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51.
Binary mixtures formed from components of the five homologous series of the 4-(4-substituted phenylazo)phenyl-4-alkoxybenzoates Ia-e were prepared and their mesophase behaviour characterized. Transition temperatures of the mixtures prepared were measured by differential scanning calorimetry and identified by polarizing optical microscopy. Each binary combination was made from components bearing a terminal alkoxy group with the same number of carbon atoms (kept constant at n = 6, 8, 10, 12, 14 or 16), while the other substituent (X) was different—CH3O, CH3, Cl, NO2, or CN. Phase diagrams were constructed for the various systems in order to investigate the effect of the terminal substituent X, as well as of the alkoxy chain length, on the phase behaviour of mixed systems. 相似文献
52.
Nouria A. Al-Awadi Bobby J. George Hicham H. Dib Maher R. Ibrahim Yehia A. Ibrahim Osman M.E. El-Dusouqui 《Tetrahedron》2005,61(34):8257-8263
Gas-phase pyrolysis (static and FVP) of 1-aroylbenzotriazoles gave the corresponding substituted benzoxazole, benzimidazole, benzamide, N-phenylbenzamide, phenanthridin-6(5H)-one derivatives and 1-cyanocyclopentadiene. The present kinetic and mechanistic findings also provide further evidence of the involvement of biradical or carbene reactive intermediates in the reaction pathway of gas-phase pyrolysis of benzotriazoles. 相似文献
53.
54.
The rates of thermal decomposition of 1-methacryloyl-3-phenylthiourea (1a), 1-methacryloyl-3-(4-nitrophenyl)thiourea (1b), 1-methacryloyl-3-(4-chloro phenyl)thiourea (1c), 1-methacryloyl-3-(4-methylphenyl)thiourea (1d), 1-methacryloyl-3-(4-methoxyphenyl)thiourea (1e), poly-1-methacryloyl-3-phenylthiourea (2) and 1-acryloyl-3-phenylthiourea (3) have been measured between 390 and 465 K. The reactions were homogeneous and unimolecular with log A = 11.48, 11.48, 11.81, 11.43, 11.11, 11.21 and 11.87s−1 and Ea = 119.7, 111.93, 120.07, 121.94, 120.84, 124.64 and 122.68 kJ mol−1, respectively. Product analysis was used to outline feasible pathways for the elimination reaction of the compounds under study. 相似文献
55.
56.
A. Maher 《Journal of sound and vibration》1980,70(2):213-220
A simple approximation, with allowance for rigid body motion, is presented for the lowest non-zero frequency of a discrete system. The procedure is an extension and modification of that previously used to obtain a bound formula [1]. Illustrative examples and comparisons with known results are presented. 相似文献
57.
The occurrence, distribution and speciation of selenium in Australian marine biota is discussed. Biochemical pathways for the accumulation of selenium by marine organisms are also postulated. Comparison of the levels of selenium in macroalgae, fish, crustaceans and molluscs indicates that preferential accumulation of selenium by particular taxa does not occur. Phaeophyta have significantly lower selenium concentrations than Rhodophyta and Chlorophyta. Fish have lower selenium contents in muscle tissues than molluscs and crustaceans. Marine animals with different dietary intake (planktonic vs herbivorous vs carnivorous) are not observed to have significantly different levels of selenium (P>0.05). Selenium in all the organisms studied was predominantly associated with free amino-acids or protein residues and was not present as characterizable inorganic selenium species (SeO32?, SeO42?). These results indicate that selenium is probably only incorporated into biota for specific biochemical purposes with any exces selenium being excreted or eliminated. 相似文献
58.
In this paper we investigate the stability of the index, the nullity and the deficiency of normally solvable linear relations in paracomplete spaces under perturbation by strictly singular and T-strictly singular linear relations. This study led us to generalize some well-known results for operators and extend some results of small perturbation of normally solvable linear relations given by T. Alvarez (2012) [3]. 相似文献
59.
Nabeil A. Abujnah R. Letizia Mohamed Farhat O. Hameed Maher Abdelrazzak S. S. A. Obayya 《Optical and Quantum Electronics》2013,45(6):503-515
In this paper, slotted microcavity ring resonators based optical storage devices are proposed and analyzed by means of multiresolution time domain technique. The effect of the structure geometrical parameters on the coupling efficiency, normalized transmission spectra and quality factor has been thoroughly investigated and compared to that of the conventional no-slot microring resonator. The suggested slotted configurations increase the quality factor at a fixed gap size between the central ring and input/output waveguides. In addition, the desired compromise between the coupling efficiency and resonance effect inside the ring can be achieved by mere optimization of the slot geometrical characteristics. 相似文献
60.
We introduce the concept of numerical range approximant which is related to that of a spectral approximant. We obtain a variant of Bouldin result on spectral approximation of normal operators [3] and an analogous result for numerical range approximation . We also extend Maher's result on partially isometric approximation [9] and Halmos' on positive approximation [6]. 相似文献