A 1H NMR Study of the Kinetics of the Reaction of Diisocyanates with Ethlene Oxide-Dimethylsiloxane-Ethylene Oxide Block Copolymer

The reaction of pure 2–4 and 2–6 tolylene diisocyanate with an OH terminated ethylene oxide-dimethylsiloxane-ethylene oxide ABA block copolymer was carried out directly in a n.m.r. tube. The kinetic of the reaction was studied by ¹H nmr spectroscopy.     

Investigation of the guided modes in anisotropic diffused slab waveguide with embedded metal layer

Abstract

The optical characteristics of the TE and TM guided modes of a multilayer anisotropic two-dimensional waveguide are investigated by using the field component transformation matrix, and also taking into account the substrate intrinsic dispersion. The embedded thin metal layer effects on the propagation constant for both lossless approximated and exact solutions are presented. The lossless approach is accurate enough for the TE waves, but it is not for the TM ones, which exhibit changes of about 10^?6 for the equivalent index. The TM modes also present attenuation constant changes between the lossy and weakly-lossy solutions of the order of 9 dB/cm. Several complex field component mappings are drawn, and the surface plasma waves are also examined.     

The Green relations approach to congruences on completely regular semigroups

On the congruence lattice (2(5) of a completely regular semigroup S the following mappings are considered _p: P and _p: VP, whereP is any of the Green relationsH, L, R orD. The equivalence relationsP andP ^V induced by these maps represent the main object of study in the paper. The former is a complete -congruence whereas the latter is a complete congruence onC(S). In particularH ,H ^V,L ^V,R ^V coincide with the kernel, trace, left trace and right trace relations onC(S), respectively. All essential properties known for the latter relations carry over to the new relationsP andP ^V. In addition, some interesting interplays of these provide for more richness in the theory of congruences on completely regular than is the case for the kernel-trace approach to congruences on regular semigroups.     

Homogenization of the heat equation for a domain with a network of pipes with a well-mixed fluid

We consider the linear heat equation in a domain occupied by a solid material with a network of pipes in which a well-mixed fluid is circulating. The temperature of the fluid in the pipe is uniform and its time variation is determined by the thermal flux on the wall of the pipe, plus a given internal source; continuity of the temperature across the pipe is also assumed. We suppose that we deal with a periodic geometry, with cells of size with inclusions of size r_g; we study in detail in the case r, referring to a previous paper for the case r In the limit »0 we get a homogenized equation. The limit depends strongly on the ratio between the time variation of the temperature in the inclusions and the thermal flux through the interface. The homogenized equation has a new specific heat, which depends on the porosity and the constant of proportionality between the time variation of temperature and the flux on the boundary of the pipe. We also have a new thermal conductivity depending on the microstructure, and volume sources appear. The main tool is the energy method and we generalize the classical results for the more standard boundary conditions for parabolic equations. Finally, we consider the network of pipes forming a random ball structure. We prove convergence for this case. The homogenized equation is of the same form as in the periodic case but auxiliary problems are stochastic.     

Time behavior of stressed nonhierarchical networks

In this paper it is shown, by means of simulation, that interesting time behavior is observed for damaged and overloaded networks, and that adaptive, decentralized intelligence can have a dramatic influence on the overall network performance. The time behavior of nonhierarchical networks is modeled by a system of nonlinear difference equations among global variables, and bistability is shown to exist. Using a simple adaptive control mechanism, it is shown that, depending upon the value of a certain network variable, either limit cycle or steady state behavior results. A few ideas are discussed for applications of nonhierarchical communications to cellular automata and to decision-making systems.     

Time evolution of infinite classical systems with singular,long range,two body interactions

Existence of dynamics for infinitely many hard-spheres inv dimensions is proven in a set of full equilibrium measure.Singular unbounded perturbations are considered with pair potentials diverging as (x – a)^–, >2 anda is the hard-core diameter. Long range forces are allowed with potentials decreasing at infinity asx , <v. The result corrects and generalizes a proof given in a previous paper by the same authors.Research partially supported by a CNR fellowship Posit. 204530.Research partially supported by a CNR fellowship.     

13C direct detected COCO-TOCSY: a tool for sequence specific assignment and structure determination in protonless NMR experiments

A novel experiment is proposed to provide inter-residue sequential correlations among carbonyl spins in (13)C detected, protonless NMR experiments. The COCO-TOCSY experiment connects, in proteins, two carbonyls separated from each other by three, four or even five bonds. The quantitative analysis provides structural information on backbone dihedral angles phi as well as on the side chain dihedral angles of Asx and Glx residues. This is the first dihedral angle constraint that can be obtained via a protonless approach. About 75% of backbone carbonyls in Calbindin D(9K), a 75 amino acid dicalcium protein, could be sequentially connected via a COCO-TOCSY spectrum. 49 [Formula: see text] values were measured and related to backbone phi angles. Structural information can be extended to the side chain orientation of aminoacids containing carbonyl groups. Additionally, long range homonuclear coupling constants, (4)J(CC) and (5)J(CC), could be measured. This constitutes an unprecedented case for proteins of medium and small size.     

Thermal diffusivity and nuclear spin relaxation: a continuous wave free precession NMR study

Continuous wave free precession (CWFP) nuclear magnetic resonance is capable of yielding quantitative and easily obtainable information concerning the kinetics of processes that change the relaxation rates of the nuclear spins through the action of some external agent. In the present application, heat flow from a natural rubber sample to a liquid nitrogen thermal bath caused a large temperature gradient leading to a non-equilibrium temperature distribution. The ensuing local changes in the relaxation rates could be monitored by the decay of the CWFP signals and, from the decays, it was possible to ascertain the prevalence of a diffusive process and to obtain an average value for the thermal diffusivity.