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排序方式: 共有5078条查询结果,搜索用时 15 毫秒
991.
2,7‐Diazapyrene is synthesized in three high‐yield steps from commercially available 1,4,5,8‐naphthalene tetracarboxylic dianhydride, which first reacts with concentrated ammonium hydroxide solution at room temperature to give 1,4,5,8‐naphthalenetetracarboxylic diimide (96%). The latter compound is subsequently reduced with borane in refluxing tetrahydrofuran to give 1,2,3,6,7,8‐hexahydro‐2,7‐diazapyrene (77%), which in turn is oxidized with manganese dioxide in refluxing benzene giving 2,7‐diazapyrene (71%). 相似文献
992.
This paper investigates the intensity tuning characteristics of a double
longitudinal modes He--Ne laser subjected to optical feedback. The intensity
undulations of the total light and the two modes are observed for different external
cavity length. Two modulations of the internal cavity length are performed. One is
only for the internal cavity length being modulated and the other is for both the
internal and the external cavity length being modulated. The undulation frequency of
the total light is found to be determined by the ratio of external cavity length to
internal cavity length in both modulations. When the external cavity length is
integral times of the internal cavity length, the fringe frequency of the total
light could be seven or even more times of that in conventional optical feedback. A
simple theoretical analysis is presented, which is in good agreement with the
experimental results. The potential use of the experimental results is also
discussed. 相似文献
993.
Based on the state equation of an ideal quantum gas, the regenerative loss of a
Stirling engine cycle working with an ideal quantum gas is calculated. Thermal
efficiency of the cycle is derived. Furthermore, under the condition of quantum
degeneracy, several special thermal efficiencies are discussed. Ratios of thermal
efficiencies versus the temperature ratio and volume ratio of the cycle are made. It
is found that the thermal efficiency of the cycle not only depends on high and low
temperatures but also on maximum and minimum volumes. In a classical gas state
the thermal efficiency of the cycle is equal to that of the Carnot cycle. In an ideal
quantum gas state the thermal efficiency of the cycle is smaller than that of the
Carnot cycle. This will be significant for deeper understanding of the gas Stirling
engine cycle. 相似文献
994.
Summary: A facile and organic‐solvent‐free method for preparing thermoprocessable multiwalled carbon nanotube (MWCNT)‐filled thermoplastics is presented. MWCNTs are oxidized, neutralized, and then assembled with cationic soap‐free poly(methyl methacrylate) (PMMA) particles directly in water. The spontaneous electrostatic coupling between the negatively charged MWCNTs and positively charged PMMA particles, and the viscoelastic and thermomechanical behavior of the nanocomposites, are investigated. The electrostatic coupling interactions improve the dispersion of nanotubes and facilitate the formation of filler networks in the polymer matrix.
995.
996.
Xin Huang Zeyuan Dong Junqiu Liu Shizhong Mao Guimin Luo Jiacong Shen 《Macromolecular rapid communications》2006,27(24):2101-2106
Summary: A tellurium‐based polymeric sufactant as a seleno‐enzyme model has been constructed by employing 11‐acryloyloxyundecyltriethylammonium bromide (AUTEAB, 4 ) and a tellurium‐containing compound ( 1 ). It demonstrates strong substrate binding ability for thiols and high glutathione peroxidase (GPx) activity about 6 orders of magnitude more efficient than the well‐known GPx mimic PhSeSePh in an ArSH assay system. More importantly, a series of tellurium‐based polymeric micelle catalysts with the catalytic tellurium center located at various positions in the micelle have been constructed, and the dramatic difference in activity indicates that the exact match of the catalytic center and binding site plays a key role in enzyme catalytic efficiency.
997.
998.
A novel micro accelerometer with adjustable sensitivity based on resonant tunneling diodes 下载免费PDF全文
Resonant tunnelling diodes (RTDs) have negative differential
resistance effect, and the current--voltage characteristics change
as a function of external stress, which is regarded as
meso-piezoresistance effect of RTDs. In this paper, a novel micro-accelerometer based on AlAs/GaAs/In0.1Ga0.9As/GaAs/AlAs
RTDs is designed and fabricated to be a four-beam-mass structure,
and an RTD-Wheatstone bridge measurement system is established to
test the basic properties of this novel accelerometer. According to
the experimental results, the sensitivity of the RTD based micro-accelerometer is adjustable within a range of 3 orders when the bias
voltage of the sensor changes. The largest sensitivity of this RTD
based micro-accelerometer is 560.2025 mV/g which is about 10 times
larger than that of silicon based micro piezoresistive
accelerometer, while the smallest one is 1.49135 mV/g. 相似文献
999.
The Galerkin-Petrov least squares method is combined with the mixed finite element method to deal with the stationary, incompressible magnetohydrodynamics system of equations with viscosity. A Galerkin-Petrov least squares mixed finite element format for the stationary incompressible magnetohydrodynamics equations is presented. And the existence and error estimates of its solution are derived. Through this method, the combination among the mixed finite element spaces does not demand the discrete Babuska-Brezzi stability conditions so that the mixed finite element spaces could be chosen arbitrartily and the error estimates with optimal order could be obtained. 相似文献
1000.
A series of Cr doped TiO2 films were prepared by micro arc oxidation (MAO) using an electrolyte of Na3PO4+K2Cr2O7. X-ray diffraction and scanning electron microscopy revealed that the films mainly consisted of anatase phase with a porous surface morphology. The films have an excellent photocatalytic effect for degradation of methylene blue and decomposition of water under visible light illumination. This arises from the formation of Cr3+/Cr4+ and oxygen vacancy energy levels owing to Cr doping. The former reduces the electron-hole recombination chance, while the latter generates a new gap between the conduction band (CB) and valence band (VB) of TiO2, which lowers the photo energy of the excited electron in the VB to the oxygen vacancy states. The mechanisms for film synthesis during the MAO process are also presented. 相似文献