Synthesis of ABCD 4‐Miktoarm star‐shaped quarterpolymers by combination of the “click” chemistry with multiple polymerization mechanism

Well‐defined ABCD 4‐Miktoarm star‐shaped quarterpolymers of [poly(styrene)‐poly(tert‐butyl acrylate)‐poly(ethylene oxide)‐poly(isoprene)] [star(PS‐PtBA‐PEO‐PI)] were successfully synthesized by the combination of the “click” chemistry and multiple polymerization mechanism. First, the poly(styryl)lithium (PS^?Li⁺) and the poly(isoprene)lithium (PI^?Li⁺) were capped by ethoxyethyl glycidyl ether (EEGE) to form the PS and PI with both an active ω‐hydroxyl group and an ω′‐ethoxyethyl‐protected hydroxyl group, respectively. After these two hydroxyl groups were selectively modified to propargyl and 2‐bromoisobutyryl group for PS, the resulted PS was used as macroinitiator for ATRP of tBA monomer and the diblock copolymer PS‐b‐PtBA with a propargyl group at the junction point was achieved. Then, using the functionalized PI as macroinitiator for ROP of EO monomer and bromoethane as blocking agent, the diblock copolymer PI‐b‐PEO with a protected hydroxyl group at the conjunction point was synthesized. After the hydrolysis, the recovered hydroxyl group of PI‐b‐PEO was modified to bromoacetyl and then azide group successively. Finally, the “click” chemistry between them was proceeded smoothly. The obtained star‐shaped quarterpolymers and intermediates were characterized by ¹H NMR, FT‐IR, and SEC in detail. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 2154–2166, 2008     

The electrochemical behavior of N-n-undecyl-N''-(sodium-p-amino-benzenesulfonate)thiourea and its interaction with bovine serum albumin

In pH 5.5 phosphate buffer solution,N-n-undecyl-N'-(sodium-p-amino-benzenesulfonate)thiourea(UPT)produced a pair of redox peaks on the bare glassy carbon electrode.At the multi-walled carbon nanotube(MWNT)modified electrode,the electrochemical behavior of UPT enhanced greatly.In the presence of bovine serum albumin (BSA),the peak currents of UPT decreased linearly due to the formation of a super-molecular complex.This method was successfully applied to the determination of BSA in a bovine serum sample.     

Typical Microstructures of Chinese Medicines with X-Ray Microscopy in Phase Contrast

Due to the low absorption contrast of plant tissues, traditional x-ray radiography has not been included in the microscopic techniques used in the identification of traditional Chinese medicines （TCMs）. With the development of x-ray phase contrast imaging （XPCI） in recent years, weakly absorbing materials could also be imaged by x- rays. Here we investigate microstructures of TCMs utilizing XPCI based on a nano-focus x-ray tube. The results demonstrated that XPCI is capable of revealing the microstructures of TCMs used as judging criteria in the identification of TCMs. The major advantages of the new method are nondestructivity, no special demand for sample preparation and suitability for thick samples.     

Nonlinear weighted best simultaneous approximation in Banach spaces

The present paper is concerned with the problem of weighted best simultaneous approximations in Banach spaces. The weighted best simultaneous approximations to sequences from S- and BS-suns in the Banach space are characterized in view of the Kolmogorov conditions. Applications are provided for weighted best simultaneous approximations from RS-sets and strict RS-sets. Our results obtained in the present paper extend and improve all earlier known results in this direction.     

WEAK CONVERGENCE OF SOME DIRICHLET SERIES

1 Besicovitch Inner ProductIll this paper, we consider Dirichlet serie8where an, tL = 1, 2,' ', are complex nunlbers. They are Besicovitch almost periodic functionsWe see the 8ystenl {e.(t); e.(t) = e--it Iog 1l, 71 = l, 2,' .} fOrnis a1l orthollor11la1 systelll witl1respect to tI1e BesicovitcI1 iIl1ler productThell we call fOrm the gelleralized trigouolnetrical polynolIlialsAccording to tl1e idea developed il1 [l],[2], auy Dirichlet seriesis weakly convergent over K witll respect to …     

会务信息的电致发光矩阵大屏幕显示

本文概述了长春物理研究所为人民大会堂研制的交流(AC)、直流(DC)电致发光(EL)矩阵大屏幕会务信息显示的结果。其中,ACEL矩阵屏幕尺寸为2.5×3m2,由30块0.46×0.46m2的单元屏拼接而成。平均亮度20尼特,对比度10:1;DCEL矩阵屏幕为:1m2,行列数120×144,平均亮度45尼特,对比度大于10:1。在环境照度60lux条件下,观察距离分别为65m、20m。并从分析EL矩阵的显示特性出发,阐明了显示系统的设计要点,控制、匹配电路和亮度、对比度的关系;还给出了部分驱动电路结构和系统的应用结果。