Restoration of universality for the rod-to-coil transition scaling in the infinite-dimensionality limit: Exact results for directed walks

We derive scaling forms for the thermodynamic and correlation quantities for the turn-weighted fully and partially directed self-avoiding walks on the hypercubic lattices ind2. In the grand canonical (fixed fugacity per step) ensemble, the conformational rod-to-coil transition sets up in the regimew¯N=O(1), wherew is the weight of each 90° turn and¯N is the (fugacity-dependent) average number of steps. Contrary to the conventional critical phenomena wisdom, the scaling functions for the two different walk models, directed and partially directed, become universal only in the limitd.     

Stability and distribution constants of thallium(I) dithiocarbamates

Stability and distribution constants of thallium(I) chelates with diethyl-(I), pyrrolidine- (II), piperidine- (III), phenylethyl- (IV) and methylphenylethyldithiocarbamate (V) have been radiometrically determined using ion-exchange and solvent extraction methods. Stability constants of individual chelates do not change considerably, however, the distribution constants of neutral chelates increase in the order II<IV<IIII<V.     

Conditioning of industrial waste in cement matrix

Results are presented of a series of experimental tests performed to determine the influence of matrix characteristics on the leaching mechanism of copper aluminium oxychloride immobilized into cement matrices. The objective of this research was to investigate the leaching mechanism of copper as a constituent of copper aluminium oxychloride (CAOX).     

Unified quantum logic

Unified quantum logic based on unified operations of implication is formulated as an axiomatic calculus. Soundness and completeness are demonstrated using standard algebraic techniques. An embedding of quantum logic into a new modal system is carried out and discussed.On leave of absence from Department of Mathematics, University of Zagreb, Pot. Pret. 165, YU-41001 Zagreb, Yugoslavia.     

On the tensor product of supersingleton representations ofosp(1, 2n)

The tensor product of two supersingleton representations _n of the Lie superalgebraosp (1, 2n) is studied forn2. The main results are as follows: (a) anticommutators and commutators of the odd generators in _{n n} form a skew-symmetric representation of the Lie algebrau(n, n); (b) simple explicit form of all irreducible components of _{n n}, which are labelled by a single parameterJ=0, 1, ..., has been found. Each of them is a^*-representation ofosp (1, 2n) for which assertion (a) is valid. The dimension of its vacuum subspace equals , i.e., the nondegenerate vacuum occurs for J=0 only. Basic property of this family of irreducible^*-representations of osp(1, 2n) are analogous to those of massless representations of osp(1, 4).Dedicated to Academician Václav Votruba on the occasion of his eightieth birthday.     

Quantitative characterization of chaotic instabilities in semiconductors

A method for quantitative characterization of chaotic dynamical systems is discussed. An electronic instrument for determining the number of independent variablesk ^*, involved in the motion, is described. It allows one to obtain these in real time from a single observable. The suggested technique has been applied to quantification of strange attractors underlying chaotic instabilities in semi-insulating GaAsCr, and n-Ge, irradiated with high energy electrons. In n-Ge, for instance, the measured numbersk ^* range from 2 to 4 depending on control parameters. These measurements reveal the highly deterministic nature of the observed chaotic oscillations. The physical mechanisms responsible for the current instabilities and chaotic behaviour are discussed.     

1,3,6,9,12,14,17,20-octaethynyltetrabenz[a,b,f,j,k,o]-4,5,10,11,15,16,21,22- octadehydro[18]annulene: a carbon-rich hydrocarbon

Dodecaynes 1a-d have been prepared via a convergent strategy that employs Sonogashira couplings as the carbon-carbon bond-forming tool. Due to the steric bulk of the DMTS groups, 1c adopts a nonplanar conformation, the dynamics of which have been probed by VT-NMR. The cobalt-catalyzed isomerization of 1a,b produced the new conjugated phenylenes 2a,b and 3a,b, respectively. [structure: see text]     

Reliable evaluation of temperature-independent parameters in correlation of vapour–liquid equilibrium data

A new algorithm/program has been elaborated for simultaneous processing of different sets of vapour–liquid equilibrium data. The program was tested with six binary hexane + isomeric pentanol systems, each of them measured at three different isobaric conditions and one isothermal system of tert-butyl-methyl-ether + 2-methyl-2-propanol measured at three different temperatures. The correlation uses the maximum likelihood method, taking into account real behaviour of vapour phase. The parameters obtained are valid within the whole temperature range of the data, and are consistent in comparison with those obtained from individual correlations of isobars or isotherms. Results are presented for the Wilson and NRTL equations.     

Transition metal complexes with Girard reagent-based ligands

The ligand, salicylaldehyde Girard-T hydrazonium chloride, [H₂SalGT]Cl (1), and two complexes [Cu(HSalGT)X₂]·H₂O (X = Br(2); Cl(3)) were synthesized and their crystal structures were determined by single-crystal X-ray analysis. In the two isostructural complexes, the Cu(II) is located in a square-pyramidal environment, with the chelating ligand and one halogen atom in the basal plane and the second halogen in the apical position. The most apparent structural difference between the 1 and its complexes 2 and 3 is the orientation of the N(CH₃)₃ group: in 1, it is practically coplanar to the rest of the molecule, while in 2 and 3 it is oriented to the side of the axially bonded halogen, which can be explained by the C–H…X intramolecular interactions. The compounds were characterized by elemental analysis, molar conductivity, magnetic susceptibility and electronic absorption spectra.