颗粒增强复合材料热应力分析的双层嵌套模型

建立了一个把增强颗粒球和基体空心球嵌入等效复合介质空腔中的“双层嵌套模型”,研究了颗粒增强材料自高温冷却下来时,不同相中热应力的分布特点。推出了热应力在弹性和弹塑性状态的各种表达式。研究表明,随着温度降低,增强体受到压应力,基体材料中存在的静水应力为拉应力。温度继续下降,将出现自增强颗粒与基体界面向外扩展的屈服区。随增强相体积分数增大,增强颗粒受到的压应力和基体中的静水拉应力减小,增强颗粒与基体界面屈服的起始温差增大,而基体材料全面屈服的温差却减小。     

Synthesis and mechanism research of an ethylene glycol-based sol-gel method for preparing PZT nanopowders

Lead zirconate titanate nanopowders Pb(Zr_0.52Ti_0.48)O₃ (PZT) were prepared by modified sol-gel process in ethylene glycol system with zirconium nitrate as the zirconium source. The research showed that it was critical to add lead acetate after the reaction of zirconium nitrate and tetrabutyl titanate in ethylene glycol system for preparing PZT of exact titanium content. The reaction mechanisms of the sol synthesis, preparation of xerogel and agglutinating process were characterized through using FT-IR, NMR, TG-FTIR, and GC-MS. The experiment proved that ethylene glycol system did not rely on hydrolysis and condensation reactions in the process of the sol formation, but on the formation of chain or network large molecules from complexation of ethylene glycol and all Ti and minor Pd, Zr. In the preparation of xerogel, the complexation reaction was so completed that it formed large molecules network composed of metal and dioxyethyl. Bulk weight loss happened before 350°C in the process of sintering xerogel to prepare PZT nanopowders. Volatile matters and vapor phase decomposition resultants were primarily oxy-compounds including ethylene glycol, aldehyde-ketone compounds, carbon dioxide and nitrate radical conversion matters. After 350°C, primary vapor phase decomposition resultants were carbon dioxide and minor carbonyl compound.     

I2-mediated α-selective Ferrier glycosylation approach to synthesis of O-glycosyl amino acids

I₂ is an effective promoter for the synthesis of 2,3-unsaturated glycosides via Ferrier glycosylation. This reaction was used in the present work for the synthesis of O-glycosylated Fmoc amino acid building blocks. This metal-free reaction afforded the desired products with good to excellent yields with good α-selectivity.     

二维映射神经元模型中频率依赖的随机共振

通过数值模拟方法, 研究了在具有稳定次阈值振荡特性的二维映射神经元体系中, 噪声对体系非线性动力学的调控作用. 通过计算发现了噪声诱导的动作电位和随机共振现象. 另外,还研究了体系的控制参数及输入信号的频率对体系动力学的影响, 发现了该体系中频率依赖的随机共振现象. 关键词： 二维映射神经元模型 次阈值振荡 高斯白噪声 随机共振     

Mechanical Reinforcement and Piezoelectric Properties of PZT Ceramics Embedded with Nano-Crystalline

The double-scale lead zirconate titanate （PZT） piezoelectric ceramics were prepared by the solid state processing with PZT nano-crystalline and micro-powder. The microstructures, electrical and mechanical properties of the double-scale PZT are investigated. All the sintered ceramics exhibit a single perovskite structure and the grain size of the dou ble-scale PZT reduces due to the incorporation of PZT nano-crystalline. Compared to normal PZT, the mechanical properties increase significantly and the piezoelectric properties decrease slightly. Mechanisms responsible for the reinforcement of the double-scale PZT are discussed.     

Dynamic Fracture Toughness and Failure Mechanisms of ZnO Whiskers Secondary Reinforced Composites

Quasi-static and dynamic fracture properties and damage mechanism of glass fiber polymer composites embeaaea with different mass percentages of ZnO whiskers are investigated by using an Instron Testing machine and a Split- Hopkinson pressure bar. According to the experimental results and linear fracture mechanics, the quasi-static fracture toughness Kic and the dynamic fracture toughness Kid under various impact velocities of specimens are obtained. Fracture mechanism is investigated by fractography analysis with a scanning electron microscope. The experimental results show that the mass percentage of ZnOw has little influence on the quasi-static fracture toughness, but a little influence on the dynamic fracture toughness and time of initial fracture point of specimens by the reason of various fracture mechanisms.