首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   991632篇
  免费   9481篇
  国内免费   3068篇
化学   521489篇
晶体学   14170篇
力学   47155篇
综合类   32篇
数学   133000篇
物理学   288335篇
  2021年   7973篇
  2020年   8781篇
  2019年   9714篇
  2018年   12567篇
  2017年   12472篇
  2016年   18596篇
  2015年   11302篇
  2014年   17720篇
  2013年   43723篇
  2012年   32725篇
  2011年   39734篇
  2010年   28719篇
  2009年   28290篇
  2008年   37186篇
  2007年   37047篇
  2006年   34422篇
  2005年   30936篇
  2004年   28475篇
  2003年   25490篇
  2002年   25224篇
  2001年   27036篇
  2000年   21194篇
  1999年   16683篇
  1998年   14122篇
  1997年   13868篇
  1996年   13465篇
  1995年   12027篇
  1994年   11920篇
  1993年   11628篇
  1992年   12680篇
  1991年   12967篇
  1990年   12542篇
  1989年   12313篇
  1988年   12123篇
  1987年   11934篇
  1986年   11414篇
  1985年   14924篇
  1984年   15421篇
  1983年   12738篇
  1982年   13377篇
  1981年   12841篇
  1980年   12177篇
  1979年   13001篇
  1978年   13638篇
  1977年   13435篇
  1976年   13222篇
  1975年   12546篇
  1974年   12459篇
  1973年   12677篇
  1972年   9087篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
2.
3.
    
The reaction of [{(η5-C5Me5)M(μ-Cl)Cl}2] {where M = Rh (1), Ir (2)} with functionalized phosphine viz., diphenyl-2-pyridylphosphine (PPh2Py) in dichloromethane solvent yield neutral ϰ1-P-coordinated rhodium and iridium complexes [(η5-C5Me5)RhCl21-P-PPh2Py)]3 and [(η5-C5Me5) IrCl21-P-PPh2Py)]4. Reaction of complexes 1 and 2 with the ligand PPh2Py in methanol under reflux give bis-substituted complexes such as [(η5-C5Me5)RhCl(ϰ1-P-PPh2Py)2]+ 5 and [(η5-C5Me5)IrCl(ϰ1-P-PPh2Py)2]+ 6, whereas stirring in methanol at room temperature gives P-, N-chelating complexes of the type [(η5-C5Me5)RhCl(ϰ2-P-N-PPh2Py)]+ 7 and [(η5-C5Me5)IrCl(ϰ2-P-N-PPh2Py)]+ 8. Neutral ϰ1-P-coordinated complexes [(η5-C5Me5)RhCl21-P-PPh2Py)]3 and [(η5-C5Me5)IrCl21-P-PPh2Py)]4 easily undergo conversion to the cationic P-, N-chelating complexes [(η5-C5Me5)RhCl(ϰ2-P-N-PPh2Py)]+ 7 and [(η5-C5Me5) IrCl(ϰ2-P, N-PPh2Py)]+ 8 on stirring in methanol at room temperature. These complexes are characterized by FT-IR and FT-NMR spectroscopy as well as analytical methods. The molecular structures of the representative complexes [(η5-C5Me5)RhCl21-P-PPh2Py)]3, [(η5-C5Me5)IrCl21-P-PPh2Py)]4 and hexafluorophosphate salt of complex [(η5-C5Me5)IrCl(ϰ2-P-PPh2Py)2]+ 6 are established by single-crystal X-ray diffraction methods  相似文献   
4.
5.
An optimal control model of exhaustible resources is used to clarify the long run relationship between mineral rent and depletion cost at the industry level. A standard first order condition of the time rate of change of rents is reformulated to reveal that rent data may be used to help forecast the rise in extraction costs resulting from resource depletion. This application of the theory of exhaustible resources is illustrated using historical mineral industry rent and extraction cost data. A forecast of U.S. coal extraction costs, following the method proposed in this paper, suggests that future rates of extraction cost increases will be similar to rates experienced in the past.  相似文献   
6.
To investigate local ordering and segregation phenomenon in a Ni91Pt9-alloy after sputtering and annealing a 3D optical atom probe (OAP) has been used. The specimen tips have been prepared from polycrystalline samples. To sputter the samples a separate preparation chamber with a scannable Ar-sputter-gun is connected to the OAP vessel. When necessary, the sample can be electrically heated to induce segregation and cure the altered layer. After a heat treatment of a Ni91 at. %Pt 9 at.% specimen at 1100 K the surface of a (111)-oriented specimen is enriched in platinum by a factor of two in relation to the bulk. The phenomenon of short-range ordering has been investigated on the surface and in the subsurface volume. A 3D reconstruction of this annealed NiPt specimen shows regions with high concentration of platinum that gives an indication at short-range ordering. Uniform sputtering of the tip without a heat treatment induces a decisive depletion of Pt on the surface and the following subatomic layers. The atom-probe results of specimens in thermal equilibrium are in close agreement to further surface sensitive results obtained from Ion Scattering Spectroscopy (ISS) and Auger Electron Spectroscopy (AES).  相似文献   
7.
Preface     
  相似文献   
8.
9.
One obtains a formula for the transformation of a vector with a given covariance matrix. The sum of the squares of the components of the transformed vector is equal to a chi-square type quadratic form, constructed with the aid of the initial vector. Taking into account this property, one finds the components of the Pearson statistic, Pearson-Fisher statistic, etc.Translated from Veroyatnostnye Raspredeleniya i Matematicheskaya Statistika, pp. 337–350, 1986.  相似文献   
10.
We find logarithmic small ball asymptotics for the L2-norm with respect to self-similar measures for a certain class of Gaussian processes including Brownian motion, Ornstein-Uhlenbeck process, and their integrated counterparts. Bibliography: 46 titles. __________ Translated from Zapiski Nauchnykh Seminarov POMI, Vol. 311, 2004, pp. 190–213.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号