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131.
P. Allenspach J. Mesot U. Staub M. Guillaume A. Furrer S. -I. Yoo M. J. Kramer R. W. McCallum H. Maletta H. Blank H. Mutka R. Osborn M. Arai Z. Bowden A. D. Taylor 《Zeitschrift für Physik B Condensed Matter》1994,95(3):301-310
Neutron diffraction, neutron spectroscopy and magnetization measurements have been employed to study the structural, electronic, and magnetic behavior of eleven compounds with the general formula Nd1+y
Ca
v
Ba2–y–v
Cu3O
x
(0y0.5; 0v0.25; 6x7). The structure turned out to react to oxygen reduction similar as other 123-compounds, yielding discontinuities close to the metal-insulator-transition and the well-known relations of bond lengths as a function ofT
c. The crystalline electric field (CEF) interaction, splitting the 10-fold degenerate ground-state J-multiplet of the Nd3+-ions into five doublet states, was investigated by neutron spectroscopy. The derived CEF parameters have been used to determine changes in the electronic surroundings of the Nd3+ ions. In addition, with the help of the CEF parameters the thermodynamic magnetic properties of these compounds were calculated which turn out to be in good agreement with the experimental data. 相似文献
132.
Tijana Zivkovic Nieck E. Benes Dave H.A. Blank Henny J.M. Bouwmeester 《Journal of Sol-Gel Science and Technology》2004,31(1-3):205-208
An intermediate surfactant-templated silica (STS) layer is applied between the supporting mesoporous γ-Al2O3 and the amorphous microporous silica overlayer resulting in dual-layered microporous silica membranes for gas separation applications that show improved values for both hydrogen flux and selectivity. Determination of thickness and porosity of as-deposited membrane layers by spectroscopic ellipsometry reveals that the STS layer is present as a distinctive layer of ~20 nm thickness, with penetration up to a depth of ~70 nm into the underlying γ-Al2O3support layer, whose thickness and porosity are determined to be 1.3 μm and 50%, respectively. 相似文献
133.
As part of a collaborative study of cellular efflux of cholesterol and phospholipids, photoactivable analogues 4-8 of phosphatidylcholine (PC) having benzophenone groups in the choline moiety and at the end of the C2 and C1 alkyl chains have been synthesized. The efficient preparation via Suzuki coupling of the appropriate long-chain benzophenone-containing carboxylic acid and alcohol and their incorporation by adaptation of known approaches into the acyl- and ether-linked PC analogues 6-8 are described. Development of a method for radiolabeling these PC analogues, via hydrogenation of a double bond in modified side chains, is also described. 相似文献
134.
Luise Wennrich Werner Engewald Hansjörg Herden 《Monatshefte für Chemie / Chemical Monthly》1985,116(8-9):889-899
High silica molecular sieves (silicalite, ZSM-5) were tested as adsorbents for gas chromatographic trace analysis. Therefore the retention behaviour of low-boiling organic compounds (hydrocarbons, halogenated hydrocarbons, amines, alcohols and ethers) on these materials was investigated. The specific retention volumes at different temperatures have been determined and elution orders and peak shapes were studied. The retention data allow a simple calculation of the breakthrough volumes (dynamic adsorption capacity) and the chromatographic characterisation of the adsorbents. Both nitrogen and oxygen containing compounds could not—or at least unreproducibely—be eluated up to 300°. The elution order and the peak shape of compounds with the same number of carbon atoms but different geometric and electronic structure (e.g.n-butenes;n-hexane, cyclohexane, benzene) can be explained by the action of exclusion effects and different diffusion barriers. On the basis of calculated breakthrough volumes we conclude that silicalite should be useful in the preconcentration of both saturated C3–C6 hydrocarbons and C1–C2 chlorinated hydrocarbons from gaseous streams. 相似文献
135.
Wolfgang Malisch Herbert Blau Konrad Blank Carl Krüger L.K. Liu 《Journal of organometallic chemistry》1985,296(3):c32-c36
]The reaction of the acyliron phosphorus ylide Cp(CO)2FeC(O)CHPMe3 with MeOSO2F yields the acyliron phosphonium salt [Cp(CO)2FeC(O)C(Me)- HPMe3]SO3F, while Cp(CO)2FeC(O)C(Me)PEt3 undergoes exclusively O-alkylation to the complex salt [Cp(CO)2FeC(OMe)C(Me)PEt3]SO3F, (A). The acyliron ylides Cp(CO)2FeC(O)C(R)PR3 (R R′ Me; or R H, R′ Et) are converted to a mixture of the O- and C-methylated products. According to spectroscopic data and X-ray diffraction analysis of A the O- alkylation products have to be described as phosphoniovinyliron complexes. 相似文献
136.
Hubert Blank 《ChemInform》2002,33(50):216-216
137.
Carsten Blank Martina Chirilus Bruckner Christopher Chong Vincent Lescarret Guido Schneider Hannes Uecker 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2008,59(3):554-557
We prove the validity of a technical assumption necessary in a proof of the validity of the nonlinear Schr?dinger equation
as envelope equation in quadratic spatially periodic media.
相似文献
138.
139.
140.
N. L. Achouri F. de Oliveira Santos M. Lewitowicz B. Blank J. Äystö G. Canchel S. Czajkowski P. Dendooven A. Emsallem J. Giovinazzo N. Guillet A. Jokinen A. M. Laird C. Longour K. Peräjärvi N. Smirnova M. Stanoiu J. -C. Thomas 《The European Physical Journal A - Hadrons and Nuclei》2006,27(3):287-300
In an experiment performed at the LISE3 facility of GANIL, we studied the decay of 22Al produced by the fragmentation of a 36Ar primary beam. A β-decay half-life of T1/2 = 91.1±0.5ms was measured. The β-delayed one- and two-proton emission as well as β-α and β-delayed γ-decays were measured
and allowed us to establish a partial decay scheme for this nucleus. New levels were determined in the daughter nucleus 22Mg. The comparison with model calculations strongly favours a spin-parity of Iπ = 4+ for the ground state of 22Al. 相似文献