曼地亚红豆杉枝条中紫杉醇的超声提取研究

研究了曼地亚红豆杉枝条中紫杉醇的超声浸提,通过液液萃取对粗提物进行二次纯化,用高效液相色谱检测紫杉醇的含量。试验确定紫杉醇的最佳浸提工艺条件为:浸提时间:90min(三次浸提,30m in/次);温度:50℃;原料粒径:0.180~0.120mm。最佳工艺条件下用10.0g原料提取得到的0.0465g浸膏中,紫杉醇质量浓度为6.182%。     

帽状银纳米粒子的制备及表面增强拉曼活性研究

采用真空热蒸发法在自组装的单层阵列二氧化硅纳米粒子表面沉积银膜制备了帽状银纳米粒子。通过透射电镜(TEM)、扫描电镜(SEM)和紫外-可见-近红外分光光度计 (UV-Vis-NIR)对其表面形貌及光学性质进行了表征。以吡啶-(2-偶氮-4)间苯二酚作为探针分子，研究了该复合纳米粒子的表面增强拉曼散射 (SERS) 活性，增强因子高达2.88×10⁶。结果表明在二氧化硅纳米粒子表面制备的帽状银纳米粒子是很好的表面增强拉曼散射活性基底。     

Effect of Mo content in MoO3/g-Al2O3 on the catalytic activity for transesterification of dimethyl oxalate with phenol

The influence of molybdenum content on the catalytic performance in the transesterification of dimethyl oxalate (DMO) with phenol to methyl phenyl oxalate (MPO) and diphenyl oxalate (DPO) was investigated. The results indicated that the MoO₃/Al₂O₃ catalyst with 14 wt% Mo content gave maximal DPO yield with 6.1% and 75.1% DMO conversion. The component, structure and phase of MoO₃/Al₂O₃ catalysts were characterized by means of X-ray diffraction (XRD), BET specific surface area, temperature-programmed desorption of ammonia (NH₃-TPD), and FTIR analysis of adsorbed pyridine. This revised version was published online in June 2006 with corrections to the Cover Date.     

SiO2 /Au核壳结构纳米粒子的制备及表征

通过以金纳米粒子为表面晶种和壳生长的方法制备了金纳米壳包覆二氧化硅的复合纳米粒子。采用TEM 和UV-Vis对复合粒子进行了表征和研究，结果表明所得到的复合粒子粒径均匀、金纳米壳光滑完整，且壳厚度可通过反应物的用量来控制。当核半径与壳厚度之比在4到13之间变化时,复合粒子的光学共振峰在可见光区到近红外光区范围内可发生大于500 nm波长的移动。     

A new crossover approach for solving the multiple travelling salesmen problem using genetic algorithms

This paper proposes a new crossover operator called two-part chromosome crossover (TCX) for solving the multiple travelling salesmen problem (MTSP) using a genetic algorithm (GA) for near-optimal solutions. We adopt the two-part chromosome representation technique which has been proven to minimise the size of the problem search space. Nevertheless, the existing crossover method for the two-part chromosome representation has two limitations. Firstly, it has extremely limited diversity in the second part of the chromosome, which greatly restricts the search ability of the GA. Secondly, the existing crossover approach tends to break useful building blocks in the first part of the chromosome, which reduces the GA’s effectiveness and solution quality. Therefore, in order to improve the GA search performance with the two-part chromosome representation, we propose TCX to overcome these two limitations and improve solution quality. Moreover, we evaluate and compare the proposed TCX with three different crossover methods for two MTSP objective functions, namely, minimising total travel distance and minimising longest tour. The experimental results show that TCX can improve the solution quality of the GA compared to three existing crossover approaches.     

镍基板上低温合成定向纳米碳管

纳米碳管具有非常优异的场发射效应 ,亮度高、均匀且稳定的纳米碳管场效应发射器 ,例如平板显示器、阴极射线管以及信号灯等有着非常广阔的应用前景 [1] .由于纳米碳管的场发射效应与纳米碳管的方向性有关[2 ] ,因此定向纳米碳管的制备及其场发射性能研究是当前的一个研究热点     

Discounted MEAN bound for the optimal searcher path problem with non-uniform travel times

We consider an extension of the optimal searcher path problem (OSP), where a searcher moving through a discretised environment may now need to spend a non-uniform amount of time travelling from one region to another before being able to search it for the presence of a moving target. In constraining not only where but when the search of each cell can take place, the problem more appropriately models the search of environments which cannot be easily partitioned into equally sized cells. An existing OSP bounding method in literature, the MEAN bound, is generalised to provide bounds for solving the new problem in a branch and bound framework. The main contribution of this paper is an enhancement, discounted MEAN (DMEAN), which greatly tightens the bound for the new and existing problems alike with almost no additional computation. We test the new algorithm against existing OSP bounding methods and show it leads to faster solution times for moving target search problems.     

一系列水合和非水合铀酰卤族(F,Cl,Br)配合物在水溶液中的结构和紫外吸收光谱性质的密度泛函理论研究

本文考虑相对论效应并应用密度泛函理论(DFT)研究水溶液中UO2Xn(H2O)5-n(X=F,Cl,Br;n=1～4)和UO2Xn(X=F,Cl,Br;n=1～6)一系列水合和非水合铀酰化合物的结构和紫外吸收光谱性质。将这一系列物质命名为Xnm(X为F,Cl,和Br;n为卤素配体个数,m为水分子配体的个数)。在水溶液中,溶剂化效应采用类导体屏蔽模型(COSMO)并采用SAS溶剂接触曲面构造空穴模拟水溶剂对配合物的作用。配合物的紫外光谱性质采用考虑旋-轨耦合相对论效应的含时密度泛函(SO-TD-DFT)进行计算。U=O键随着F配体数目的增加而明显伸长,然而随Cl和Br配体数目的增加变化较小。随X配体数目的增加和水分子参与配位,铀与X的结合能逐渐减弱。配合物的紫外光谱计算表明铀酰氟的各种配合物并不出现特征吸收峰,而铀酰氯和铀酰溴的各种配合物均有特征吸收光谱。通过分子轨道分析可以很好解释光谱所体现的特征。     

基于模糊中值滤波的椒盐噪声去除方法

研究基于模糊中值滤波的椒盐噪声去除方法。通过比较图像各像素点的灰度值,定义基于图像梯度信息的各点被判别为噪声点的模糊隶属函数。利用此模糊隶属函数对中值滤波方法进行加权,得到了一种加权中值滤波器,可实现边缘处椒盐噪声的有效滤除。讨论这种模糊加权方法与其它先进滤波方法的结合途径,指出了其推广应用价值。最后利用数值实验验证本文方法的有效性,结果表明,相比于自适应中值滤波方法,本文方法得到的滤波图像在峰值信噪比及结构相似度方面均有明显提高。     

多束物光干涉和实时监控的全息照相实验

本文突破传统的干涉光路,使用两束物光与一束参考光产生的干涉图样来记录信息,并同时使用麦克尔逊干涉条纹实现对干涉条纹的放大与实时监控,以获得最佳拍摄效果.除此之外,本文还对三束光波的干涉进行理论分析及数理推导,从理论与实践的角度对全息照相技术进行探讨.