
term is a constant, we prove convergence to either a constant mean curvature hypersurface or a translating soliton – depending
on the boundary conditions at infinity.
It is a pleasure to thank my PhD advisors Klaus Ecker and Gerhard Huisken for their assistance and encouragement. I also thank
Maria Athanassenas, Oliver Schnürrer and Marty Ross for their interest and useful comments, and the Max Planck Gesellschaft
for financial support. 相似文献
37.
3,4-Dihydro-2H-pyrrole derivatives were synthesized by the 1,3-dipolar cycloaddition reaction of nitrile ylides with acrylamides. Acrylamide substitution patterns and benzimidoyl chloride equilibration were investigated. 相似文献
38.
In this paper the effects of surface roughness and annealing temperature (T) of latex coating films on adhesion are discussed for the different stages of the film formation process. The surface free energy of latex films was assessed in terms of practical work of adhesion (W) (or adherence) using a custom-built adhesion-testing device (ATD), atomic force microscopy (AFM), and contact angle measurements. For preannealed latex films surface roughness averages (Ra) were determined from AFM height images and were related to the values of W obtained from ATD measurements at room temperature. The results obtained using these tests exhibiting surface behavior on different length scales indicate a dependence of the measured adhesion on surface roughness and temperature, as well as on the length scale of the measurements.First preannealed samples were studied, which were obtained by heat treatment above the respective glass transition temperatures (Tg). Increasing the temperature of preannealing resulted in a decrease of the adherence observed in ATD experiments at room temperature. However, on the nanoscale, using AFM, no significant variation of the adherence was observed. This observation can be explained by roughness arguments. Preannealing decreases roughness which results in lower adherence values measured by ATD while for essentially single asperity AFM experiments roughness has an insignificant effect. Specimens were also annealed over a constant period of time (90 min) at different temperatures. At the end of the heat treatment, adhesion was measured at the treatment temperature by ATD. The amplified effect of temperature observed in this case on adherence is attributed to the combination of roughness decrease and increasing test temperature. In a third set of experiments completely annealed samples were studied by ATD as well as by AFM as a function of temperature. With increasing T values ATD showed a decrease in adherence, which is attributed to a decreasing surface free energy of the annealed films at elevated T values. AFM, on the other hand, showed an opposite trend which is assigned to increasing penetration of the tip into the tip/wetting polymer samples versus increasing temperature. Finally, annealing isotherms as a function of time were investigated by ATD in situ at different temperatures. This last set of experiments allowed us to optimize annealing time and temperature to achieve complete curing. 相似文献
39.
A current interpretation of XPS spectra of Ni metal assumes that the main 6 eV satellite is due to a two hole c3d94s2 (c is a core hole) final state effect. We report REELS observation in AES at low voltages of losses (plasmons and inter-band transitions) corresponding to the satellite structures in Ni metal 2p spectra. The satellite near 6 eV is attributed to a predominant surface plasmon loss. A current interpretation of Ni 2p spectra of oxides and other compounds is based on charge transfer assignments of the main peak at 854.6 eV and the broad satellite centred at around 861 eV to the cd9L and the unscreened cd8 final-state configurations, respectively (L is a ligand hole). Multiplet splittings have been shown to be necessary for assignment of Fe 2p and Cr 2p spectral profiles and chemical states. The assignments of Ni 2p states are re-examined with intra-atomic multiplet envelopes applied to Ni(OH)2, NiOOH and NiO spectra. It is shown that the free ion multiplet envelopes for Ni2+ and Ni3+ simulate the main line and satellite structures for Ni(OH)2 and NiOOH. Fitting the NiO Ni 2p spectral profile is not as straightforward as the hydroxide and oxyhydroxide. It may involve contributions from inter-atomic, non-local electronic coupling and screening effects with multiplet structures significantly different from the free ions as found for MnO. A scheme for fitting these spectra using multiplet envelopes is proposed. 相似文献
40.