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951.
Del Canto E Natali M Movia D Giordani S 《Physical chemistry chemical physics : PCCP》2012,14(17):6034-6043
Light controllable release of antinflammatory zinc ions by a smart multifunctional material composed of spiropyrans and single walled carbon nanotubes (SWNTs) is demonstrated. The exploitation of a number of complementary characterization techniques allows the investigation of both composition and performance of the multifunctional SP/SWNT nanomaterial developed. Moreover, its suitability for potential applications in bio-systems is suggested by the effective removal of the metal catalyst and the introduction of biocompatible linkers into the SP/SWNT material. The realization of potential photo controllable SP/SWNTs based drug delivery systems (DDSs) is envisaged, where nanotubes act as intracellular carriers of light modulated receptors for bioactive agents. 相似文献
952.
953.
The histone code refers to the complex network of histone post-translational modifications that control gene expression and are of high interest as drivers of a large number of human diseases. We report here on a mix-and-match toolkit of readily available dyes and calixarene host molecules that can be combined to form dye-displacement sensors that respond to a wide variety of cationic peptides. Using the data from only two or three such simple supramolecular sensors as a chemical sensor array produces fingerprints of data that discriminate robustly among many kinds of histone code elements. "Reads" that are accomplished include the discrimination of unmethylated, mono-, di-, and trimethylated lysines on a single histone tail sequence, identification of different modifications and combinations of modifications on a single histone tail sequence, identification of a single modification type in several different sequence contexts, and identification of isomeric dimethylarginine modifications. Reads that are sometimes troublesome for antibodies are achieved. We also report on the ability of the sensor array to report simultaneously on the concentrations and identities of histone modifications. This sensor array discriminates between post-translationally modified analytes without being limited to partners that contain a single, programmed binding interaction. 相似文献
954.
Moliner M Willhammar T Wan W González J Rey F Jorda JL Zou X Corma A 《Journal of the American Chemical Society》2012,134(14):6473-6478
A new molecular sieve, ITQ-38, containing interconnected large and medium pores in its structure has been synthesized. The rational combination of dicationic piperidine-derivative molecules as organic structure directing agents (OSDAs) with germanium and boron atoms in alkaline media has allowed the synthesis of ITQ-38 zeolite. High-resolution transmission electron microscopy (HRTEM) has been used to elucidate the framework topology of ITQ-38, revealing the presence of domains of perfect ITQ-38 crystals as well as very small areas containing nanosized ITQ-38/ITQ-22 intergrowths. The structure of ITQ-38 is highly related to ITQ-22 and the recently described polymorph C of ITQ-39 zeolite. It shares a common building layer with ITQ-22 and contains the same building unit as the polymorph C of ITQ-39. All three structures present similar framework density, 16.1 T atoms/1000 ?(3). 相似文献
955.
Manuel A. Leiva G. Ma. Consuelo Araya Ana Maria Alvarado Rodrigo J. Seguel 《Accreditation and quality assurance》2012,17(1):53-63
The present work presents a measurement uncertainty evaluation according to Guide to the Expression of Uncertainty in Measurement
(GUM) of the concentration of the cations K+ and Li+ and anions NO3−2 and SO4−2 in fine airborne particulate matter, refers to particles less than 2.5 μm in diameter (PM2.5), as measured by ion chromatography (US-EPA 300 method). The GUM method is not typically used to report uncertainty. In general,
the analytical results only report the measurement’s standard deviation under repetition as an uncertainty; thus, not all
sources of uncertainty are considered. In this work, the major sources of uncertainty regarding the measurements were identified
as contributions to linear least square regression lines, repeatability, precision, and trueness. The expanded uncertainty
was approximately 20% for anions and cations. The largest contribution to uncertainty was found to be repeatability. 相似文献
956.
957.
We study the classical dynamics of the RbCs molecule in the presence of a static electric field. Under the Born–Oppenheimer approximation, we perform a rovibrational investigation which includes the interaction of the field with the molecular polarizability. The stability of the equilibrium points and the phase space structure of the system are explored in detail. We find that, for strong electric fields or for energies close to the dissociation threshold, the molecular polarizability causes relevant effects on the system dynamics. 相似文献
958.
Jesús M.F. Castillo Manuel González Pier Luigi Papini 《Nonlinear Analysis: Theory, Methods & Applications》2012
We study the stability properties of the class of weak*-extensible spaces introduced by Wang, Zhao, and Qiang showing, among other things, that weak*-extensibility is equivalent to having a weak*-sequentially continuous dual ball (in short, w*SC) for duals of separable spaces or twisted sums of w*SC spaces. This shows that weak*-extensibility is not a 3-space property, solving a question posed by Wang, Zhao, and Qiang. We also introduce a restricted form of weak*-extensibility, called separable weak*-extensibility, and show that separably weak*-extensible Banach spaces have the Gelfand–Phillips property, although they are not necessarily w*SC spaces. 相似文献
959.
Manuel Ritoré 《Calculus of Variations and Partial Differential Equations》2012,44(1-2):47-60
Let D be a closed disk centered at the origin in the horizontal hyperplane {t?=?0} of the sub-Riemannian Heisenberg group ${\mathbb{H}^n}$ , and C the vertical cylinder over D. We prove that the perimeter of any set E such that ${D\subset E\subset C}$ is larger than or equal to the one of the rotationally symmetric sphere with constant mean curvature of the same volume, and that equality holds only for these spheres using a recent result by Monti and Vittone (Math Z 1–17, 2010). 相似文献
960.
Jaciel Robles-Nu?ez Fernando Chi?as-Castillo Manuel Sanchez-Rubio Javier Lara-Romero Rafael Huirache-Acu?a Sergio Jimenez-Sandoval Gabriel Alonso-Nu?ez 《Chemical Papers》2012,66(12):1130-1136
MoS2 sheathed carbon nanotubes have been successfully synthesized using a hydrothermal route under controlled conditions. The resultant material was studied by XRD, EDS, HRTEM, and Raman spectroscopy. Advantages of the preparation presented here compared to other methods are: a) lower reaction temperature, b) high yield of sheathed nanotubes including ends and full body, c) simple process with non-toxic materials, and d) no damage inflicted to nanotubes. 相似文献