Electrical conductivity and stimulated thermocurrent studies of the dicalcium strontium propionate single crystal

Electrical conductivity and stimulated thermocurrent studies of dicalcium strontium propionate (DSP) in pure, Fe³⁺ and acetate-doped single crystals have been performed in the temperature range 303–503 K. Conductivity measurements of pure and doped crystals indicate that propionate anions are responsible for the transition occurring at 400 K. Thermoelectric power measurements in the range 340–500 K of DSP (pure indicate that the transport charge carriers are electrons. A model for the conduction mechanism is proposed on the basis of π or resonating electrons of the carboxyl groups moving via tunnelling involving metal ions (Sr²⁺ and Ca²⁺). From activation energies estimated from conductivity and STC measurements the STC peak in DSP (Fe³⁺) occurring at 511 K is attributed to an impurity-vacancy jump mechanism.     

Chemical structure and curing dynamics of bisphenol S,PEEKTM-like,and resveratrol phthalonitrile thermoset resins

This effort provides a multifaceted analysis of the structural changes and material dynamics of thermally driven softening and curing of three distinct phthalonitrile (PN) resins that cross-link into thermally stable and oxidation-resistant thermosets. Although this material system has yielded a large subset of fire-retardant composites that require facile processing and low-temperature curing, to date, insufficient information had been available on the fundamental processes that drive their softening and curing stages. Our approach conducted a complementary analysis the chemistry, monomer mobility, and rheology of three PN polymers in order to correlate the curing processes with corresponding structural and behavioral transformations of thermosets. We focused on PNs with a bisphenol S backbone, a bisphenol A (PEEK^TM-like) backbone, and a resveratrol backbone. We relied on quasi-elastic neutron scattering (QENS) in order to analyze the in situ dynamics and self-diffusion properties of PN monomers, and to track changes in their mobilities during cross-linking and staging. Our analysis facilitates proper control over the staging and final curing of these resins and enables more efficient processing of these thermosets.     

Isolation of four new CoII/CoIII and NiII complexes with a pentadentate Schiff base ligand: syntheses, structural descriptions and magnetic studies

In this paper we report the temperature and pH dependent syntheses and systematic characterization of four new Co(II)/Co(III) and Ni(II) complexes with a pentadentate Schiff base ligand H(3)L obtained by condensing 1,3,-diaminopropan-2-ol with 2-hydroxyacetophenone in 1:2 molar ratio. The room temperature syntheses involving Co(II) and Ni(II) nitrates and the ligand H(3)L lead to the isolation of the dinuclear species [Co(2)L(2)(H(2)O)] (1), and the mononuclear complex [Ni(LH)] (3), respectively, whereas refluxing at basic pH leads to the tetranuclear complexes, [Co(II)(2)Co(III)(2)L(2)(μ(3)-OMe)(2)(NO(3))(H(2)O)(2)]NO(3)·2(H(2)O) (2), and [Ni(4)L(2)(μ(3)-OMe)(2)(H(2)O)(2)]·2H(2)O (4). 1 is found to be a simple mono alkoxo-bridged Co(III) dinuclear species, whereas 2 and 4 are both rhomb-like tetrameric complexes with double oxo bridges and μ(3)-methoxo bridges, derived from the methanol solvent, in an open dicubane arrangement. Moreover 2 shows six coordinate ordered Co(II) and Co(III) ions and 4 has both six- and five-coordinate Ni(II) centers. Compound 3 is assigned a tentative mononuclear structure based on IR, UV-Vis spectroscopic, (1)H-NMR and ESI mass study results and is supposed to have one Ni(II) center coordinated with a ligand fragment in square planar geometry. The variable temperature magnetic susceptibility study for 2 and 4 is performed which indicate for both 2 and 4 the presence of intracluster dominant ferromagnetic interactions.     

Stable carbon isotopes in dissolved inorganic carbon: extraction and implications for quantifying the contributions from silicate and carbonate weathering in the Krishna River system during peak discharge

We present a comparative study of two offline methods, a newly developed method and an existing one, for the measurement of the stable carbon isotopic composition (δ¹³C) of dissolved inorganic carbon (DIC; δ¹³C_DIC) in natural waters. The measured δ¹³C_DIC values of different water samples, prepared from laboratory Na₂CO₃, ground and oceanic waters, and a laboratory carbonate isotope standard, are found to be accurate and reproducible to within 0.5 ‰\ (1σ). The extraction of CO₂ from water samples by these methods does not require pre-treatment or sample poisoning and can be applied to a variety of natural waters to address carbon cycling in the hydrosphere. In addition, we present a simple method (based on a two-end-member mixing model) to estimate the silicate-weathering contribution to DIC in a river system by using the concentration of DIC and its δ¹³C. This approach is tested with data from the Krishna River system as a case study, thereby quantifying the contribution of silicate and carbonate weathering to DIC, particularly during peak discharge.     

Sensing of Zn2+ion by N-Furfurylsalicylaldimine Based on CHEF Process†

The recognition ability of N-Furfurylsalicylaldimine (HL) toward various cations (Pb²⁺, Hg²⁺, Ba²⁺, Cd²⁺, Ag⁺, Zn²⁺, Cu²⁺, Ni²⁺, Co²⁺, K⁺, Sr²⁺, and Na⁺) has been studied by UV–Vis and fluorescence spectroscopy. The compound showed highly selective fluorescence signaling behaviour for Zn²⁺ ions in methanol-water medium based on CHEF process and is capable of distinguishing Zn²⁺ from Cd²⁺ ion. From single crystal X-ray analysis it is revealed that a Zn²⁺ ion binds two ligand molecules through imine nitrogen and phenolate oxygen atom.

Photograft Copolymerization of Methyl Methacrylate and Natural Rubber Using Quinoline-Bromine C.T. Complex as Photoinitiator in Benzene Solution

Photografting of poly(methyl methacrylate), PMMA chains on natural rubber (NR) chain backbones was studied in benzene solution using quinoline-bromine (Q-Br₂) charge transfer complex as photoinitiator and MMA as monomer at 35°C in visible light. Analysis of overall products for determination of grafting efficiencies was done following a method of selective extraction of only the free rubber fraction by benzene-petroleum ether mixtures followed by separation of the NR-PMMA graft copolymer from free PMMA in the residue (taken in benzene solution) by fractional precipitation with methanol. High grafting efficiencies in the range of 75–95% were easily and generally obtained. Effects of variation of concentrations of initiator, rubber, and monomer on grafting efficiencies were examined and reported. Prior photodegradation of the rubber resulted in substantial lowering in grafting efficiencies. Overall mechanism of graft copolymerization has been discussed.     

Synthesis of Quinoline Analogs: Search for Antimalarial Agents

Summary. Novel synthesis routes for the promising antimalarial agents 4(3-hydroxypyrrolidin-1-yl) and 4(3-hydroxypiperidine-1-yl)-2,8-bis(trifluoromethyl)quinoline have been developed.     

Fractional Fourier plane image encryption technique using radial hilbert-, and Jigsaw transform

A new method for image encryption using integral order radial Hilbert transform (RHT) filter in the fractional Fourier transform (FRT) domain has been proposed. The technique is implemented using the popular double random phase encoding method in the fractional Fourier domain. The random phase masks (RPMs), integral orders of the RHT, fractional orders of FRT, and indices of the Jigsaw transform (JT) have been used as keys for encryption and decryption. Simulation results have been presented and the schematic representation for optical implementation has been proposed. The mean-square-error and signal-to-noise ratio between the decrypted image and the input image have been calculated for the correct as well as incorrect orders of the RHT. Effect of occlusion and noise on the performance of the proposed scheme has also been studied. The robustness of the technique has been verified against attack using partial windows of the correct random phase masks. Similar investigations have also been carried out for the chosen-, and the known-plain-text attacks.