Laplacian Operators and Radon Transforms on Grassmann Graphs

Let Ω be a vector space over a finite field with q elements. Let G denote the general linear group of automorphisms of Ω and let us consider the left regular representation associated with the natural action of G on the set X of linear subspaces of Ω. In this paper we study a natural basis B of the algebra End_G(L ₂(X)) of intertwining maps on L ₂(X). By using a Laplacian operator on Grassmann graphs, we identify the kernels in B as solutions of a basic hypergeometric difference equation. This provides two expressions for these kernels. One in terms of the q-Hahn polynomials and the other by means of a Rodrigues type formula. Finally, we obtain a useful product formula for the mappings in B. We give two different proofs. One uses the theory of classical hypergeometric polynomials and the other is supported by a characterization of spherical functions in finite symmetric spaces. Both proofs require the use of certain associated Radon transforms.     

Quasi-Hamiltonian structure and Hojman construction

Given a smooth vector field Γ and assuming the knowledge of an infinitesimal symmetry X, Hojman [S. Hojman, The construction of a Poisson structure out of a symmetry and a conservation law of a dynamical system, J. Phys. A Math. Gen. 29 (1996) 667-674] proposed a method for finding both a Poisson tensor and a function H such that Γ is the corresponding Hamiltonian system. In this paper, we approach the problem from geometrical point of view. The geometrization leads to the clarification of several concepts and methods used in Hojman's paper. In particular, the relationship between the nonstandard Hamiltonian structure proposed by Hojman and the degenerate quasi-Hamiltonian structures introduced by Crampin and Sarlet [M. Crampin, W. Sarlet, Bi-quasi-Hamiltonian systems, J. Math. Phys. 43 (2002) 2505-2517] is unveiled in this paper. We also provide some applications of our construction.     

Self-inverse Sheffer sequences and Riordan involutions

In this short note, we focus on self-inverse Sheffer sequences and involutions in the Riordan group. We translate the results of Brown and Kuczma on self-inverse sequences of Sheffer polynomials to describe all involutions in the Riordan group.     

Auger electron emission in proton-induced interactions in living matter: A TILDA-V Monte Carlo tracking

The present work focuses on studying the contribution of the Auger electron emission in proton-induced interactions in biological matter. The Monte Carlo track-structure code, TILDA-V, was then used for modeling the protons beams of 10 keV to 100 MeV in biological matter, namely, water vapor and hydrated DNA. The main ionizing processes are described by means of an extensive set of ab initio differential and total cross sections computed within a quantum-mechanical CDW-EIS approximation.     

Network Dynamics in Elemental Assimilation and Metabolism

Metabolism and physiology frequently follow non-linear rhythmic patterns which are reflected in concepts of homeostasis and circadian rhythms, yet few biomarkers are studied as dynamical systems. For instance, healthy human development depends on the assimilation and metabolism of essential elements, often accompanied by exposures to non-essential elements which may be toxic. In this study, we applied laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) to reconstruct longitudinal exposure profiles of essential and non-essential elements throughout prenatal and early post-natal development. We applied cross-recurrence quantification analysis (CRQA) to characterize dynamics involved in elemental integration, and to construct a graph-theory based analysis of elemental metabolism. Our findings show how exposure to lead, a well-characterized toxicant, perturbs the metabolism of essential elements. In particular, our findings indicate that high levels of lead exposure dysregulate global aspects of metabolic network connectivity. For example, the magnitude of each element’s degree was increased in children exposed to high lead levels. Similarly, high lead exposure yielded discrete effects on specific essential elements, particularly zinc and magnesium, which showed reduced network metrics compared to other elements. In sum, this approach presents a new, systems-based perspective on the dynamics involved in elemental metabolism during critical periods of human development.     

Spectrum of γ-Fluids: A statistical derivation

The spectrum of massless bosonic and fermionic fluids satisfying the equation of statep=(–1) is derived using elementary statistical methods. As a limiting case, the Lorentz-invariant spectrum of the vacuum (=0,p=–) is deduced. These results are in agreement with our earlier derivation for bosons using thermodynamics and semiclassical considerations.     

Long Distance Electronic Effects on the Rotational Potential Barriers Around the Caromatic-Cethylenic Bond

A systematic study of the rotational activation free energy around the C_aromatic-C_ethylenic bond of para-substituted styrene systems is carried out in the present work from a quantum chemistry point of view.

Calculations of the rotational potential barriers in the AM1 approach are developed as function of the electron-donor groups localized on the aromatic ring. Based on these calculations and thermodynamical data, we predict changes in the activation free energy barriers due to the long distance electronic effects of the substituents in acetophenones, cinnamaldehydes and benzalketones according to the following equation:

Our results agree the experimental measurements registered up to date and the standard deviations are similar to experimental determinations.